欢迎登录材料期刊网

材料期刊网

高级检索

用二次熔融法制备了SrAl2O4∶Eu2+,Dy3+荧光粉掺杂低熔点硫磷酸盐的发光玻璃复合材料。采用DSC、透射光谱、XRD、发射光谱、SEM等测试手段对样品进行了表征。研究了熔制温度、熔制时间等因素对复合材料光学性能的影响。结果表明:熔制温度为700℃、熔制时间为30min的发光玻璃复合材料在365nm紫外光激发下,发射出峰值波长为514nm的黄绿光,保留了荧光粉的发光性能。

Low melting sulfophosphate glass/SrAl2O4: Eu2+,Dy3+ phosphor composites were prepared by two-step melting method.The samples were characterized by differential scanning calorimetry(DSC),transmittance spectra,X-ray diffractometry(XRD),emission spectra,scanning electron microscopy(SEM),etc.The effects of synthetic conditions(melting temperature,duration of reaction time) on luminescent properties of the composite samples were investigated.The experimental results show that the optimized composite(melting temperature 700℃,melting time 30min) emits strong yellow-green light when it is excited by 365 nm ultraviolet light,and maintains the luminescent properties of the phosphor.

参考文献

[1] Murayama;Yoshihiko et al.Phosphorescent phosphor[P].United States:5424006,5686022,1995-06-13.
[2] Rase Takashi et al.Long persistent phosphorescence phosphor[P].United States:5839718,1998-11-4.
[3] 郝庆隆;李鹏程 等.长余辉磷光体及其制备方法[P].中国:95109878.0,1997-03-05.
[4] 朱爱玲,廉世勋,李承志,张华京.绿色长余辉发光玻璃的合成和性质[J].光谱实验室,2003(01):23-27.
[5] 王蕊,马达,王雪涛,马雷.SrAl2O4:Eu2+,Dy3+长余辉发光玻璃的研制[J].沈阳化工学院学报,2008(02):137-140.
[6] Hiroyo Segawa;Satoshi Ogata;Naoto Hirosaki;Satoru Inoue;Tadashi Shimizu;Masataka Tansho;Shinobu Ohki;Kenzo Deguchi .Fabrication of glasses of dispersed yellow oxynitride phosphor for white light-emitting diodes[J].Optical materials,2010(2):170-175.
[7] 樊先平;乔旭升 等.一种应用于半导体照明的荧光粉/玻璃复合体及其制备方法[P].中国:200910154360.6,2010-06-09.
[8] 朱爱玲,廉世勋,李承志,毛向辉.用两种方法合成长余辉发光玻璃的对比研究[J].中国稀土学报,2002(06):625-629.
[9] Petru Pascuta;Gheorghe Borodi;Nicolaie Jumate;Ioan Vida-Simiti;Dan Viorel;Eugen Culea .The structural role of manganese ions in some zinc phosphate glasses and glass ceramics[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(2):479-483.
[10] Ning Da;Mingying Peng;Sebastian Krolikowski;LotharWondraczek .Intense red photoluminescence from Mn2+-doped(Na+;Zn2+)sulfophosphate glasses and glass ceramics as LEDconverters[J].Optics Express,2010,18(03):2549-2557.
[11] 杨云霞;徐志珍 等.SiO2玻璃涂层的碱土铝酸盐长余辉荧光粉及其制备方法[P].中国:01113200.0,2001-12-05.
[12] 孙鹏飞,王红英,鞠成,杨明家.两步法制备Eu,Dy掺杂硼硅酸盐玻璃及发光性能研究[J].佳木斯大学学报(自然科学版),2010(02):248-250.
[13] 林元华,张中太,陈清明,唐子龙,龚江宏.长余辉光致发光玻璃的制备及其性能研究[J].材料科学与工艺,2000(01):1-6.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%