欢迎登录材料期刊网

材料期刊网

高级检索

用电子回旋共振等离子体增强化学气相沉积(ECR-PECVD)的方法制备了磷掺杂微晶硅薄膜材料.通过Hall,Raman光谱和XRD的测试分析,研究了衬底温度和磷烷流量对掺杂薄膜组织结构和电学性能的影响.根据AFM照片分析了薄膜的表面形貌,进而推测了薄膜的内部组成.实验发现:衬底温度在250 ℃时,磷烷的加入会大大降低薄膜的晶化率.衬底温度提高到350 ℃后这种影响明显下降.薄膜的载流子浓度和电导率受薄膜晶化率影响明显,衬底温度的升高对薄膜电学性能提高有较大帮助.

参考文献

[1] Chapin D M;Fuller C S;Pearson G L .A New Silicon P-N Junction Photocell for Converting Solar Radiation into Electrical Power[J].Journal of Applied Physics,1954,25:676.
[2] Goetzberger A.;Hebling C.;Schock HW. .Photovoltaic materials, history, status and outlook [Review][J].Materials Science & Engineering, R. Reports: A Review Journal,2003(1):1-46.
[3] 许颖,刁宏伟,张世斌,励旭东,曾湘波,王文静,廖显伯.微量掺碳ne-SiC:H薄膜用于p-i-n太阳电池的窗口层[J].物理学报,2007(05):2915-2919.
[4] 雷青松,徐火希,王晓晶,季峰,徐静平.P/I界面处理对a-Si:H柔性太阳能电池性能的影响[J].人工晶体学报,2008(05):1187-1190.
[5] H. Chen;W. Z. Shen;W. S. Wei .Structural order effect in visible photoluminescence properties of nanocrystalline Si:H thin films[J].Applied physics letters,2006(12):121921-1-121921-3-0.
[6] Yue Kuo .Doping gas effects on plasma enhanced chemical vapor deposition on heavily phosphorus-doped n↑(+) silicon film[J].Applied physics letters,1997(17/20):2821-2823.
[7] 刘明,王子欧,奚中和,何宇亮.磷掺杂纳米硅薄膜的研制[J].物理学报,2000(05):983-988.
[8] 汪昌州,杨仕娥,陈永生,杨根,郜小勇,卢景霄.硼掺杂对μc-Si:H薄膜微结构和光电性能的影响[J].人工晶体学报,2007(01):123-128.
[9] 陈城钊,邱胜桦,刘翠青,吴燕丹,李平,余楚迎,林璇英.纳米晶硅薄膜中氢含量及键合模式的红外分析[J].物理学报,2009(04):2565-2571.
[10] 李世彬,吴志明,李伟,于军胜,蒋亚东,廖乃镘.氢化硅薄膜的晶化机理研究[J].物理学报,2008(11):7114-7118.
[11] Richter H;Ley L .Optical Properties and Transport in Microcrystalline Silicon Prepared at Temperature below 400 ℃[J].Journal of Applied Physics,1981,52(12):7281-7286.
[12] Xu Y;Gu B;Qin F W .Electron Cyclotron Resonance Plasma Enhanced Metalorganic Chemical Vapor Deposition System with Monitoring in Situ for Epitaxial Growth of Group-Ⅲ Nitrides[J].Journal of Vacuum Science and Technology A:Vacuum Surfaces and Films,2004,A22(02):302-308.
[13] Wu A M;Deng W T;Qin F W et al.Fabrication and Its Characteristics of Low-temperature Polycrystalline Silicon Thin Films[J].Science in China(Series E),2009,52:260-263.
[14] Tsukidate Y.;Suemitsu M. .Growth kinetics and doping mechanism in phosphorus-doped Si gas-source molecular beam epitaxy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(0):43-48.
[15] Ying WB.;Kamiura Y.;Kawamoto K.;Yang WY.;Mizokawa Y. .The chemical composition changes of silicon and phosphorus in the process of native oxide formation of heavily phosphorus doped silicon[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(1/2):1-14.
[16] 陈治明.非晶半导体材料与器件[M].北京:科学出版社,1991:89.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%