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将商业用交联聚乙烯在150℃下ASTM Ⅱ类老化箱内进行老化试验,用热失重分析仪研究了TG快速热寿命评估方法与实际老化过程中的联系。结果表明:寿命终止时的交联聚乙烯在空气氛围中第一阶段的热降解行为比较接近于实际运行中的老化过程。交联聚乙烯在150℃下的热老化终止寿命接近336 h,老化活化能为114.25 kJ/mol,通过热老化寿命公式得到交联聚乙烯在工作温度70℃下的使用寿命大概为74年,比较接近实际应用值。

Commercial cross-linked polyethylene(XLPE) was thermal aged in ASTM Ⅱ oven under 150℃, and the relationship between TG rapid evaluation method of thermal life and actual thermal ag-ing process was studied. The results show that the first stage decomposition process of the XLPE reach-ing the end life is close to the actual thermal aging process. The thermal aging end life of the XLPE at 150℃ is 336 h, and the activation energy is 114.25 kJ/mol. The service life of the XLPE at the working temperature of 70℃ is 74 year obtained by Arrhenius equation, which is close to the applied value.

参考文献

[1] 金天雄,刘飞,江平开,金石南,李哲凡.热老化XLPE电缆绝缘的介电击穿行为的研究[J].电线电缆,2008(06):28-31,39.
[2] 宋淑艳;焦爱红 .2000年全国火灾形势分析与思考[J].现代消防与产品研究,2001,9(01):21-24.
[3] Parks L L;Kushler B D;Serapiglia M J et al.Fire Risk Assessment of Telecommunications Central Offices[J].FIRE TECHNOLOGY,1998,34(02):156-176.
[4] Gillen, KT;Bernstein, R;Derzon, DK .Evidence of non-Arrhenius behaviour from laboratory aging and 24-year field aging of polychloroprene rubber materials[J].Polymer Degradation and Stability,2005(1):57-67.
[5] M. Celina;K.T. Gillen;R.A. Assink .Accelerated aging and lifetime prediction: Review of non-Arrhenius behaviour due to two competing processes[J].Polymer Degradation and Stability,2005(3):395-404.
[6] 徐亮,伍卫军,丁严艳.典型热塑性聚合物热解行为研究[J].火灾科学,2010(03):143-149.
[7] Gulmine JV;Akcelrud L .Correlations between structure and accelerated artificial ageing of XLPE[J].European Polymer Journal,2006(3):553-562.
[8] Montanari G.C.;Motori A. .Short-term thermal endurance characterization of polymeric cable insulating materials. Use of oxidative stability measurements[J].IEEE transactions on dielectrics and electrical insulation: A publication of the IEEE Dielectrics and Electrical Insulation Society,1996(4):561-566.
[9] 韩晔,张盈锁,翟晓军.热重点斜法(TPS)概述[J].绝缘材料,2003(06):51-54.
[10] 王正洲;范维澄;瞿保钧 等.常用高分子装饰材料的燃烧特性[J].火灾科学,1999,8(03):67-71.
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