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对于钛合金化铝镇静钢,热力学计算结果显示,稳定的脱氧产物为Al2O3,Al2TiO5只有在钢中铝的质量分数低于0.008%后才会形成.通过对Ti-IF钢实际冶炼过程中的取样分析发现:加入钛铁后,钢中会出现不稳定的Al-Ti复合氧化物,可能是钛铁中的钛氧化物与钢中铝逐渐反应而形成的产物;浇铸过程中,中间包覆盖剂中SiO2等可还原性氧化物含量比较高时,在钢-渣界面处铝的损失非常严重,因此在靠近钢液侧就会产生局部富钛区域,从而满足生成Al2TiO5或者Ti3O5的热力学条件,在湍流运动的条件下,生成的钛氧化物很容易被卷入钢液内部.

参考文献

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