介孔二氧化硅掺杂染料后在传感器、荧光探针、药物输送、以及非线性光学材料特别是激光材料耐光性等领域具有广阔的应用前景并已成为当前研究的热点.本文综述了近十年来以介孔二氧化硅为主体掺杂荧光染料罗丹明B的研究进展,详细讨论了染料在介孔二氧化硅中的形成机理、聚集状态以及影响规律.最后,对罗丹明B染料掺杂介孔二氧化硅的研究进行了展望.
参考文献
| [1] | Noelting E;Dziewonski K .Zur Kenntniss de'r Rhodamine[J].Berichte der deutschen chemischen Gesellschaft,1905,38(03):3516-3527. |
| [2] | Kresge C;Leonowicz M;Roth W et al.Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J].NATURE,1992,359(6397):710-712. |
| [3] | Zhao D;Feng J;Huo Q et al.Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J].SCIENCE,1998,279(5350):548-552. |
| [4] | Tanev PT;Pinnavaia TJ .A NEUTRAL TEMPLATING ROUTE TO MESOPOROUS MOLECULAR SIEVES[J].Science,1995(5199):865-867. |
| [5] | Xiaoying Liu;Bozhi Tian;Chengzhong Yu;Feng Gao;Songhai Xie;Bo Tu;Renchao Che;Lian-Miao Peng;Dongyuan Zhao .Room-Temperature Synthesis in Acidic Media of Large-Pore Three-Dimensional Bicontinuous Mesoporous Silica with Ia3d Symmetry[J].Angewandte Chemie International Edition,2002(20):3876-3881. |
| [6] | Yokoi T;Yoshitake H;Tatsumi T .Synthesis of anionicsurfactant-templated mesoporous silica using organoalkoxysilanecontaining amino groups[J].Chemistry of Materials,2003,15(24):4536-4538. |
| [7] | Zhuang X;Bartley L E;Babcock H P et al.A single-molecule study of RNA catalysis and folding[J].SCIENCE,2000,288(5473):2048-2051. |
| [8] | Brian J. Scott;Michael H. Bartl;Gernot Wirnsberger;Galen D. Stucky .Energy Transfer in Dye-Doped Mesostructured Composites[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2003(29):5499-5502. |
| [9] | Grandi S;Tomasi C;Mustarelli P et al.Characterisation of a new sol-gel precursor for a SiO2-rhodamine 6G hybrid class Ⅱ material[J].Journal of Sol-Gel Science and Technology,2007,41(01):57-63. |
| [10] | Magdalena Stempniewicz;Michael Rohwerder;Frank Marlow .Release from Silica SBA-3-like Mesoporous Fibers:Cross-Wall Transport and External Diffusion Barrier[J].Chemphyschem: A European journal of chemical physics and physical chemistry,2007(1):188-194. |
| [11] | Zhao Y;Zheng B;Du J et al.A fluorescent "turn-on" probe for the dual-channel detection of Hg (Ⅱ) and Mg (Ⅱ) and its application of imaging in living cells[J].TALANTA,2011,85(04):2194-2201. |
| [12] | Changsheng Shan;Huafeng Yang;Jiangfeng Song;Dongxue Han;Ari Ivaska;Li Niu .Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Graphene[J].Analytical chemistry,2009(6):2378-2382. |
| [13] | Wan, X.;Liu, T.;Hu, J.;Liu, S. .Photo-degradable, protein-polyelectrolyte complex-coated, mesoporous silica nanoparticles for controlled Co-release of protein and model drugs[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2013(4):341-347. |
| [14] | Wan Y;Guo Q;Wang X et al.Photophysical properties of rhodamine isomers:A two-photon excited fluorescent sensor for trivalent chromium cation (Cr 《 sup 》 3 + 《/sup 》)[J].Analytica Chimica Acta,2010,665(02):215-220. |
| [15] | Ganschow M.;Wohrle D.;Schulz-Ekloff G.;Wark M. .Anchoring of functional dye molecules in MCM-41 by microwave-assisted hydrothermal cocondensation[J].Angewandte Chemie International Edition,2000(1):161-163. |
| [16] | Yuri Yamada;Hisashi Yamada;Tadashi Nakamura;Kazuhisa Yano .Manipulation of the Spontaneous Emission in Mesoporous Synthetic Opals Impregnated with Fluorescent Guests[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(23):13599-13605. |
| [17] | Zhang N;Li G;Cheng Z et al.Rhodamine B immobilized on hollow Au-HMS material for naked-eye detection of Hg《 sup》2 + 《/sup 》 in aqueous media[J].Journal of Hazardous Materials,2012,229:404-410. |
