采用沉淀法合成F-,Sr2+单掺杂和共掺杂的氧化铈,探讨了不同掺杂离子对氧化铈紫外屏蔽性能和氧化催化性能的影响.XRD结果表明,F-,Sr2+单掺杂或共掺杂的CeO2均为立方萤石结构,但衍射峰因掺杂离子的不同而稍有偏移.UV-Vis光谱表明,F-,Sr2+单掺杂和共掺杂的氧化铈的紫外屏蔽性能均优于纯氧化铈.共掺杂氟锶后的氧化铈的氧化催化性明显比纯氧化铈的弱,但是,单掺杂氟离子或锶离子的氧化铈的氧化催化性比纯氧化铈的强.
参考文献
[1] | 李梅,柳召刚,刘铃声,胡艳宏,武国琴,熊晓柏.氧化铈超细粉体的制备研究[J].中国稀土学报,2003(04):465-467. |
[2] | 王嵩龄,刘钧云,贾江涛,廖春生,严纯华.大粒度、高表观比重氧化铈的合成[J].中国稀土学报,2008(01):117-120. |
[3] | 朱兆武,龙志奇,崔大立,张顺利,张国成.超细CeO2粉体的制备及其紫外线吸收性能[J].中国有色金属学报,2005(03):435-440. |
[4] | 刘连利;赵志成 .二氧化铈-氧化铝纳米复合粉体的制备及抗紫外线性能研究[J].无机盐工业,2010,42(03):17. |
[5] | 吴红苗 .纳米二氧化铈的制备与表征[D].浙江大学,2008. |
[6] | 付海 .氧化铈在天然橡胶中的应用研究[D].内蒙古科技大学,2009. |
[7] | 郭鹏,邵光杰,胡婕,孙丽娟,刘海彪,郑礼明.有机溶剂中溶胶-凝胶法制备纳米钙钛矿型氧化物[J].中国稀土学报,2006(z1):49-52. |
[8] | 陈伟凡,李凤生,于吉义,李永绣.盐助溶液燃烧法制备高比表面氧化铈纳米粉体[J].中国稀土学报,2006(04):408-413. |
[9] | 柴希娟 .锌铈复合氧化物的紫外光屏与催化特性研究[D].昆明理工大学,2004. |
[10] | El-Toni AM;Yin S;Hayasaka Y;Sato T .Coating and photochemical properties of calcia-doped ceria with amorphous silica by a seeded polymerization technique[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(12):1293-1297. |
[11] | Wang Z;Quan Z;Lin J .Remarkable changes in the optical properties of CeO2 nanocrystals induced by lanthanide ions doping[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(13):5237-5242. |
[12] | Li Gaoren;Qu Dunlin;Arurault L;Tong Yexiang .Hierarchically porous Gd3 +-doped CeO2 nanostructures for the remarkable enhancement of optical and magnetic properties[J].Physical Chemistry,2009,113:1235. |
[13] | Kempaiah M;Shu Y;Sato T .Morphology control of cerium oxide particles synthesized via a supercritical solvothennal method[J].Applied Materials,2009,11:2694. |
[14] | 王艳荣,李彦涛,李亚萍.纳米CeO2的紫外吸收和表面改性研究[J].化工时刊,2008(01):4-6. |
[15] | 文贵华;毛健;高跃升;白昱 .纳米CeO2的表面改性及在油中的分散稳定性研究[J].功能材料,2009,40(增刊):394. |
[16] | 李梅,付海,柳召刚,胡艳红,李岩峰,吴锦绣.硬脂酸改性氧化铈的效果表征与机理研究[J].稀土,2010(03):11-14. |
[17] | Sronek L;Majimel J;Kihn Y;Montardi Y,Tressaud A,Feist M,Legein C,Buzare Y,Body M,Demourgues A .New highly divided Ce-Ca-based oxyfluorides with UV-shielding properties:Study of the Cet-x Cax O2-x and Ce1-x CaxO2-x-y/2 Fy series[J].Chemistry of Materials,2007,19:5110. |
[18] | Sronek L;Lhoste J;Gaudon M;Legein C,Buzare Y,Body M,Criniere G,Tressaud A,Pechev S,Demourgues A .Probing the local enviroments of fluorine in Ce-based fluorite-type oxyfluorides with 19F MAS NMR spectroscopy[J].Physical Chemistry,2008,112:860. |
[19] | Yabe S.;Sato T. .Cerium oxide for sunscreen cosmetics[J].International Journal of Quantum Chemistry,2003(1/2):7-11. |
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