欢迎登录材料期刊网

材料期刊网

高级检索

将MEH-PPV混合入YAG荧光粉中,并利用实验室自主研发的一种集成封装LED散热支架替代传统支架,该支架可利用热电偶直接测量出结温。研究了结温对混合MEH-PPV的白光LED光谱特性的影响。实验表明,随着结温的不断升高,蓝光光谱峰值随着结温的升高而不断下降,发生红移;荧光粉的吸收增强,黄光波段和红光波段的光谱峰值先增后减,并且红光波段的光谱发生蓝移;器件的显色指数从90.3下降至78.6,色温从3265K先快速升高至3672K,随后又缓慢下降至3612K,而光通量和发光效率则表现为先上升后下降,且它们的下降趋势基本吻合。

Mixing MEH-PPV with YAG phosphors,we utilize a new kind of light-emitting diodes which are encapsulated the LED chip to the aluminum plate directly to replace the traditional stent.The junction temperature can be directly measured by the thermocouple.Research the influence of the junction temperature on white LED spectral characteristics.Experiments show that: with the junction temperature rising,blue spectrum peak was declining and red shift was occurred;the absorption of phosphor was enhanced,while yellow and red spectral peaks increase first and then decrease;the blue shift of the red light band spectrum was occurred;and the color render index falls from 90.3 to 78.6,while the color temperature increases from 3265K to 3672K rapidly first,then drop to 3612K slowly;the flux and luminous efficiency have the same variation trend which increase first and then decrease.

参考文献

[1] Chen Quan;Luo Xiaobing;Zhou Shengjun et al.Dy namic junction temperature measurement for high power light emitting diodes[J].Review of Scientific Instru-ments,2011,82:084904.
[2] 宋恩海,赵韦人,周国雄,豆喜华,俞军,易春雨.白光LED用荧光粉Ba1.97Ca1-x(B3O6)2:Eu0.032+,Mnx2+的制备及其发光特性[J].光谱学与光谱分析,2010(12):3191-3194.
[3] Francis L T;Rao P P;Thomas M et al.New orange-red emitting phosphor La3 NbO::Eu3+ under blue exci-tation[J].Materials Letters,2012,81:142-144.
[4] Lee, G.-H.;Kang, S. .Solid-solution red phosphors for white LEDs[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2011(12):2582-2588.
[5] Guzik, M.;Tomaszewicz, E.;Kaczmarek, S.M.;Cybińska, J.;Fuks, H. .Spectroscopic investigations of Cd_(0.25)Gd _(0.50)□_(0.25)WO_4:Eu~(3 +) - A new promising red phosphor[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2010(37/40):1902-1907.
[6] Tang An;Zhang Dingfei;Yang Liu et al.Synthesis and photoluminescence properties of In2(MoO4)3:Eua+,Bia+ red phosphor for nea UV white LED[J].Journal of Functional Materials,2012,43(07):817-819.
[7] Yan Mifang;Xue Lihong;Yan Youwei et al.Lumines-cence properties of mSr2P2 07:Eua+ phosphor for white light emitting diode[J].Journal of Functional Materials,2011,42(11):1998-2004.
[8] 毕长栋,张方辉.LED激发有机材料MPPV的光谱分析[J].光谱学与光谱分析,2012(03):619-621.
[9] 刘立明,郑晓东.LED结温与光谱特性关系的测量[J].光子学报,2009(05):1069-1073.
[10] Mao Defeng;Guo Welling;Gao Guo et al.Research on the thermal resistance and junction temperature of high-power LEDs[J].Research Progress ol 5se,2012,30(02):308-312.
[11] 孔凡,欧昌刚,郑怡,张苏洋,杨昌正,吴兴龙,袁仁宽.链构象对稀溶液中MEH-PPV的光致发光的影响[J].发光学报,2004(06):731-736.
[12] Tang C W;Huang Xiaowen.Organic electroluminescent materials devices[M].北京:清华大学出版社,2007:82-83.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%