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采用放电等离子烧结法(SPS)在400℃、420℃、440℃的烧结温度下制备了n型Bi2Te3块体材料,利用X射线衍射对块体材料进行了物相分析,在300~500K的温度范围内分别测量了块体材料的塞贝克系数α、电导率σ以及热导率K,利用MSP(Modified Small Punch)小样品试验法对块体材料进行了力学性能分析.结果表明:400℃烧结材料的热电性能优值ZT具有最大值,约为O.79;块体材料在440℃时具有最大的MSP断裂强度,约为119.5MPa,表明了MSP试验法是评价小尺寸陶瓷材料力学性能方便、可靠的有效方法.

参考文献

[1] Hoffert MI;Caldeira K;Benford G;Criswell DR;Green C;Herzog H;Jain AK;Kheshgi HS;Lackner KS;Lewis JS;Lightfoot HD;Manheimer W;Mankins JC;Mauel ME;Perkins LJ;Schlesinger ME;Volk T;Wigley TM .Advanced technology paths to global climate stability: energy for a greenhouse planet.[J].Science,2002(5595):981-987.
[2] DiSalvo F J .Thermoelectric cooling and power generation[J].Science,1999,285(5428):703-706.
[3] 曾令可,漆小玲,王慧,刘艳春.氧化物热电材料热导率的研究[J].硅酸盐通报,2009(03):525-530.
[4] 赵丽荣,宋英,刘洪权,王福平.Ca3Co4O9基氧化物热电材料研究进展[J].硅酸盐通报,2007(05):948-952,984.
[5] Dutta S;Shubha V;Ramesh T G et al.Thermal and electronic properties of Bi1-χSbχ alloys[J].Journal of Alloys and Compounds,2009,467(01):305-309.
[6] Yixin Zhao;Jeffrey S. Dyck;Brett M. Hernandez .Improving Thermoelectric Properties of Chemically Synthesized Bi2Te3-Based Nanocrystals by Annealing[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(26):11607-11613.
[7] 毛顺杰,栾伟玲,黄琥,涂善东,郭景坤.氧化物热电材料的研究现状与应用[J].硅酸盐通报,2005(03):59-63,110.
[8] Yan, X.;Poudel, B.;Ma, Y.;Liu, W.S.;Joshi, G.;Wang, H.;Lan, Y.;Wang, D.;Chen, G.;Ren, Z.F. .Experimental studies on anisotropic thermoelectric properties and structures of n-type Bi_2Te_(2.7)Se_(0.3)[J].Nano letters,2010(9):3373-3378.
[9] M. Zakeri;M. Allahkarami;Gh. Kavei;A. Khanmohammadian;M. R. Rahimipour .Synthesis of nanocrystalline Bi{sub}2Te{sub}3 via mechanical alloying[J].Journal of Materials Processing Technology,2009(1):96-101.
[10] Zhi Xiong;Wan Jiang;Ying Shi .Evaluation of High-temperature Strength of Mo/PSZ Composites by Modified Small Punch Tests[J].Materials transactions,2005(3):631-636.
[11] Schultz J M;Mchugh J P;Tiller W A .Effects of heavy deformation and annealing on the electrical properties of Bi2Te3[J].Journal of Applied Physics,1962,33:2443.
[12] Ruiz CM;Saucedo E;Martinez O;Bermudez V .Hexagonal CdTe-Like rods prompted from Bi2Te3 droplets[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(15):5588-5591.
[13] Xu X C;Wang C F;Yao Q et al.Preparation of Bi2Te3-polyaniline heterostructured nanorods by two-step electrochemical depositions[J].Journal of Inorganic Materials,2006,21(06):1482-1486.
[14] Rice R W;Freiman S W .Grain-size dependence of fracture energy in ceramics:Ⅱ,A model for noncubic materials[J].Journal of the American Ceramic Society,1981,64(06):350-354.
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