Nano-pore carbon aerogels were prepared by the sol-gel polymerization of resorcinol (1,3-dihydroxybenzene)(C6H4(OH)2) with formaldehyde (HCHO) in a slightly basic aqueous solution, followed by super-critical drying under liquid carbon dioxide as super-critical media and carbonization at 700 ℃ under N2 gas atmosphere. The key of the work is to fabricate carbon aerogels with controllable nano-pore structure, which means extremely high surface area and sharp pore size distribution. Aiming to investigate the effects of preparation conditions on the gelation process, the bulk density, and the physical and chemical structure of the resultant carbon aerogels, the molar ratio of R/C (resorcinol to catalyst) and the amount of distilled water were varied, consequently two different sets of samples, with series of R/C ratio and RF/W (Resorcinol-Formaldehyde to water, or the content of reactant) ratio, were prepared. The result of N2 adsorption/desorption experiment at 77 K shows that the pore sizes decreasing from 11.4 down tO2.2 nm with the increasing of the molar ratio of R/C from 100 to 400, and/or, the pore sizes decreasing from 3.8 down to 1.6 nm with the increasing of reactant content from 0.4 to 0.6.
参考文献
| [1] | Pekala R W;Alviso C T;Kong F M et al.[J].J Non-Cry Solids,1992,145:90. |
| [2] | Pekala R W .[P].US 4997804,1991-3-5. |
| [3] | Li W C;Guo S C .Letters to the Editor[J].Carbon,2000,38:1499. |
| [4] | Czakkel O;Marthi K;Geissler E.[J].Mic Meso Materials,2005:124. |
| [5] | Berthon-Fabry S;Langohr D;Achard P;Charrier D;Djurado D;Ehrburger-Dolle F .Anisotropic high-surface-area carbon aerogels[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(0):136-144. |
| [6] | Tamon H.;Araki T.;Okazaki M.;Ishizaka H. .Control of mesoporous structure of organic and carbon aerogels[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(9):1257-1262. |
| [7] | Tamon H;Ishizaka H;Yamamoto T et al.[J].Carbon,1999,37:2049. |
| [8] | Reynolds G A M;Fung A W P;Wang Z H et al.[J].J Non-Cry Solids,1995,188:27. |
| [9] | Feng Y N;Miao L;Cao Y G et al.[J].Adv Mater Res,2006,11-12:19. |
| [10] | Yamashita Y;Ouchi K .[J].Carbon,2000,38:1520. |
| [11] | Sing K S W;Everett D H;Haul R A W et al.[J].Pure and Applied Chemistry,1985,57:603. |
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