| [18] | Nozawa K;Osono C;Sugawara M .Biotinylated MCM-41 channels as a sensing element in planar bilayer lipid membranes[J].Sensors and Actuators, B. Chemical,2007(2):632-640. |
| [19] | Massey M;Algar W R;Krull U J .Fluorescence resonance energy transfer (FRET) for DNA biosensors:FRET pairs and Forster distances for various dye-DNA conjugate[J].Analytica Chimica Acta,2006,568(01):181-189. |
| [20] | Moeller C;Verber C;Adelman A .Laser pumping by excitation transfer in dye mixtures[J].Applied Physics Letters,2003,18(07):278-280. |
| [21] | Ahmed S;Gergely J;Infante D .Energy transfer organic dye mixture lasers[J].The Journal of Chemical Physics,2003,61(04):1584-1585. |
| [22] | Burlamacchi P;Ranea Sandoval H .Characteristics of a multicolor dye laser[J].Optics communication,1979,31(02):185-188. |
| [23] | Kusumoto Y;Sato H;Maeno K et al.Energy transfer dye laser:confirmation of energy transfer by reabsorption effect[J].Chemical Physics Letters,1978,53(02):388-390. |
| [24] | Marason E .Energy transfer dye mixture for argon-pumped dye laser operation in the 700 to 800 nm region[J].Optics communication,1982,40(03):212-214. |
| [25] | Sucharita Sinha;Alok K. Ray;Soumitra Kundu;Sasikumar;Tamal B. Pal;Sivagiriyal K. S. Nair;Kamalesh Dasgupta .Spectral characteristics of a binary dye-mixture laser[J].Applied optics,2002(33):7006-7011. |
| [26] | Ahamed MB.;Palanisamy PK. .Nd : YAG laser pumped energy transfer distributed feedback dye laser in Rhodamine 6G and Acid blue 7 dye mixture[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2002(1/3):67-80. |
| [27] | Wang LZ;Liu YL;Chen F;Zhang JL;Anpo M .Manipulating energy transfer processes between rhodamine 6G and rhodamine B in different mesoporous hosts[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(14):5541-5548. |
| [28] | Hoppe R;Ortlam A;Rathousky J et al.Synthesis of titaniumcontaining MCM-41 mesoporous molecular sieves in the presence of zinc phthalocyanine and rhodamine B[J].Microporous Materials,1997,8(05):267-273. |
| [29] | Shao YF;Wang LZ;Zhang JL;Anpo M .The photoluminescence of rhodamine B encapsulated in mesoporous Si-MCM-48, Ce-MCM-48, Fe-MCM-48 and Cr-MCM-48 molecular sieves[J].Journal of Photochemistry and Photobiology, A. Chemistry,2006(1/2):59-64. |
| [30] | Turgay Seckin;Ahmet Gultek;Suleyman Kartaca .The grafting of Rhodamine B onto sol-gel derived mesoporous silicas[J].Dyes and Pigments,2003(1):51-57. |
| [31] | Mina Guli;Yue Chen;Xiaotian Li;Guangshan Zhu;Shilun Qiu .Fluorescence of postgrafting Rhodamine B in the mesopores of rodlike SBA-15[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2007(2):723-727. |
| [32] | Jun Watanabe;Mekawy M.Mahmoud;Rise Fujiwara;Yosuke Amino;Yong Chen .Extraction mechanisms of charged organic dye molecules into silica-surfactant nanochannels in a porous alumina membrane[J].Analytica chimica acta,2006(1):157-163. |
| [33] | Deryaguin B.Effect of surface forces on the properties of boundary and thin layers of liquids and disperse systems[A].,1965 |
| [34] | Inagaki S;Fukushima Y;Kuroda K .Synthesis of highly ordered mesoporous materials from a layered polysilicate[J].Journal of the Chemical Society Chemical Communications,1993,8:680-682. |
| [35] | Yang P;Wirnsberger G;Huang H C et al.Mirrorless lasing from mesostructured waveguides patterned by soft lithography[J].SCIENCE,2000,287(5452):465-467. |
