综述了近年来磁性纳米Fe3O4的多种制备方法:化学共沉淀法、沉淀氧化法、水热法、微乳液法、溶胶-凝胶法、机械研磨法和高温分解法.由于化学共沉淀法是制备纳米Fe3O4铁粒子最常用的方法,所以特别对此方法的反应机理做了详细阐述.介绍了磁性纳米Fe3O4在生物医学方面的具体应用并展望了其今后的发展方向.
参考文献
[1] | Welo L A;Baudisch O .The two-stage transformaiton of magnetite into hematite[J].Philosophical Magazine,1995,50:399. |
[2] | Massart R .Preparation of aqueous magnetic liquids in alkaline and acidic media[J].IEEE Transactions on Magnetics,1981,17:1247. |
[3] | Chen JP.;Klabunde KJ.;Hadjipanayis GC.;Devlin E. Kostikas A.;Sorensen CM. .SIZE-DEPENDENT MAGNETIC PROPERTIES OF MNFE2O4 FINE PARTICLES SYNTHESIZED BY COPRECIPITATION[J].Physical Review.B.Condensed Matter,1996(13):9288-9296. |
[4] | Ozaki M.Formation of magnetic particles in fine particles[M].New York,USA:Marcel Dekker,Inc,2000:662. |
[5] | Tang Z X;Sorensen C M;Klabunde K J et al.Preparation of manganese ferrite fine particles from aqueous solution[J].Journal of Colloid and Interface Science,1991,146:38. |
[6] | Zhang ZJ.;Chakoumakos BC.;Yin JS.;Wang ZL. .Temperature dependence of cation distribution and oxidation state in magnetic Mn-Fe ferrite nanocrystals[J].Journal of the American Chemical Society,1998(8):1800-1804. |
[7] | Neveu S.;Bee A.;Robineau M.;Talbot D. .Size-selective chemical synthesis of tartrate stabilized cobalt ferrite ionic magnetic fluid[J].Journal of Colloid and Interface Science,2002(2):293-298. |
[8] | Liu Z L et al.Synthesis and magnetic properties of Fe3O4nanoparticles[J].Journal of Materials Synthesis and Processing,2002,10:83. |
[9] | 邱星屏.四氧化三铁磁性纳米粒子的合成及表征[J].厦门大学学报(自然科学版),1999(05):711-715. |
[10] | Kim DK.;Mikhaylova M.;Zhang Y.;Muhammed M. .Protective coating of superparamagnetic iron oxide nanoparticles[J].Chemistry of Materials,2003(8):1617-1627. |
[11] | Misawa T;Hashimoto K;Shimodaira S .The mechanism of formation of iron oxide and oxyhydroxides in aqueous solutions at room temperature[J].Corrosion Science,1974,14:131. |
[12] | Music S;Popovic S;Gotic M .Mossbauer spectroscopy and X-ray diffraction of oxide precipitate formed from FeSO4 solution[J].Journal of Materials Science,1990,25:3186. |
[13] | Zao R;Pan P .A spectrophotometric study of Fe(Ⅱ)-Chloride complexes in aqueous solutions from 10 to 100"C[J].Canadian Journal of Chemistry,2001,79:131. |
[14] | Sweeton F H;Baes J C F .The solubility of magnetite and hydrolysis of ferrous ion in qqueous solutions at elevated temperatures[J].Journal of Chemical Thermodynamics,1970,2:479. |
[15] | Sugimoto T;Matijevic E .Formation of uniform spherical nagnetite particles by crystallization from ferrous hydroxide gels[J].Journal of Colloid and Interface Science,1980,74:227. |
[16] | Charles J;Flynn M .Hydrolysis of inorganic iron(Ⅲ) salts[J].Chemical Reviews,1984,84:31. |
[17] | Cornell R M;Schwertmann U.The iron oxides[M].Weinheim:VCH Verlagsgesellschaft,1996:247. |
[18] | Otterstedt,Brandredth D A.Small particles technology[M].New York:Plenum Press,1998:45. |
[19] | Wu K T et al.Magnetic and optical properties of Fe3O4nanoparticle ferrofluids prepared by coprecipitation technique[J].IEEE Transactions on Magnetics,2001,37:2651. |
[20] | Misawa T et al.Formation of Fe(Ⅱ)-Fe(Ⅲ) green complex on oxidation of ferrous ion in perchloric acid solution[J].Journal of Radioanalytical and Nuclear Chemistry,1973,3:4159. |
