为了弄清膦酸自组装液的溶剂含水量对自组装膜性能的影响,分别以无水乙醇及其与不同含量去离子水的混合液为溶剂配制了十四烷基膦酸自组装液,通过浸泡法在氧化430不锈钢表面制备自组装膜.利用接触角测试、极化曲线、电化学交流阻抗及扫描电镜(SEM)研究了不同溶剂条件下十四烷基膦酸自组装膜的耐点蚀性能.结果表明:随自组装时间延长,膦酸自组装膜覆盖度增大,接触角增加,自组装6h时得到的自组装膜最致密,接触角最大；溶剂中水有利于形成更致密的自组装膜,随着溶剂含水量增加,膜的耐点蚀能力增强.
参考文献
| [1] | 何业东;齐慧滨.材料腐蚀与防护概论(第1版)[M].北京:机械工业出版社,2009:95-102. |
| [2] | 陈泽民,路品,邢海燕.铝材表面的自组装成膜新工艺[J].材料保护,2011(01):58-59,66. |
| [3] | 郭增昌,王云芳,王汝敏.铝合金表面自组装膜层的表征及耐蚀性研究[J].材料保护,2007(07):1-4. |
| [4] | 杨程,成波,滕乐金,王锦鹏.金-烷基硫醇的自组装及其聚合物基复合材料的介电性能[J].材料工程,2010(05):34-37. |
| [5] | Stratman M;Volmer M;Reyeders B .Anbindungs-verhalten organischer monomere auf eisenoberfl chenund korrosion der durch die anbindung chemisch modifizierten oberfl chen[J].Werkstoffe und Korrosion(Materials and Corrosion),1991,42(01):19-34. |
| [6] | Kunitsugu Aramaki;Tadashi Shimura .Self-assembled monolayers of carboxylate ions on passivated iron for preventing passive film breakdown[J].Corrosion Science,2004(2):313-328. |
| [7] | Felhosi I;Telegdi J;Palinkas G et al.Kinetics of selfassembled layer formation on iron[J].Elctrochimica Acta,2002,47(13):2335-2340. |
| [8] | Harm U.;Burgler R.;Furbeth W.;Mangold KM.;Juttner K. .Novel protective coatings for steel based on a combination of self-assembled monolayers and conducting polymers[J].Macromolecular symposia,2002(0):65-75. |
| [9] | A. Paszternak;I. Felhosi;Z. Paszti;E. Kuzmann;A. Vertes;E. Kalman;L. Nyikos .Surface analytical characterization of passive iron surface modified by alkyl-phosphonic acid layers[J].Electrochimica Acta,2010(3):804-812. |
| [10] | Tadashi Shimura;Kunitsugu Aramaki .Self-assembled monolayers of p-toluene and p-hydroxymethylbenzene moieties adsorbed on iron by the formation of covalent bonds between carbon and iron atoms for protection of iron from corrosion[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(3):1378-1393. |
| [11] | 吴岭 .铂纳米粒子的制备及其在铁电极表面自组装的研究[D].山东大学,2007. |
| [12] | Gouzman I;Dubey M;Carolus MD;Schwartz J;Bernasek SL .Monolayer vs. multilayer self-assembled alkylphosphonate films: X-ray photoelectron spectroscopy studies[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2006(4):773-781. |
| [13] | Al-Khaldi, T.A.;Lyon, S.B. .The effect of interfacial chemistry on coating adhesion and performance: A mechanistic study using aminobutylphosphonic acid[J].Progress in Organic Coatings: An International Review Journal,2012(4):449-455. |
| [14] | Hamoudi H;Dablemont C;Disorder V A E .Solvent Effects and Substitutional Self-Assembly of Alkane Dithiols from Alkane Thiol SAMs[J].Surface Science,2011,605:116-120. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%