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Rare earth compounds can be used as PVC thermal stabilizers. According to the infrared spectra of the mixture of PVC and some stearates, the mechanism of stabilization of different stearates was studied. The specialty of rare earth stabilizers was found. They can change the conformation of PVC and restrain the elimination of HCl. From this aspect, the unique synergetic effect with other stabilizers of rare earth compounds can be explained.

参考文献

[1] Yassin A A;Sabba M W .Degradation and stabilization of poly(vinyl chloride)[J].Macromolecular Chemistry and Physics,1991,C30(3,4):491.
[2] Xu Guangxian.Rare Earths (in Chin.)[M].北京:冶金工业出版社,1995:679.
[3] Mao Junjun;Su Qingde;Zhao Guiwen .Studies on applied model and synergetic effect of rare earth[J].稀土学报(英文版),1996,14(04):312.
[4] Smith A L.Applied Infrared Spectroscopy[M].New York: John Wiley & Sons, Inc,1979:186.
[5] Su Qingde;Mao Junjun;Zhao Guiwen et al.A study on the structure of degraded PVC by photoacoustic spectroscopy[J].Journal of Molecular Structure,1997,403:231.
[6] Yang Zhanhong;Shu Wangen .Application prospect of rare earth heat stabilizer in PVC plastics[J].稀土,1995,16(05):47.
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