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采用机械共混法制备了淀粉/丙烯酸钠(NaAA)/氯丁橡胶(CR)吸水复合材料,考察了去离子水和3.5%(质量分数)NaCl溶液两种吸水介质对其力学性能和吸水性能的影响,并且观察了复合材料吸水前后的微观形貌。结果表明浸水后,随吸水量的增加,材料力学性能的降低;复合材料在盐溶液中的吸水率远小于在去离子水中的吸水率;在反复使用过程中,能够很好地保持其原有的吸水性能,具有优异的反复使用性能;通过扫描电子显微镜(SEM)观察了复合材料吸水前后的微观形态结构,吸水组分聚NaAA颗粒吸水干燥后表面发生褶皱。

Stacrh/NaAA/CR water-absorbent composites were prepared by blending polychloroprene with starch, NaAA and vulcanizing agents. The effects of the different swelling mediums on mechanical properties and water absorbent properties of stacrh/NaAA/CR water-absorbent composites were investigated in deionized water and NaCl solution by changing the swelling medium. And the morphology of the composites before and after water absorption was observed by the scanning electron microscopy (SEM). The results show that after water absorption, mechanical properties of the composites reduced with the increase in water absorbing capaci- ty. The water swelling ratios in deionized water were higher than those in NaCl solution. The composites which have excellent repeatedly used performance can maintain their original water absorbent properties by repeated used. The structure of the NaAA particles changed greatly before and after water absorption. NaAA was the main water absorbing component.

参考文献

[1] Liu CS;Ding JP;Zhou L;Chen SH .Mechanical properties, water-swelling behavior, and morphology of water-swellable rubber prepared using crosslinked sodium polyacrylate[J].Journal of Applied Polymer Science,2006(2):1489-1496.
[2] 周文英,齐署华,安群力,王彩凤,袁江龙,郭建.吸水膨胀橡胶研究进展[J].合成橡胶工业,2007(01):68-72.
[3] 刘柏贤;潘介子.高吸水性(膨胀)树脂在建筑工程上应用[J].化学建材,1992(05):188-189.
[4] 李秀辉,吴江渝,杨鹏,郭三维.基于SAP吸水膨胀橡胶的耐温耐盐性能[J].材料工程,2010(04):33-35,41.
[5] Sung-Seen Choi;Sung-Ho Ha .Water swelling behaviors of silica-reinforced NBR composites in deionized water and salt solution[J].Journal of industrial and engineering chemistry,2010(2):238-242.
[6] Choi S S;Ha S H .Influence of the swelling temperature and acrylonitrile content of NBR on the water swelling be- haviors of silica-filled NBR vuleanizates[J].Journal of In- dustrial and Engineering Chemistry,2009,15:167-170.
[7] 刘岚,向洁,罗远芳,贾德民.吸水膨胀橡胶的研究进展[J].高分子通报,2006(09):23-29.
[8] Flory P J.Principles of polymer chemistry[M].Ithaca,New York:Cornell University Press,1953:576-584.
[9] Omidian H.;Sammes PG.;Meldrum I.;Hashemi SA. .A model for the swelling of superabsorbent polymers[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(26):6697-6704.
[10] 梁桂花,张立群,冯予星,吴友平.淀粉/SBR复合材料的吸水性对力学性能的影响[J].特种橡胶制品,2007(05):1-4.
[11] Wang GJ.;Chen XF.;Li M. .Preparation and water-absorbent properties of a water-swellable rubber[J].Journal of Applied Polymer Science,1998(8):1219-1225.
[12] Shuai-Shuai Song;Hong-Bin Qi;You-Ping Wu .Preparation and properties of water-absorbent composites of chloroprene rubber, starch, and sodium acrylate[J].Polymers for advanced technologies,2011(12):1778-1785.
[13] 计臣;宋帅帅;吴友平 .NaAA的用量对淀粉、NaAA、CR吸水复合材料的结构和性能的影响[J].特种橡胶制品,20t1,32(02):1-5.
[14] Ji C;Song S S;Zhang L Q et al.The role of dicumyl peroxide in the preparation of ehloroprene rubber/ starch/sodium acrylate water-swellable composites[J].Carbohydrate Polymers,2011,86(02):581-586.
[15] Mahdavinia GR;Pourjavadi A;Hosseinzadeh H;Zohuriaan MJ .Modified chitosan 4. Superabsorbent hydrogels from poly(acrylic acid-co-acrylamide) grafted chitosan with salt- and pH-responsiveness properties[J].European Polymer Journal,2004(7):1399-1407.
[16] 范力仁,徐志良,沈上越.非金属矿物/高分子吸水保水复合材料研究进展[J].功能材料,2005(12):1827-1830,1836.
[17] 沈上越,夏开胜,范力仁,舒小伟.煅烧高岭土/PAA-AM高吸水保水复合材料的合成与性能研究[J].功能材料,2007(01):154-156,160.
[18] 王志成,平琳,刘玲.交联聚丙烯酸钠颗粒度对氯丁橡胶吸水膨胀率的影响[J].新型建筑材料,2005(04):41-42.
[19] H. Omidian;S.A. Hashemi;P.G. Sammes;I. Meldrum .Modified acrylic-based superabsorbent polymers (dependence on particle size and salinity)[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(7):1753-1761.
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