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为了预测在固化度、温度和固化放热共同作用下,树脂体系的黏度随时间的变化,提出了一种确定反应性树脂体系黏度随时间变化关系的新方法.该方法从等温黏度一时间曲线和同化度一时间曲线出发,分别得到黏度一固化度关系和黏度-温度关系,从而将影响反应性流体黏度变化的两个主要因素温度和固化程度分离开来.基于反应性树脂体系的局部绝热假设,将反应性树脂体系的固化放热引入到黏度变化关系中,得到反应性树脂体系黏度在固化度、温度和固化放热共同作用下的黏度-时间关系.黏度预测值与用旋转黏度计测量值的黏度变化趋势具有高度的一致性,可以应用此方法实现对实际环境中考虑固化反应热效应的反应性树脂体系黏度的预测.

参考文献

[1] Park J,Kang M K.A numerical simulation of the resin film infusion process[J].Composite Structures,2003,60(4):431-437.
[2] Ivankovic M,lncarnato L.Kenny J M,et al.Curing kinetics and chemorheology of epoxy/anhydride system[J].Journal of Applied Polymer Science,2003,90(11):3012-3019.
[3] 粱志勇.复合材料液体成型工艺技术基础研究[D].北京:北京航空航天大学,2000.
[4] 石凤,段跃新,梁志勇,等.RTM专用双马来酰亚胺树脂体系化学流变特性[J].复合材料学报,2006,23(1):56-61.Shi Feng,Duan Yuexin,Liang Zhiyong,et al.Rheological behavior of a bismaleimide resin system for RTM process[J].Acta Materiae Compositae Sinica,2006,23(1):56-61.
[5] 尹明仁.LCM工艺可视化模拟仿真平台的研究[D].北京:北京航空航天大学,2000.
[6] Kiuna N,LawrenceC J,Fontana Q P V,et al.A model for resin viscosity during cure in the resin transfer moulding process LJ].Composites Pan A,2002,33(11):1497-1503.
[7] Maazouz A,Dupuy J,Seytre G.Polyurethane and unsaturated polyester hybrid networks:Chemorheological and dielectric study for the resin transfer molding process(RTM)[J].Polymer Engineering & Science,2000,40(3):690-701.
[8] Hoes K.New set-up for measurement of permeability properties of fibrous reinforcements for RTM[J].Composites Part A,2002,33(7):959-969.
[9] 路遥,段跃新,粱志勇,等.钡酚醛树脂体系化学流变特性研究[J].复合材料学报,2002,19(5):33-37.Lu Yao,Duan Yuexin,Liang Zhiyong,et al.Rheological behaviours of barium-phenolic resin system for RTM process[J].Acta Materiae Compositae Sinica,2002,19(5):33-37.
[10] Judd N C W,Wright W W.Voids and their effects on the mechanical properties of composites-An appraisal[J].SAMPE Journal,1978(14):10-14.
[11] 董萌.RFI成型工艺用树脂膜的研究[D].西安:西北工业大学,2007.
[12] Kang M K,Jung J J.Analysis of resin transfer mounding process with controlled multiple gates resin injection[J].Composites Pan A,2000,31:407-422.
[13] Williams M L,Landel R F,Ferry J D.The temperature dependence of relaxation mechanisms in amorphous polymers and other glass forming liquids[J].J Am Chem Soc,1955,77:3701-3707.
[14] Vyazovkin S,Sbirrazzuoli N.Kinetic methods to study isothermal and nonisothermal epoxy-anhydride cure[J].Macromol Chem Phys,1999,200(10):2294-2303.
[15] Lee D S,Hen C D.A chemorheological model for the cure of unsaturated polyester resin[J].Polymer Engineering and Science,1987,27(13):955-963.
[16] Fontana Q P V.Viscosity:Thermal history treatment in resin transfer moulding process modeling[J].Composites Part A,1997,29A(1/2):153-158.
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