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轧制了不同Al含量(0、2%、4%)的304不锈钢,利用OM、XRD、EPMA研究其轧制态显微组织,并对其力学性能及耐腐蚀性进行研究.结果表明:随Al含量的增加,合金基体由单一的γ相转变为α+γ双相组织,Al元素分别以固溶和Al4C3沉淀相的形式分布在基体上,随Al含量增加,析出的Al4C3相增多.合金的强度随着Al含量的增加,先降低后增加,而伸长率逐渐降低.利用SEM分析合金的断口形貌表明,其断裂形式均为韧性断裂.合金腐蚀速率随着Al含量增加明显降低,含4 mass%Al304比304耐晶间腐蚀性能提高一倍以上.Al4C3相的析出减少了贫铬区及合金表面形成更为稳定的Al203钝化膜是其耐蚀性提高的主要因素.

参考文献

[1] 徐乐江.中国不锈钢市场与发展中的宝钢不锈钢事业[J].宝钢技术,2006(01):1-5.
[2] 张胜寒,贾伟,郭彦磊,冯玲.304不锈钢晶间腐蚀的研究[J].汽轮机技术,2011(03):236-238.
[3] Ramakrisnan V;Mcgurty J A;Jayarman N.Oxidation of high-aluminum austenitic stainless steels[J].Oxidation of Metals,1988(03):185-200.
[4] Mcgurtyj A .Austenitic iron alloys[P].US 4086085,1978.
[5] Pivin J C;Delaunay D;Roques-Carmes C et al.Oxidation mechanism of Fe-Ni-20-25Cr-5Al alloys-influence of small amounts of yttrium on oxidation kinetics and oxide adherence[J].Corrosion Science,1980,20(03):351-373.
[6] Prescott R;Graham M J .The formation of aluminum oxide scales on high-temperature alloys[J].Oxidation of Metals,1992,38(3-4):233-254.
[7] Teng Z K;Liu C T;Ghosh G et al.Effect of Al on the microstructure and ductility of NiAl-strengthened ferritic steels at room temperature[J].INTERMETALLICS,2010,18(08):1437-1443.
[8] Kondo, K.;Miwa, Y.;Okubo, N.;Kaji, Y.;Tsukada, T. .Development of corrosion-resistant improved Al-doped austenitic stainless steel[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2011(1/3):892-895.
[9] M.P. Brack;V. Yamamoto;M.L. Sanlella .The Development of Alumina-Forming Austenitic Stainless Steels for High-Temperature Structural Use[J].JOM,2008(7):12-18.
[10] 喇培清,李玉峰,刘闪光,申达,王鸿鼎.Al元素对316L不锈钢组织和室温力学性能的影响[J].钢铁,2010(05):71-75,87.
[11] 喇培清,李玉峰,刘闪光.316L不锈钢中添加Al后的抗腐蚀性能[J].材料保护,2010(12):62-64.
[12] Brady M P;Yamamoto Y;Santella M L et al.Composition,microstructure and water vapor effects on internal/external oxidation of aluminium-forming austenitic stainless steel[J].Oxidation of Metals,2009,72(5-6):311-333.
[13] 田村今男 .α-γ2相混合組織をもつFe-Cr-Ni合金の時効举動について[J].日本金属学会志,1976,40(04):353-360.
[14] Nilsson J O .Super duplex stainless steels[J].Materials Science and Technology,1992,8:685-700.
[15] 张宝宏.金属电化学腐蚀与防护[M].北京:化学工业出版社,2005:83.
[16] 肖纪美.不锈钢的金属学问题[M].北京:冶金工业出版社,2006:155.
[17] 顾学民.铍、碱土金属、硼、Al、镓分族[M].北京:科学出版社,1990:468-469.
[18] H. Asteman;M. Spiegel .A comparison of the oxidation behaviours of Al_2O_3 formers and Cr_2O_3 formers at 700 ℃ - Oxide solid solutions acting as a template for nucleation[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2008(6):1734-1743.
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