有机/无机杂化钙钛矿(C4H9NH3)2ZnCl4的制备与表征

功能材料, 2005, 36(8): 1217-1219.

1.浙江大学,高分子科学与工程学系,硅材料国家重点实验室,浙江,杭州,310027

2.浙江大学,高分子科学与工程学系,硅材料国家重点实验室,浙江,杭州,310027

3.浙江大学,高分子科学与工程学系,硅材料国家重点实验室,浙江,杭州,310027

4.香港科技大学,化学系,香港

基金项目: 国家自然科学基金(50225312,50433020) 香港研究资助局资助项目(50318001) 国家自然科学基金

Preparation and characterization of a novel organic-inorganic hybrid perovskite (C4H9NH3)2ZnCl4

合成了新型的有机/无机杂化钙钛矿(C4H9NH3)2ZnCl4,采用元素分析、红外光谱和X射线衍射对其结构进行了表征,结果表明这种材料具有规则的层状结构,有序性高,热分析结果表明(C4H9NH3)2ZnCl4在170℃的高温处存在一个固-固相转变.

[1]	Mitzi D B;Chondroudis K;Kagan C R.[J].IBM Journal of Research and Development,2001(01):29.
[2]	Kagan C R;Mitzi D B;Dimitrakopoulos C.[J].SCIENCE,1999:945.
[3]	Lee KW.;Lee CE. .Magnetic resonance study of the two-dimensional spin diffusion in the Heisenberg paramaget (C18H37NH3)(2)MnCl4[J].Solid State Communications,2003(6):343-346.
[4]	Barma S;Venkataraman N V;Vasudevan S.[J].Journal of Physical Chemistry B,2003:1875.
[5]	Xu Z;Mitzi D B.[J].Dimitrakopoulos C Inorg Chem:2031.
[6]	Cheng Z Y;Gao B X;Pang M L et al.[J].Chemistry of Materials,2003,15:4705.
[7]	Cheng ZY.;Wang Z.;Xing RB.;Han YC.;Lin J. .Patterning and photolumine scent properties of perovskite-type organic/inorganic hybrid luminescent films by soft lithography[J].Chemical Physics Letters,2003(3-4):481-486.
[8]	Venkataraman N V;Bhagyalakshmi S;Vasudevan S.[J].Chemical Physics and Physical Chemistry,2002(04):4533.
[9]	Venkataraman NV.;Barman S.;Vasudevan S.;Seshadri R. .Structural analysis of alkyl chain conformation in the layered organic-inorganic hybrids (CnH2n+1NH3)(2)PbI4 (n=12,16,18) by IR spectroscopy[J].Chemical Physics Letters,2002(1/2):139-143.
[10]	Mitzi D B.[J].CHEMISTRY OF MATERIALS,1996(08):791.
[11]	刘崭,石高全,陈凤恩,马明明.正十二烷基胺支撑的四碘化锡层状半导体材料的研究[J].无机化学学报,2003(11):1185-1190.

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