Synthesis of AIN by NH4Cl-assisted direct nitridation of secondary Al resources was studied. Aluminum alloy scrap contained Mg and Zn element was used. Milled Al scrap(-1 mm)was mixed with NH4Cl and heated at 1000℃ for 1 h in presence of 1 L/min N2 flow gas. The nitridedproduct was evaluated by X-ray diffraction semi-quantitative analysis and scanning electron microscopy(SEM). Aluminium nitride of 90.5% concentration was obtained with a hexagonal crystalline form. AIN is mostly formed in nano-whisker morphology(50~150 nm)which is homogenously distributed.
参考文献
[1] | M Kasu;N Kobayashi .[J].Applied Physics Letters,2001,79:3642. |
[2] | V. N. Tondare;C. Balasubramanian;S. V. Shende;D. S. Joag;V. P. Godbole;S. V. Bhoraskar;M. Bhadbhade .Field emission from open ended aluminum nitride nanotubes[J].Applied physics letters,2002(25):4813-4815. |
[3] | Q Wu;Z Hu;X Z Wang;Y N Lu, K F Huo and S Z Deng .[J].Journal of Materials Chemistry,2003,13:2024. |
[4] | J M Bonar;D H Kind;A T Stockli;L O Nilsson .[J].Solid-State Electronics,2001,45:893. |
[5] | G Selvasuray;L Sheet.[J].Materials Science and Technology,1994(09):463. |
[6] | K Komeya;N Matsukaze;T Meguro .[J].Journal of the Chemical Society of Japan,1993,101:1319. |
[7] | T Okada;M Obata;M Toriyama;S Kanzaki .[J].Journal of the Chemical Society of Japan,1999,107:455. |
[8] | A Calka;J I Nikolov.[J].Nanostructured Materials,1995(06):409. |
[9] | J I Nikolov;J S Williams;D J Llewellyn;A Calka .[J].Materials Research Society Symposium Proceedings,1998,481:649. |
[10] | M. Radwan;M. Bahgat;A.A. El-Geassy .Formation of aluminium nitride whiskers by direct nitridation[J].Journal of the European Ceramic Society,2006(13):2485-2488. |
[11] | M Radwan;M Bahgat.[J].Journal of Nanoscience and Nanotechnology,2006(06):1. |
[12] | F E Farghaly .[D].Ain-shams University,Cairo,Egypt,2001. |
[13] | K Kondoh;Y Takeda .[J].Journal of the Japan Society of Powder and Powder Metallurgy,1999,46(08):801. |
[14] | J Liu;X Gao;J Chen;Q Wang, Y Shen and Q Gao .[J].Thermochimica Acta,1995,253:265. |
[15] | Q H Hou;R Mutharasan;M Koczak .[J].Materials Science and Engineering A,1995,195:121. |
[16] | H Ye;X Liu;B Luan .[J].Materials Letters,2004,58:2361. |
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