EVOLUTION OF THE ELECTROCHEMICAL CHARACTERISTICS DURING PITTING CORROSION OF PURE ALUMINUM IN SODIUM CHLORIDE SOLUTION

金属学报(英文版), 2005, 18(4): 525-532.

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Department of Chemistry, Zhejiang University, Hangzhou 310027, China

2.Department of Chemistry, Zhejiang University, Hangzhou 310027, China;Department of Chemistry, Ningxia University, Yinchuan 750021, China

3.Department of Chemistry, Zhejiang University, Hangzhou 310027, China

4.Department of Chemistry, Ningxia University, Yinchuan 750021, China

5.Department of Chemistry, Zhejiang University, Hangzhou 310027, China;State Key Laboratory for Gorrosion and Protection of Metals, Institute of Metal Research, The Chinese Academy of Sciences,Shenyang 110016,China

6.Department of Chemistry, Zhejiang University, Hangzhou 310027, China;State Key Laboratory for Gorrosion and Protection of Metals, Institute of Metal Research, The Chinese Academy of Sciences,Shenyang 110016,China

基金项目: 宁夏自然科学基金(200420) 国家重点基础研究发展计划(973计划)(G19990650) 国家自然科学基金(20203015)

EVOLUTION OF THE ELECTROCHEMICAL CHARACTERISTICS DURING PITTING CORROSION OF PURE ALUMINUM IN SODIUM CHLORIDE SOLUTION

Keywords： pure aluminum

The corrosion behavior of pure aluminum in neutral 3.0% (mass fraction) sodium chloride (NaCl) solution has been studied using electrochemical impedance spectroscopy (ELS) measurement in conjunction with the scanning electron microscopy (SEM) technique. EIS information on the evolution of pitting corrosion over a period of 15 days has been obtained and analyzed with equivalent circuit technique. The results shown that, during the ensemble constant immersion time, two time constants involved, the high frequency one originated from the protective layer on the corroding surface while the low frequency one from the diffusion process or the corrosion reaction and so on. And there existed a period for oxide film to growth and thickening prior to the commencement of the attacking of chloride ions to the substrate. Meanwhile, good relationship between EIS and the material corrosion type/severity has been obtained, which has been interpreted according to the characteristics of corrosion process such as auto acceleration of pitting corrosion and the protection of local anodic reaction to the area around them.

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EVOLUTION OF THE ELECTROCHEMICAL CHARACTERISTICS DURING PITTING CORROSION OF PURE ALUMINUM IN SODIUM CHLORIDE SOLUTION

参考文献