目前，有关用肉桂酸和有机胺合成咪唑啉衍生物及其合成产物的缓蚀性能与机理研究未见介绍。利用肉桂酸和二乙烯三胺脱水反应生成咪唑啉衍生物，采用失重法、电化学方法、量子化学计算研究了合成缓蚀剂对Q235钢的缓蚀性能和机理。结果表明，新型肉桂基咪唑啉的缓蚀率随缓蚀剂浓度的增大而升高，＂-31mol／LHCl中缓蚀剂浓度为800mg／L时，对Q235钢的缓蚀率可达94．7％；该缓蚀剂为以抑制阴极过程为主的混合型缓蚀剂，缓蚀机理为负催化效应。从量子化学的角度来看，新型肉桂基咪唑啉分子结构中含有苯环、一C=N一和一C=C一等供电子基团，可以在金属表面牢固吸附。
参考文献
| [1] | 刘建平,杨新丽,周晓湘.酸洗缓蚀剂ZZF缓蚀性能研究[J].腐蚀科学与防护技术,2010(02):101-103. |
| [2] | Ismail Abdelrhman Aiad;A. A. Hafiz;M. Y. El-Awady .Some Imidazoline Derivatives as Corrosion Inhibitors[J].Journal of Surfactants and Detergents,2010(3):247-254. |
| [3] | Cruz J;Martinez R;Genesca J et al.Experimental and the-oretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media[J].Journal of Electroanalytical Chemistry,2004,566:111121. |
| [4] | 陈武,梅平,潘阳秋.油田酸化液中咪唑啉及其季铵盐的缓蚀作用[J].腐蚀与防护,2011(01):17-20,28. |
| [5] | 张光华,王腾飞,孙卫玲,董惟昕,费菲.硫脲基烷基咪唑啉类缓蚀剂的制备、缓蚀性能及其机理[J].材料保护,2011(02):21-23,58. |
| [6] | Blair C M;Groves W;Gross W F et al.Processes for preventing corrosion and corrosion inhibitors[P].US,2466517,1949-04-26. |
| [7] | Edwards A;Osborne C;Webster S et al.Mechanistic studies of the corrosion inhibitor oleic imidazoline[J].CorrosionScience,1994,36(02):315-325. |
| [8] | 张军,胡松青,张立红,尤龙,刘金祥,于立军.咪唑啉自组装膜抑制CO2对碳钢腐蚀的分子模拟[J].中国石油大学学报（自然科学版）,2009(04):141-144,149. |
| [9] | M. A. Quraishi;M. Z. A. Rafiquee;Nidhi Saxena .Inhibition of Mild Steel Corrosion in Presence of Fatty Acid Imidazolines in Hydrochloric Acid[J].Protection of Metals,2008(1):91-98. |
| [10] | 樊国栋,葛君,柴玲玲.新型咪唑啉缓蚀剂的合成及性能评价[J].精细石油化工,2011(01):73-77. |
| [11] | 邵彤;徐家业;张群正 等.咪唑啉类化合物在盐酸中对A3钢的缓蚀性能[J].油田化学,2000,14(04):317-319. |
| [12] | 曹楚南.腐蚀电化学原理(第3版)[M].北京:化学工业出版社,2008:202-202. |
| [13] | Kissi M;Bouklah M;Hammouti B;Benkaddour M .Establishment of equivalent circuits from electrochemical impedance spectroscopy study of corrosion inhibition of steel by pyrazine in sulphuric acidic solution[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(12):4190-4197. |
| [14] | Tavakoli H;Shahrabi T;Hosseini M G.Synergistic effect on corrosion inhibition of copper by sodium dodecyl-benze-nesulponate (SDBS) and 2-mercaptobenzoxazole[J].Materials Chemistry and Physics,2008(109):281-286. |
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