| [36] | K. J. Lee;J. H. Oh;Y. Kim;J. Jang .Fabrication of Photoluminescent-Dye Embedded Poly(methyl methacrylate) Nanofibers and Their Fluorescence Resonance Energy Transfer Properties[J].Advanced Materials,2006(17):2216-2219. |
| [37] | Urisu T;Kajiyama K .Concentration dependence of the gain spectrum in energy-transfer dye mixtures[J].Journal of Applied Physics,2008,47(08):3563-3565-. |
| [38] | Mohan D;Sanghi S;Singh R et al.Energy transfer excitation in an N2-laser-pumped coumarin 485-rhodamine B dye mixture through optical gain characteristics[J].Journal of Photochemistry and Photobiology A:Chemistry,1992,68(01):77-84. |
| [39] | Yan L.;Whitesides GM.;Zhao XM. .Patterning a preformed, reactive SAM using microcontact printing[J].Journal of the American Chemical Society,1998(24):6179-6180. |
| [40] | Augenstein L G.Physical processes in radiation biology[A].,1964 |
| [41] | McKiernan J M;Yamanaka S A;Dunn B et al.Spectroscopy and laser action of rhodamine 6G doped aluminosilicate xerogels[J].Journal of Physical Chemistry,1990,94(15):5652-5654. |
| [42] | Canham L .Laser dye impregnation of oxidized porous silicon on silicon wafers[J].Applied Physics Letters,1993,63(03):337-339. |
| [43] | Costa TMH;Gallas MR;Benvenutti EV;daJornada JAH;UNIV FED RIO GRANDE SUL INST QUIM BR-91501970 PORTO ALEGRE RS BRAZIL. .Infrared and thermogravimetric study of high pressure consolidation in alkoxide silica gel powders[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1997(2/3):195-201. |
| [44] | LU Y.;GANGULI R.;DREWIEN C. A.;ANDERSON M. T.;BRINKER C. J.;GONG W.;GUO Y.;SOYEZ H.;DUNN B.;HUANG M. H.;ZINK J. I. .CONTINUOUS FORMATION OF SUPPORTED CUBIC AND HEXAGONAL MESOPOROUS FILMS BY SOL GEL DIP-COATING[J].Nature,1997(6649):364-368. |
| [45] | Malashkevich G;Poddeneznyi E;Mel' nichenko I et al.Luminescence-spectrum and strength properties of rhodamine 6G-doped silica gel films[J].Physics of the Solid State,1998,40(03):427-431. |
| [46] | Ogawa M .Organized molecular assemblies on the surfaces of inorganic solids-photofunctional inorganic-organic supramolecular systems[J].Annual Reports Section"C"(Physical Chemistry),1998,94:209-257. |
| [47] | Aida M.;Dupuis M.;Yamataka H. .Ab initio molecular dynamics simulations on the hydrolysis of methyl chloride with explicit consideration of three water molecules[J].Chemical Physics Letters,1998(4-6):474-480. |
| [48] | Tu J;Li N;Chi Y et al.The study of photoluminescence properties of Rhodamine B encapsulated in mesoporous silica[J].Materials Chemistry and Physics,2009,118(02):273-276. |
| [49] | Melosh N;Davidson P;Feng P et al.Macroscopic shear alignment of bulk transparent mesostructured silica[J].Journal of the American Chemical Society,2001,123(06):1240-1241. |
| [50] | Mester ZN.;Sturgeon R.;Pawliszyn J.;Lam J. .Determination of methylmercury by solid-phase microextraction inductively coupled plasma mass spectrometry: a new sample introduction method for volatile metal species[J].Journal of Analytical Atomic Spectrometry,2000(7):837-842. |
| [51] | del Monte F.;Levy D.;Mackenzie JD. .Rhodamine fluorescent dimers adsorbed on the porous surface of silica gels[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(19):7377-7382. |
| [52] | Gernot Wirnsberger;Galen D. Stucky .Microring Lasing from Dye-Doped Silica/Block Copolymer Nanocomposites[J].Chemistry of Materials,2000(9):2525-2527. |