[21] | Regazzoni A E;Urrutia G A;Blesa M A et al.Some observations on the composition and morphology of synthetic magnetites obtained by different routes[J].Journal of Radioanalytical and Nuclear Chemistry,1981,43:1489. |
[22] | Fried T.;Markovich G.;Shemer G. .Ordered two-dimensional arrays of ferrite nanoparticles[J].Advanced Materials,2001(15):1158-0. |
[23] | Kang Y S;Risbud S;Rabolt J F et al.Synthesis and characterization of nanometer-size Fe3O4 and γ-Fe2O3 particles[J].Chemistry of Materials,1996,8:2209. |
[24] | Gee SH.;Hong YK.;Erickson DW.;Park MH.;Sur JC. .Synthesis and aging effect of spherical magnetite (Fe3O4) nanoparticles for biosensor applications[J].Journal of Applied Physics,2003(10 Pt.2):7560-7562. |
[25] | Ma M.;Zhang Y.;Yu W.;Shen HY.;Zhang HQ.;Gu N. .Preparation and characterization of magnetite nanoparticles coated by amino silane[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2003(2/3):219-226. |
[26] | Qu S;Yang H;Ren D et al.Magnetite nanoparticles prepared by precipitation from partially reduced ferric chloride aqueous solutions[J].Journal of Colloid and Interface Science,1999,215:190. |
[27] | Hong CY.;Horng HE.;Hsu CJ.;Yao YD.;Yang HC.;Jang IJ. .ORDERED STRUCTURES IN FE3O4 KEROSENE-BASED FERROFLUIDS[J].Journal of Applied Physics,1997(8 Pt.2a):4275-4277. |
[28] | Vayssieres L.;Tronc E.;Jolivet JP.;Chaneac C. .Size tailoring of magnetite particles formed by aqueous precipitation: An example of thermodynamic stability of nanometric oxide particles[J].Journal of Colloid and Interface Science,1998(2):205-212. |
[29] | 孟哲,张冬亭,王春平.磁性纳米级Fe3O4的氧气诱导、空气氧化液相合成与表征[J].光谱实验室,2003(04):489-491. |
[30] | 王全胜.沉淀氧化法制备Fe3O4的影响因素研究[J].北京理工大学学报,1994(02):200. |
[31] | 何秋星,李伟洲,陈权启.水热法制备纳米Fe3O4的研究[J].广西大学学报(自然科学版),2004(02):170-174. |
[32] | 邹大香,王海燕,杨晓辉,李新建.影响水热合成纳米Fe304晶粒纯度和平均粒径的因素[J].科学技术与工程,2003(03):253-256. |
[33] | 钟维卓 .纳米材料及其水热法制备(上)[J].上海化工,1998,23(11):25. |
[34] | 钟维卓 .纳米材料及其水热法制备(下)[J].上海化工,1998,23(12):15. |
[35] | 陈兴,邓兆祥,李宇鹏,李亚栋.水热法制备超顺磁性铁氧体纳米微粒[J].无机化学学报,2002(05):460-464. |
[36] | Arturo M .Magnetic iron oxide nanoparticles synthesizedvia microemulsions[J].Journal of Colloid and Interface Science,1993,158:446. |
[37] | 何秋星,杨华,陈权启,刘素琴,黄可龙.微乳化法制备纳米磁性Fe3O4微粒工艺条件研究[J].磁性材料及器件,2003(02):9-11. |
[38] | 徐滨士.纳米表面工程[M].北京:化学工业出版社,2004:27. |
[39] | Xu Jing;Yang Haibin;Fu Wuyou .Preparation and magnetic properties of magnetic nanoparticles by sol-gel method[J].Journal of Magnetism and Magnetic Materials,2007,309(01):307. |
[40] | 英廷照;沈辉 等.高分散纳米Fe3O4颗粒的制备和表征[J].机械科学与技术,1998,17:147. |
[41] | 陈辉.高温分解法合成Fe3O4磁性纳米微粒[J].河南化工,2004(02):11-12. |
[42] | Yin Yadong et al.Silver nanowires can be directly coated with amorphous silicta to generate well-controlled coaxial nanocables of silver/silica[J].NANO LETTERS,2002,2(04):42. |
[43] | 陈志军,彭凯,路文忠,周思凯.Fe3O4/聚合物磁性高分子微球的制备[J].材料导报,2006(z2):198-200,205. |
[44] | 韩涛,李富荣,张渊明,颜秋平,周汉新.一种磁性纳米药物载体的阿霉素吸附与脱附实验[J].材料科学与工程学报,2006(02):258-263. |
[45] | Ma M.;Zhang Y.;Yu W.;Shen HY.;Zhang HQ.;Gu N. .Preparation and characterization of magnetite nanoparticles coated by amino silane[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2003(2/3):219-226. |
[46] | 马明,朱毅,张宇,张东生,唐祖明,张海黔,顾宁.四氧化三铁纳米粒子与癌细胞相互作用的初步研究[J].东南大学学报(自然科学版),2003(02):205-207. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%