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采用热力学平衡计算方法作出Ni-Cr-Mo 三元相图,并据此对实际Ni 基高温合金进行了σ相的析出预测。通过与Inconel_(713)C 合金的试验结果对比,证明此法可以用于不含Co 的Ni 基高温合金的σ相控制。

For a free-cobalt Ni-base alloy,it is considered that thematrix is composed of Ni,Cr,Mo and Al,and the σ-phase is composed of Ni,Cr and Mo.Power series model was chosen to express the free energy.Bytreating experimental diagram with data optimum programme

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