| [53] | Gernot Wirnmsberger;Peidong Yang;Howard C.Huang;Barian Scott;Tao Deng;George M.Whitesides;Bradley F.Chmelka;Galen D.Stucky .Patterned Block-Copolymer -Silica Mesostructures as Host Media for the Laser Dye Rhodamine 6G[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2001(27):6307-6313. |
| [54] | Yariv S;Cross H.Organo-clay complexes and interactions[M].CRC Press,2001 |
| [55] | Freddy Kleitz;Shin Hei Choi;Ryong Ryoo .Cubic Ia3d large mesoporous silica: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes[J].Chemical communications,2003(17):2136-2137. |
| [56] | Chang ZX.;Kevan L. .Photoionization of tetraphenylporphyrin in mesoporous SiMCM-48, AlMCM-48, and TiMCM-48 molecular sieves[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(3):911-916. |
| [57] | van-de-Vijver MJ;He YD;van't-Veer LJ;Dai H;Hart AA;Voskuil DW;Schreiber GJ;Peterse JL;Roberts C;Marton MJ;Parrish M;Atsma D;Witteveen A;Glas A;Delahaye L;van-der-Velde T;Bartelink H;Rodenhuis S;Rutgers ET;Friend SH;Bernards R .A gene-expression signature as a predictor of survival in breast cancer.[J].The New England journal of medicine,2002(25):1999-2009. |
| [58] | Gao X;Nie S .Doping mesoporous materials with multicolor quantum dots[J].The Journal of Physical Chemistry(B)Materials Surfaces Interfaces & Physical,2003,107(42):11575-11578. |
| [59] | Tourné-Péteilh C;Lerner D A;Charnay C et al.The Potential of Ordered Mesoporous Silica for the Storage of Drugs:The Example of a Pentapeptide Encapsulated in a MSU-Tween 80[J].Chem Phys Chem,2003,4(03):281-286. |
| [60] | Ryo Sasai;Nobuo Iyi;Taketoshi Fujita;Fernando Lopez Arbeloa;Virginia Martinez Martinez;Katsuhiko Takagi;Hideaki Itoh .Luminescence Properties of Rhodamine 6G Intercalated in Surfactant/Clay Hybrid Thin Solid Films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(11):4715-4719. |
| [61] | Wang, JF;Tsung, CK;Hong, WB;Wu, YY;Tang, J;Stucky, GD .Synthesis of mesoporous silica nanofibers with controlled pore architectures[J].Chemistry of Materials,2004(24):5169-5181. |
| [62] | A. Anedda;C.M. Carbonaro;F. Clemente;R. Corpino;P.C. Ricci;S. Rossini .Rhodamine 6G impregnated porous silica: A photoluminescence study[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2005(5/8):641-644. |
| [63] | Tania Maria Haas Costa;Helena Sofia Hoffmann;Edilson Valmir Benvenutti;Valter Stefani;Marcia Russman Gallas .Pressure-induced changes on the optical properties and microstructure of silica-gel matrices doped with rhodamine 6G[J].Optical materials,2005(12):1819-1824. |
| [64] | Arbeloa FL;Martinez VM;Arbeloa T;Arbeloa IL .Photoresponse and anisotropy of rhodamine dye intercalated in ordered clay layered films[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,2007(2):85-108. |
| [65] | Magdalena Stempniewicz;Ahmed S.G.Khalil;Michael Rohwerder .Diffusion in Coiled Pores - Learning from Microrelease and Microsurgery[J].Journal of the American Chemical Society,2007(34):10561-10566. |
| [66] | Kano K;Miyake T;Uomoto K et al.Evidence for stacking of cationic porphyrin in aqueous solution[J].Chemistry Letters,1983,12):1867-1870. |
| [67] | Yoshiumi Kohno;Shunsuke Tsubota;Yoshinori Shibata .Enhancement of the photostability of flavylium dye adsorbed on mesoporous silicate[J].Microporous and Mesoporous Materials,2008(1/3):70-76. |
| [68] | Chia-Hung Lee;Leu-Wei Lo;Chung-Yuan Mou;Chung-Shi Yang .Synthesis and Characterization of Positive-Charge Functionalized Mesoporous Silica Nanoparticles for Oral Drug Delivery of an Anti-Inflammatory Drug[J].Advanced functional materials,2008(20):3283-3292. |
