对新一代锂离子电池,特别是动力型电池用微孔型聚合物电解质膜材料的制备方法以及几类典型的聚合物电解质膜的特点进行了归纳和总结;比较了这一领域里萃取法、倒相法和直接造孔法的技术与工艺特点;用材料在实际电池中的机械强度、吸液率、耐高温性能、导电性能和电化学窗口宽度等指标考察了3种主要类型--单相型、两相型和复合型微孔聚合物电解质的各自优势与缺点;对微孔聚合物电解质的研制前景和开发趋势进行了展望.
参考文献
| [1] | 陈芳,马晓燕,屈小红,黄韵,姚雪丽.锂离子电池凝胶聚合物电解质改性的研究现状[J].高分子通报,2006(10):70-75. |
| [2] | Chung N K;Kwon Y D;Kim D .Thermal,mechanical,swelling,and electrochemical properties of poly(vinylidene fluoride)-co-hexafluoropropylene/poly(ethylene glycol)hybridtype polymer electrolytes[J].Journal of Power Sources,2003,124:148. |
| [3] | Pu Wemua;He Xiangming;Wang Li et al.Preparation of PVDF-HFP mieroporous membrane for Li-ion batteries by phase inversion[J].Journal of Membrane Science,2006,272:11. |
| [4] | Boudin F;Andrieu X;Jehoulet C et al.Microporous PVDF gel for lithium-ion batteries[J].Journal of Power Sources,1999,81-82:804. |
| [5] | Zhang S S;Ervin M H;Xu K et al.Li-ion battery with poly (acrylonitrile-methyl methacrylate)-based microporous gel electrolyte[J].Solid State Ionics,2005,176:41. |
| [6] | 任旭梅,顾辉,陈立泉,吴锋,黄学杰.新型锂离子电池聚合物电解质的制备[J].高等学校化学学报,2002(07):1383-1385. |
| [7] | 胡拥军,陈白珍,李义兵,袁艳.增塑型锂离子电池聚合物电解质[J].化工进展,2006(02):163-166. |
| [8] | Wang Zhanliang;Tang Zhiyuan .Characterization of the polymer electrolyte based on the blend of poly(vinylidene fluoride-co-hexafluoropropylene)and poly(vinyl pyrrolidone)for lithium ion battery[J].Materials Chemistry and Physics,2003,82:16. |
| [9] | 袁艳,陈白珍,胡拥军.聚合物电解质P（VDF-HFP）/PVP的制备和性能研究[J].电池,2006(04):260-262. |
| [10] | 陈作锋,姜艳霞,庄全超,董全峰,王野,孙世刚.一种新型微孔聚合物电解质的制备与表征[J].科学通报,2005(07):638-642. |
| [11] | 胡拥军,陈白珍,袁艳,李义兵.直接挥发法制备无纺布增强型聚合物电解质[J].功能材料,2006(09):1401-1403,1407. |
| [12] | Zhang S S;Xu K;Foster D L et al.Microporous gel electrolyte Li-ion battery[J].Journal of Power Sources,2004,125:114. |
| [13] | Tian Zheng;He Xiaoming;Pu Weihua et al.Preparation of poly(acrylonitrile-butyl acrylate)gel electrolyte for lithiumion batteries[J].Electrochimica Acta,2006,52:688. |
| [14] | Xi Jingyu;Qiu Xinping;Li Jian et al.PVDF-PEO blends based mieroporous polymer electrolyte:Effect of PEO on pore configurations and ionic conductivity[J].Journal of Power Sources,2006,157:501. |
| [15] | Yeon-Bok Jeong;Dong-Won Kim .Effect of thickness of coating layer on polymer-coated separator on cycling performance of lithium-ion polymer cells[J].Journal of Power Sources,2004(2):256-262. |
| [16] | 唐定国,刘建红,其鲁,晨晖,慈云祥.无纺布支撑聚合物凝胶电解质锂离子电池[J].科学通报,2004(22):2290-2293. |
| [17] | Kim Heetak;Kim Kyoungbae;Kim Sunwook et al.Li-ion polymer battery based on phase-separated gel polymer electrolyte[J].Electrochimica Acta,2000,45:4001. |
| [18] | Tian Zheng;Pu Weihua;He Xiaoming et al.Preparation of a microporous polymer electrolyte based on poly(vinyl chloride)/poly(acrylonitrile-butyl acrylate)blend for Li-ion batteries[J].Electrochimica Acta,2007,52:3199. |
| [19] | Wang Zhanliang;Tang Zhiyuan .A novel polymer electrolete based on PMAML/PVDF-HFP blend[J].Electrochimica Acta,2004,49:1063. |
| [20] | Li Weili;Yuan Mingyong;Yang Muiie .Dual-phase polymer electrolyte with enhanced phase compatibility hased on Poly (MMA-g-PVC)/PMMA[J].European Polymer Journal,2006,42:1396. |
| [21] | 范丽珍,南策文,党智敏,施展.聚氧乙烯-改性蒙脱石复合材料电性能的研究[J].硅酸盐学报,2003(01):57-59,65. |
| [22] | Song J Y;Cheng C L;Wang Y Y et al.Microstructure of poly(vinylidene fluoride)-blend polymer eloetrolye and its effect on transport properties[J].Journal of the Electrochemical Society,2002,149(09):A1230. |
| [23] | 李芳,李康,孙岳明,张力.P（VdF-HFP）型聚合物电解质的结构和导电性研究[J].功能高分子学报,2004(02):251-255. |
| [24] | 庞明娟,唐定国,其鲁,晨晖.锂离子二次电池用PVDF-HFP/PAMA共混物基聚合物电解质膜的研制[J].高分子学报,2005(03):448-452. |
| [25] | He Xiangming;Shi Qiao;Zhou Xiao et al.In situ composite of nano SiO2-p(VDF-HFP)porous polymer electrolytes for Li-ion batteries[J].Electrochimica Acta,2005,51:1069. |
| [26] | 陈作锋,姜艳霞,庄全超,董全峰,孙世刚.MCM-41介孔分子筛掺杂的微孔型聚合物电解质的制备与表征[J].电化学,2005(02):162-166. |
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