阐述了氢溢流机理的基本概念,总结了氢在负载金属上的吸附位置和解离方式、氢在金属颗粒与炭材料间的扩散方式、氢在炭表面上的吸附位和解吸机理.指出了负载金属炭材料在储氢应用中的多元合金和表面官能团等研究方向.
参考文献
| [1] | W. Curtis Conner Jr.;John L. Falconer .Spillover in Heterogeneous Catalysis[J].Chemical Reviews,1995(3):759-788. |
| [2] | Farouq Ahmed;Md. Khorshed Alam;Ai Suzuki .Dynamics of Hydrogen Spillover on Pt/γ-Al2O3 Catalyst Surface: A Quantum Chemical Molecular Dynamics Study[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(35):15676-15683. |
| [3] | Farouq Ahmed;Md. Khorshed Alam;Ryuji Muira;Ai Suzuki;Hideyuki Tsuboi;Nozomu Hatakeyama;Akira Endou;Hiromitsu Takaba;Momoji Kubo;Akira Miyamoto .Adsorption and dissociation of molecular hydrogen on Pt/CeO_2 catalyst in the hydrogen spillover process: A quantum chemical molecular dynamics study[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2010(24):7643-7652. |
| [4] | Yingwei Li;Ralph T. Yang .Hydrogen Storage on Platinum Nanoparticles Doped on Superactivated Carbon[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(29):11086-11094. |
| [5] | Wang YH;Yang RT .Increased hydrogen spillover by gaseous impurity: The Benson-Boudart method for dispersion revisited[J].Journal of Catalysis,2008(1):198-201. |
| [6] | Zhao Wang;Frances H. Yang;Ralph T. Yang .Enhanced Hydrogen Spillover on Carbon Surfaces Modified by Oxygen Plasma[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(3):1601-1609. |
| [7] | Zhao Wang;Ralph T. Yang .Enhanced Hydrogen Storage on Pt-Doped Carbon by Plasma Reduction[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(13):5956-5963. |
| [8] | Anthony J.Lachawiec;Gongshin Qi;Ralph T.Yang .Hydrogen Storage in Nanostructured Carbons by Spillover:Bridge-Building Enhancement[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(24):11418-11424. |
| [9] | Yingwei Li;Ralph T.Yang .Hydrogen Storage in Metal-Organic Frameworks by Bridged Hydrogen Spillover[J].Journal of the American Chemical Society,2006(25):8136-8137. |
| [10] | Stuckert, N.R.;Wang, L.;Yang, R.T. .Characteristics of hydrogen storage by spillover on Pt-doped carbon and catalyst-bridged metal organic framework[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(14):11963-11971. |
| [11] | Wang, LF;Yang, RT .Hydrogen Storage on Carbon-Based Adsorbents and Storage at Ambient Temperature by Hydrogen Spillover[J].Catalysis Reviews. Science and Engineering,2010(4):411-461. |
| [12] | Saha, D;Deng, SG .Hydrogen Adsorption on Ordered Mesoporous Carbons Doped with Pd, Pt, Ni, and Ru[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(21):12550-12560. |
| [13] | Lifeng Wang;Frances H. Yang;Ralph T. Yang .Hydrogen Storage Properties of B- and N-Doped Microporous Carbon[J].AIChE Journal,2009(7):1823-1833. |
| [14] | Lifeng Wang;Ralph T. Yang .Hydrogen Storage Properties of N-Doped Microporous Carbon[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(52):21883-21888. |
| [15] | George M. Psofogiannakis;Theodore A. Steriotis;Athanassios B. Bourlinos .Enhanced hydrogen storage by spillover on metal-doped carbon foam: an experimental and computational study[J].Nanoscale,2011(3):933-936. |
| [16] | Roy Morrison S;赵壁英;刘英俊;卜乃瑜.表面化学物理[M].北京:北京大学出版社,1984:242. |
| [17] | 辛勤;罗孟飞.现代催化研究方法[M].北京:科学出版社,2009:5. |
| [18] | Irving Langmuir .The dissociation of hydrogen into atoms.Ⅲ.The mechanism of the reaction[J].Journal of the American Chemical Society,1916,38(06):1145. |
| [19] | Conrad H;Ertl G;Latta E E .Adsorption of hydrogen on palladium single crystal surfaces[J].Surface Science,1974,41(02):435. |
| [20] | Mitsui T.;Rose MK.;Fomin E.;Ogletree DF.;Salmeron M. .Dissociative hydrogen adsorption on palladium requires aggregates of three or more vacancies[J].Nature,2003(6933):705-707. |
| [21] | Mitsui T.;Rose MK.;Fomin E.;Ogletree DF.;Salmeron M. .Hydrogen adsorption and diffusion on Pd(111)[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2003(1):5-11. |
