采用射频磁控溅射法制备Ti金属薄膜作为反应电极,结合脉冲激光沉积法在Pt/Ti/Si衬底上制备了Ti/非晶-SrTiO3-δ (STO)/Pt结构的阻变存储器件单元.器件的有效开关次数可达200次以上.利用5 mV的小电压测量处于高低阻态的器件电阻,发现在经过3.1 ×105 s以后,两种阻态的电阻值均没有明显的变化,说明器件具有较好的保持特性.器件处于高阻态和低阻态的电阻比值可达100倍以上.在9mA的限制电流下,器件的低阻态为500 Ω,有利于降低电路的功耗.氧离子和氧空位的迁移在阻变开关中起到重要的作用,界面层TiOx发挥着氧离子库的作用.阻变开关机制归因为导电细丝(Filaments)的某些部分出现氧化或者还原现象,造成导电细丝的形成和断开.
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