CdSe纳米晶薄膜的制备与特性研究

人工晶体学报, 2013, 42(7): 1376-1379.

CdSe纳米晶薄膜的制备与特性研究

曾体贤 ^1, , 刘其娅 ^2, , 陈太红 ^3, , 谌家军 ^4,

1.西华师范大学物理与电子信息学院,南充637009

2.西华师范大学物理与电子信息学院,南充637009

3.西华师范大学物理与电子信息学院,南充637009

4.西华师范大学物理与电子信息学院,南充637009

基金项目: 四川省非金属复合与功能材料重点实验室开放课题(12zxfk15) 南充市科技支撑计划(402614) 四川省教育厅重点项目(01ZB089)

关键词： CdSe薄膜 , 热蒸发 , 透过率 , 禁带宽度

Preparation and Characterization of CdSe Nanocrystalline Films

ZENG Ti-xian ^1, , LIU Qi-ya ^2, , CHEN Tai-hong ^3, , CHEN Jia-jun ^4,

1.西华师范大学物理与电子信息学院,南充637009

2.西华师范大学物理与电子信息学院,南充637009

3.西华师范大学物理与电子信息学院,南充637009

4.西华师范大学物理与电子信息学院,南充637009

Keywords： CdSe film , thermal evaporation , transmittance , band gap

采用真空热蒸发技术,在光学玻璃基片上生长出排列整齐、高质量的CdSe纳米晶薄膜.通过X射线衍射(XRD)、X射线光电子能谱分析(XPS)、扫描电镜(SEM)、傅里叶红外光谱(IR)等进行表征.结果表明,薄膜结晶性能较好,纳米晶颗粒约为40 ～70 nm,呈半月状,排列整齐；化学元素配比为49.4∶50.6,稍微富Se;红外透过率高,禁带宽度为1.89 eV,高于块状的CdSe晶体(1.70 eV).

参考文献

[1]	Lin YW;Tseng WL;Chang HT .Using a layer-by-layer assembly technique to fabricate multicolored-light-emitting films of CdSe@CdS and CdTe quantum dots[J].Advanced Materials,2006(11):1381-1386.
[2]	Dickerson BD;Irving DM;Herz E;Claus RO;Spillman WB;Meissner KE .Synthesis kinetics of CdSe quantum dots in trioctylphosphine oxide and in stearic acid[J].Applied physics letters,2005(17):1915-1-1915-3-0.
[3]	K.R. Murali;K. Srinivasan;D.C. Trivedi .Vacuum evaporated CdSe thin films and their characteristics[J].Materials Letters,2005(1):15-18.
[4]	Eich D.;Ortner K.;Kilian L.;Becker R.;Landwehr G.;Fink R. Umbach E.;Hubner D. .Photoemission investigation of MBE-grown HgSe/CdSe heterostructures[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2000(1/4):12-16.
[5]	Shen CM.;Li HL.;Zhang XG. .Effect of pH on the electrochemical deposition of cadmium selenide nanocrystal films[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2001(3):265-270.
[6]	Nemec P;Simurda M;Nemec I;Sprinzl D;Formanek P;Maly P .Highly luminescent CdSe nanocrystalline films prepared by chemical bath deposition[J].Journal of Crystal Growth,2006(1):78-86.
[7]	T.X. Zeng;B.J. Zhao;S.F. Zhu .Thermodynamic analysis of the sublimation process in cadmium selenide[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1/2):170-172.
[8]	黄平,李婧,梁建,赵君芙,马淑芳,许并社.CdSe薄膜的制备及性能表征[J].人工晶体学报,2011(01):60-65.
[9]	曾体贤,赵北君,朱世富,何知宇,卢大洲,陈宝军,唐世红.红外非线性光学晶体CdSe生长与性能表征[J].人工晶体学报,2009(02):326-329,345.
[10]	Tixian Zeng;Beijun Zhao;Shifu Zhu;Zhiyu He;Baojun Chen;Zhaoyi Tan .Optimizing the growth procedures for CdSe crystal by thermal analysis techniques[J].Journal of Crystal Growth,2011(1):15-19.

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