| [22] | Stephen Holloway .The active site for dissociative adsorption of H2:Was Langmuir right[J].Surface Science,2003,540:1. |
| [23] | Nuria Lopez;Zbigniew Lodziana;Francesc Illas;Miquel Salmeron .When Langmuir Is Too Simple: H_2 Dissociation on Pd(111) at High Coverage[J].Physical review letters,2004(14):146103.1-146103.4. |
| [24] | Roy Morrison S .Surface barrier effects in adsorption,illustrated by zinc oxide[J].Advances in Catalysis,1995,7:259. |
| [25] | Axel Gross;Arezoo Dianat .Hydrogen Dissociation Dynamics on Precovered Pd Surfaces: Langmuir is Still Right[J].Physical review letters,2007(20):206107.1-206107.4. |
| [26] | Farouq Ahmed;Md. Khorshed Alam;Ryuji Miura .Modeling of hydrogen vacancy for dissociative adsorption of H2 on Pd (111) surface by a quantum chemical molecular dynamics[J].Catalysis Today,2011(1):16-22. |
| [27] | Nelson B. ARBOLEDA Jr.;Hideaki KASAI;Wilson A. DINO;Hiroshi NAKANISHI .Potential Energy of H_2 Dissociation and Adsorption on Pt(111) Surface: First-Principles Calculation[J].Japanese journal of applied physics,2007(7a):4233-4237. |
| [28] | Durr M.;Hu Z.;Biedermann A.;Hofer U.;Heinz TF. .Real-space study of the pathway for dissociative adsorption of H-2 on Si(001) - art. no. 046104[J].Physical review letters,2002(4):6104-0. |
| [29] | Chen L;Pez G;Cooper AC;Cheng H .A mechanistic study of hydrogen spillover in MoO3 and carbon-based graphitic materials[J].Journal of Physics. Condensed Matter,2008(6):64223-1-64223-7-0. |
| [30] | George M. Psofogiannakis;George E. Froudakis .DFT Study of the Hydrogen Spillover Mechanism on Pt-Doped Graphite[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(33):14908-14915. |
| [31] | Fabing Su;Lu Lv;Fang Yin Lee .Thermally Reduced Ruthenium Nanoparticles as a Highly Active Heterogeneous Catalyst for Hydrogenation of Monoaromatics[J].Journal of the American Chemical Society,2007(46):14213-14223. |
| [32] | George S Tulevski;Matt B Myers;Mark S Hybertsen et al.Formation of catalytic metal-molecule contacts[J].Science,2005,309:591. |
| [33] | Rodriguez N M;Baker R T K .Interaction of hydrogen with metal sulfide catalysts- Direct observation of spillover[J].Journal of Catalysis,1993,140(02):287. |
| [34] | Batley G E;Ekstrom A;Johnson D A .Studies oft opochemicalheterogeneous catalysis 3.Catalysis of the reduction of metal oxides by hydrogen[J].Journal of Catalysis,1972,34(03):368. |
| [35] | George M Psofogiannakis;George E Froudakis .Fundamental studies and perceptions on the spillover mechanism for hydrogen storage[J].Chemical Communications,2011,47:7933. |
| [36] | Hornekaer L;Sljivancanin Z;Xu W;Otero R;Rauls E;Stensgaard I;Laegsgaard E;Hammer B;Besenbacher F .Metastable structures and recombination pathways for atomic hydrogen on the graphite (0001) surface[J].Physical review letters,2006(15):6104-1-6104-4-0. |
| [37] | Morisset S;Aguillon F;Sizun M;Sidis V .Quantum dynamics of H-2 formation on a graphite surface through the Langmuir Hinshelwood mechanism[J].The Journal of Chemical Physics,2004(13):6493-6501. |
| [38] | S.Morisset;F.Aguillon;M.Sizun;V.Sidis .Wave-packet study of H_2 formation on a graphite surface through the Langmuir-Hinshelwood mechanism[J].The Journal of Chemical Physics,2005(19):194702,1-8-0. |
| [39] | Rocco Mertinazzo;Gian Franco Tantardini .Quantum study of Eley-Rideal reaction and collision induced desorption of hydrogen atoms on a graphite surface.Ⅰ.H-chemisorbed case[J].Journal of Chemical Physics,2006,124(12):124702. |
| [40] | Rocco Mertinazzo;Gian Franco Tantardini .Quantum study of Eley-Rideal reaction and collision induced desorption of hydrogen atoms on a graphite surface.Ⅱ.H-physisorbed case[J].Journal of Chemical Physics,2006,124(12):124703. |
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