采用熔融-晶化法制备了Tb3+掺杂的CaMoO4为主晶相的透明钼酸盐玻璃陶瓷。利用DSC、XRD、SEM确定了该体系玻璃样品的最佳热处理制度：715℃保温2.5 h；随着热处理时间的增加，玻璃陶瓷中的晶粒尺寸逐渐变大；利用UV-Vis-NIR得到样品玻璃陶瓷在可见光区的透过率可达80%；并利用荧光光谱讨论了在相同热处理条件下，不同Tb3+掺杂浓度对玻璃陶瓷样品发光性能的影响，研究表明Tb3+掺杂浓度为7.0mol%时样品的荧光强度最大。
Tb3+ doped transparent molybdate glass ceramics containing CaMoO4 were successful fabricated by melt-quenching technique. The optimal heat-treated system for the glass sample was determined by DSC,XRD and SEM(715℃ for 2. 5 h). The grain size of the glass ceramics gradually increased with the increasing of heat treatment time. The UV-Vis-NIR spectra indicated that the sample transparency was approximately up to 80% in visible light range. The effect of different Tb3+ doping concentration on the luminescence properties of the glass ceramics under the condition of the same heat treatment by fluorescence spectrum. The experimental result indicated that the Tb3+ doping concentration was 7. 0 mol%, the sample has the maximum fluorescence intensity.
参考文献
| [1] | Ernst Heumann;Sebastian Bar;Katja Rademaker;Gunter Huber;Stuart Butterworth;Andreas Diening;Wolf Seelert.Semiconductor-laser-pumped high-power upconversion laser[J].Applied Physics Letters,20066(6):061108-1-061108-3-0. |
| [2] | 杨建虎;戴世勋;姜中宏.稀土离子的上转换发光及研究进展[J].物理学进展,2003(3):284-298. |
| [3] | Biswas A.;Maciel GS.;Friend CS.;Prasad PN..Upconversion properties of a transparent Er3+-Yb3+ co-doped LaF3-SiO2 glass-ceramics prepared by sol-gel method[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,20032/3(2/3):393-397. |
| [4] | Jun Ho Chung;Jeong Ho Ryu;Sang Yeop Lee.Effect of Yb~(3+) and Tm~(3+) concentrations on blue and NIR upconversion luminescence in Yb~(3+) , Tm~(3+) co-doped CaMoO_4[J].CERAMICS INTERNATIONAL,20132(2):1951-1956. |
| [5] | 翟永清;韩英;张弯;殷艳杰;赵鑫;王莉莉.CaMoO4∶Dy黄绿色荧光粉的微波合成及掺杂PO43-的荧光增强效应[J].发光学报,2016(7):765-772. |
| [6] | Jun Ho Chung;Jeong Ho Ryu;Sung Wook Mhin.Controllable white upconversion luminescence in Ho~(3+)/Tm~(3+)/Yb~(3+) co-doped CaMoO4[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20129(9):3997-4002. |
| [7] | 符启慧;刘君武.Eu3+掺杂CaMoO4粉体的制备及发光性能[J].中国陶瓷,2016(5):27-30. |
| [8] | 陈国华;唐林江;职利;成钧;刘心宇.玻璃组成对CaO-Al_2O_3-SiO_2系玻璃烧结、晶化和性能的影响[J].中南大学学报（自然科学版）,2009(5):1270-1275. |
| [9] | 袁利娜 .硼硅酸盐玻璃/氮化铝低温共烧复合材料的制备与性能研究[D].天津大学,2013. |
| [10] | 王倩 .Ce3+/Tb3+掺杂氟氧化物微晶玻璃的光谱性能研究[D].宁波大学,2015. |
| [11] | 薄素玲 .稀土离子Eu、Tb掺杂的以CaMoO<,4>和SiO<,2>一元或二元体系为基质的发光材料的制备与发光性质研究[D].内蒙古师范大学,2009. |
| [12] | 朱立刚 .稀土离子掺杂发光玻璃的制备与性能研究[D].中南大学,2012. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%