| [69] | Tapasi Sen;Krishna Kanta Haldar;Amitava Patra .Au Nanoparticle-Based Surface Energy Transfer Probe for Conformational Changes of BSA Protein[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(46):17945-17951. |
| [70] | Suh M;Lee HJ;Park JY;Lee UH;Kwon YU;Kim DJ .A mesoporous silica thin film as uptake host for guest molecules with retarded release kinetics[J].Chemphyschem: A European journal of chemical physics and physical chemistry,2008(10):1402-1408. |
| [71] | K. Ananthanarayanan;P. Natarajan .Fabrication and photophysical studies of phenosafranine and proflavine dyes encapsulated in mesoporous MCM-41 along with titanium dioxide nanoparticles[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2009(1/3):179-189. |
| [72] | Matthew T. Hurley;Zifan Wang;Amanda Mahle;Daniel Rabin;Qing Liu;Douglas S. English;Michael R. Zachariah;Daniel Stein;Philip DeShong .Synthesis, Characterization, and Application of Antibody Functionalized Fluorescent Silica Nanoparticles[J].Advanced functional materials,2013(26):3335-3343. |
| [73] | Mas, N.;Agostini, A.;Mondrag?n, L.;Bernardos, A.;Sancen?n, F.;Marcos, M.D.;Martínez-Má?ez, R.;Costero, A.M.;Gil, S.;Merino-Sanjuán, M.;Amor?s, P.;Orzáez, M.;Pérez-Payá, E. .Enzyme-responsive silica mesoporous supports capped with azopyridinium salts for controlled delivery applications[J].Chemistry: A European journal,2013(4):1346-1356. |
| [74] | Wang Y;Li B;Zhang L et al.Targeted Delivery System Based on Magnetic Mesoporous Silica Nanocomposites with Light-Controlled Release Character[J].ACS applied materials & interfaces,2012,5(01):11-15. |
| [75] | BRUCE DUNN;JEFFREY I.ZINK .Molecules in Glass:Probes,Ordered Assemblies,and Functional Materials[J].Accounts of Chemical Research,2007(9):747-755. |
| [76] | Raquel Hernandez;Anne-Christine Franville;Payam Minoofar .Controlled Placement of Luminescent Molecules and Polymers in mesostructured Sol-Gel Thin Films[J].Journal of the American Chemical Society,2001(6):1248-1249. |
| [77] | Minoofar PN.;Hernandez R.;Chia S.;Dunn B.;Zink JI.;Franville AC. .Placement and characterization of pairs of luminescent molecules in spatially separated regions of nanostructured thin films[J].Journal of the American Chemical Society,2002(48):14388-14396. |
| [78] | C.S.Yun.t A.Javier;T.Jennings;M.Fisher;S.Hira;S.Peterson;B.Hopkins;N.O.Reich;G.F.Strouse .Nanometal Surface Energy Transfer in Optical Rulers,Breaking the FRET Barrier[J].Journal of the American Chemical Society,2005(9):3115-3119. |
| [79] | Marci C.Burt;Bakul C.Dave .Externally Tunable Dynamic Confinement Effect in Organosilica Sol-Gels[J].Journal of the American Chemical Society,2006(36):11750-11751. |
| [80] | Li-Ning Sun;Hong-Jie Zhang;Chun-Yun Peng;Jiang-Bo Yu;Qing-Guo Meng .Covalent Linking of Near-Infrared Luminescent Ternary Lanthanide (Er~(3+),Nd~(3+),Yb~(3+)) Complexes on Functionalized Mesoporous MCM-41 and SB A-15[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(14):7249-7258. |
| [81] | Sewell G;Forster RJ;Keyes TE .Influence of steric confinement within zeolite Y on photoinduced energy transfer between [Ru(bpy)(3)](2+) and iron polypyridyl complexes[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2008(5):880-888. |
| [82] | 龚建勋,刘正义,曾德长,闻立时.改性还原染料分子自组装性的研究[J].材料科学与工程学报,2007(02):193-196,224. |
| [83] | 王芳芳,殷立峰,傅吉全.介孔氧化钛的溶剂热合成及其光催化性能[J].材料科学与工程学报,2008(04):627-630. |
| [84] | 殷立峰,傅吉全.盐处理对介孔MCM-41结构和稳定性的调变[J].材料科学与工程学报,2007(04):620-623. |
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