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Synthesis of AIN by NH4Cl-assisted direct nitridation of secondary Al resources was studied. Aluminum alloy scrap contained Mg and Zn element was used. Milled Al scrap(-1 mm)was mixed with NH4Cl and heated at 1000℃ for 1 h in presence of 1 L/min N2 flow gas. The nitridedproduct was evaluated by X-ray diffraction semi-quantitative analysis and scanning electron microscopy(SEM). Aluminium nitride of 90.5% concentration was obtained with a hexagonal crystalline form. AIN is mostly formed in nano-whisker morphology(50~150 nm)which is homogenously distributed.

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