对传统和新发展的各种钛提取技术的基本原理、工艺特点及进展进行了回顾.介绍了目前国内外正在开发或改进的钛生产工艺,其中包括二氧化钛的直接电化学还原法、Armstrong(ITP)法、钙热还原法、金属氢化物还原法、四氯化钛熔盐电解还原钛、SOM法等,指出新工艺在工业应用中存在的问题.作者认为:由于传统的Kroll法生产成本高,限制了钛的应用,只有开发新的、连续化的生产工艺,才能从根本上达到降低生产成本的目的.
参考文献
| [1] | 王向东,徐彦儒.关于年产5000 t级海绵钛现代生产技术及装备产业化项目的推荐意见[J].钛工业进展,2001(04):1-3. |
| [2] | Kroll W J .[J].Trans Am Electrochem Socff,1940,78:35. |
| [3] | 欧阳全胜,赵中伟,祝永红.海绵钛生产工艺及其新进展[J].稀有金属与硬质合金,2004(02):47-52. |
| [4] | Kuang-Oscar Yu .[J].Rare Metal Materlals and Engineering,2006,35(z1):21. |
| [5] | Haarberg G M et al.[J].Journal of Applied Electrochemistry,1993,23:217. |
| [6] | 莫畏.钛冶金[M].北京:冶金工业出版社,1998:50. |
| [7] | Ryosuke O Suzuki .[J].Journal of Physics and Chemistry of Solids,2005,66:461. |
| [8] | Ryosuke O. Suzuki;Shinji Fukui .Reduction of TiO_2 in Molten CaCl_2 by Ca Deposited during CaO Electrolysis[J].Materials transactions,2004(5):1665-1671. |
| [9] | Ono K et al.[J].Journal of the Minerals,Metals & Materials Society,2002,54(02):56. |
| [10] | Technologies E H K .[OL].http://ms.ornl.gor/programs/energyeff/HVPM/Krafl-Titanium.pdf,2002-7. |
| [11] | Gerdemann S J .[J].Advances Materials ＆Process,2001,159(07):41. |
| [12] | Moxson VS et al.[J].Journal of the Minerals,Metals & Materials Society,2000,52(05):24. |
| [13] | Froes F H .[J].Journal of the Minerals,Metals & Materials Society,1998,50(09):41. |
| [14] | Paillere P.[A].France:Soc France Metail,1989:901. |
| [15] | Ginatta M V.[A].France:Soc France Metail,1989:753. |
| [16] | 杜继红,祁和述.Ti（Ⅳ）在氯化物熔体中的电化学还原[J].稀有金属材料与工程,1998(03):165-168. |
| [17] | Chen George Z et al.[J].Journal of the Electrochemical Society,2002,149(11):455. |
| [18] | Corby G Anderson et al.[J].Rare Metal Materlals and Engineering,2006,35(z1):127. |
| [19] | Alexander D T L et al.[J].Acta Materialia,2006,54:2933. |
| [20] | Meng Ma et al.[J].Journal of Alloys and Compounds,2006,420:37. |
| [21] | Chen G Z et al.[J].NATURE,2000,407:361. |
| [22] | Fray D J et al.[J].Journal of Materials Science and Technology,2004,20:295. |
| [23] | Katsutoshi Ono .Fundamental Aspects of Calciothermic Process to Produce Titanium[J].Materials transactions,2004(5):1660-1664. |
| [24] | Schwandt C et al.[J].Electrochimica Acta,2005,51:66. |
| [25] | Alexander D T L .[J].Acta Materialia,2006,54:2933. |
| [26] | Uday B. Pal;David E. Woolley;George B. Kenney .Emerging SOM technology for the green synthesis of metals from oxides[J].JOM,2001(10):32-35. |
| [27] | 现代HYSCO扩张拼焊板设备及生产[J].上海金属,2003(02):40. |
| [28] | 杜继红,奚正平,李晴宇,李争显,唐勇.电化学还原TiO2制备金属钛及反应过程的研究[J].稀有金属材料与工程,2006(07):1045-1049. |
| [29] | Du Jihong et al.[J].Transactions of Nonferrous Metals Society of China,2007,17:s514. |
| [30] | Li Qingyu et al.[J].Transactions of Nonferrous Metals Society of China,2007,17:560. |
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