欢迎登录材料期刊网

材料期刊网

高级检索

以SiH4和H2作为反应气体,采用HWCVD的方法分别在石英玻璃、AZO、Si(100)和Si(111)衬底上制备了多晶硅薄膜。利用X射线衍射(XRD),拉曼(Raman)光谱和傅里叶红外(FT-IR)吸收光谱研究了不同衬底对多晶硅薄膜的择优取向、晶化率和应力的影响,用SEM观察了多晶硅薄膜的表面形貌。研究发现在4种衬底上生长的多晶硅薄膜均为(111)择优取向。单晶硅片对多晶硅薄膜有很强的诱导作用,并且Si(111)的诱导作用优于Si(100)的诱导作用。AZO对多晶硅薄膜生长也有一定的诱导作用。通过计算薄膜晶态比,得到除以石英为衬底的样品外,其它3种样品的晶态比均在90%以上,尤其以单晶硅片为衬底的样品更高。石英玻璃、AZO和Si(100)上生长的多晶硅薄膜中均存在压应力。

Poly-crystalline silicon thin films were prepared on quartz glass,AZO,Si(100) and Si(111) substrates using SiH4 and H2 by hot wire chemical vapor deposition(HWCVD).Crystalline fraction,orientation and stress in the films deposited on different substrates were characterized by XRD,Raman spectrum and FT-IR.Surface morphology was observed by SEM.The results show that all the samples are(111) oriented.Si substrates can promote the crystallization of the films deposited on them,and Si(111) substrate has better induction effect than Si(100) substrate.AZO which is(002) oriented also shows induction effect.Raman spectra are fitted and crystalline fraction for all the films are calculated.The result shows that except the film deposited on quartz glass,all the other samples have crystalline fraction above 90%,with especially higher ones for films on Si substrates.There exist compressive stress in the samples except the film deposited on Si(111).

参考文献

[1] 唐正霞,沈鸿烈,鲁林峰,黄海宾,蔡红,沈剑沧.氧化铝膜对铝诱导制备多晶硅薄膜的影响[J].真空科学与技术学报,2010(01):38-42.
[2] 唐正霞,沈鸿烈,解尧,鲁林峰,江枫,沈剑沧.100μm大晶粒多晶硅薄膜的铝诱导法制备[J].功能材料,2010(03):453-456.
[3] 夏冬林,王慧芳,石正忠,张兴良,李蔚.电场辅助铝诱导晶化非晶硅薄膜[J].人工晶体学报,2010(04):862-866,871.
[4] 柴展,张贵锋,王赛,侯晓多.热丝法制备多晶硅薄膜晶体取向及形态的研究[J].真空科学与技术学报,2007(01):76-79.
[5] 黄创君,林璇英,林揆训,余楚迎,姚若河.低温制备高质量多晶硅薄膜技术及其应用[J].功能材料,2001(06):561-563.
[6] 谷锦华,周玉琴,朱美芳,李国华,丁琨,周炳卿,刘丰珍,刘金龙,张群芳.低温制备微晶硅薄膜生长机制的研究[J].物理学报,2005(04):1890-1894.
[7] Mason MS.;Chen CM.;Atwater HA. .Hot-wire chemical vapor deposition for grained polycrystalline epitaxial silicon growth on large-silicon templates[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):54-57.
[8] Rath JK. .Low temperature polycrystalline silicon: a review on deposition, physical properties and solar cell applications [Review][J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(4):431-487.
[9] Paillard V.;Laguna MA.;Temple-Boyer P.;Caussat B.;Couderc JP.;de Mauduit B.;Puech P. .Resonant Raman scattering in polycrystalline silicon thin films[J].Applied physics letters,1998(12):1718-1720.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%