微型可充锂锰电池具有很广阔的应用前景.讨论了微型可充锂锰电池所用正极材料的结构、合成方法、电化学性能.不同晶型的纯MnO2材料的可充性都比较差,对MnO2材料进行改性得到的复合二氧化锰(CDMO)可显著改善电池的循环性和稳定性.掺杂铋元素后所得到的CDMO可达到微型蓄电池的性能要求.
参考文献
| [1] | Abou-El-Sherbini Kh S .Structure investigation and electrochemical behavior of γ-MnO2 synthesized from three-dimensional framework and layered structures[J].Journal of Solid State Chemistry,2002,166:375. |
| [2] | Pistois G;Antonini A;Zane D et al.Synthesis of Mn spinels from different polymorphs of MnO2[J].Journal of Power Sources,1995,56:37. |
| [3] | Chambre Y;Pannetier J .Structural and electrochemical properties of the proton/γ-MnO2 system[J].Journal of Solid State Chemistry,1995,23(01) |
| [4] | NOHMA T;Saito T;Furukawa N .Manganese oxides for a lithium secondary battery-composite dimensional manganese oxide ( CDMO)[J].Journal of Power Sources,1989,26:389. |
| [5] | Kim HyungSun;Kim HyunJoong;Cho WonIl et al.Discharge characteristics of chemically prepared MnO2 and electrolytic MnO2 in non-aqueous electrolytes[J].Journal of Power Sources,2002,112:660. |
| [6] | Park M S;Yoon W Y .Characteristics of a Li/MnO2 battery using a lithium powder anode at high-rate discharge[J].Journal of Power Sources,2003,114:237. |
| [7] | NOHMA T;Yamamoto Y;Nishio K et al.Lithium-containing manganese dioxide (composite dimensional manganese oxide:CDMO) as positive material for a lithium secondary battery[J].Journal of Power Sources,1990,32:373. |
| [8] | NOHMA T;Yamamoto Y;Nakane I et al.Improvement of lithiumcontaining manganese dioxide (composite dimensional manganese oxide: CDMO) as positive material for lithium secondary batteries[J].Journal of Power Sources,1992,39:51. |
| [9] | Banov B;Momchilov A;Massot M et al.Lattice vibrations of materials for lithium rechargeable batteries V. local structure of Li0. 3 MnO2[J].Materials Science and Engineering,2003,B100:87. |
| [10] | Wu Fei;Wang Dequan;Zhang Lixia et al.Evaluation of composite-MnO2 as cathode material for rechargeable Li/MnO2 batteries[J].Journal of Power Sources,1995,54:367. |
| [11] | Yoshio Masaki;Nakamura Hiroyoshi;Xia Yongyao.Lithiated manganese dioxide,Li0.33 MnO2,as a 3V cathode for lithium batteries[J].Electrochimica Acta,1999(45):273. |
| [12] | Nakamura Hiroyoshi;Motooka Koichi;Noguchi Hideyuki et al.Lithiated manganese oxides as a cathode for lithium batteries[J].Journal of Power Sources,1999,81-82:632. |
| [13] | 刘金成,梁新波,周震涛.微型扣式Li-MnO2蓄电池的研制[J].电源技术,2004(03):153-155. |
| [14] | Julien C M;Massot M .Spectroscopic studies of the structural transitions in positive electrodes for lithium batteries[J].Journal of Power Sources,2003,119-121:743. |
| [15] | Yuan Liangjie;Li Zicheng;Sun Jutang et al.Synthesis and characterization of activated MnO2[J].Materials Letters,2003,57:1945. |
| [16] | Sugantha M;Ramakrishnan P A;Hermann A M et al.Nanostructured MnO2 for Li batteries[J].International Journal of Hydrogen Energy,2003,28:597. |
| [17] | Ghaemi M;Ghavami R K;KhosrariFard L et al.Electrolytic MnO2 via non-isothermal electrode heating: a promising approach for optimizing performances of electroactive materials[J].Journal of Power Sources,2004,125:256. |
| [18] | Dai Jinxiang;Li Sam F Y;Kok Siong Siow et al.Synthesis and characterization of the hollandite-type MnO2 as a cathode material in lithium batteries[J].Electrochimica Acta,2000,45:2211. |
| [19] | Johnson C S;Thackeray M M .Ammonia-and lithia-doped manganese dioxide for 3V lithium batteries[J].Journal of Power Sources,2001,97-98:437. |
| [20] | Johnson C S;Dees D W;Mansuetto M F et al.Structural and electrochemical studies of α-manganese dioxide ( α-MnO2 )[J].Journal of Power Sources,1997,68:570. |
| [21] | 刘金成,周震涛.λ-MnO2的结构与电性能研究[J].中国锰业,2003(04):25-28. |
| [22] | Bach Stephane;Pereira Ramos Jean Pierre;Cachet Christine et al.Effect of Bi-doping on the electrochemical behavior of layered MnO2 as lithium intercalation compound[J].Electrochimica Acta,1995,40(06):785. |
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