欢迎登录材料期刊网

材料期刊网

高级检索

分别介绍了锂钴氧化物、锂镍氧化物、锂锰氧化物、多元复合层状氧化物及磷酸铁锂的溶胶凝胶法合成.探讨了采用不同元素掺杂来提高比容量和循环稳定性的改性方法.提出了目前溶胶-凝胶法在锂离子电池正极材料制备中存在的问题,并展望了它未来的发展趋势.

参考文献

[1] 黄可龙;王兆翔;刘素琴.锂离子电池原理与关键技术[M].北京:化学工业出版社,2008
[2] 吴宇平;戴晓兵;马军旗.锂离子电池--应用与实践[M].北京:化学工业出版社,2004
[3] 马荣骏.锂离子电池及其正极材料的研究进展[J].有色金属,2008(01):1-6.
[4] 马莹.湿法工艺在锂离子电池材料制备中的应用[J].矿冶工程,2005(01):65-67.
[5] Kim Y;Hong Y;Kim M G et al.Li0.93[Li0.21 Co0.28Mn0[J].51]O2 nanoparticals for lithium battery cathode material made by cationic exchange from K-birnessite[J] Electrochem Commun,2007,9:1041.
[6] 林晓园,陈立宝,王太宏.共沉淀法制备LiNi0.5Mn1.5O4正极材料及其性能[J].电源技术,2010(07):644-646.
[7] 吴士超,郭云霞,周建华,赵建庆,丁晓春,何建平.高温热处理对水热离子交换法制备钛酸锂纳米棒的结构和性能影响[J].无机材料学报,2011(02):123-128.
[8] Yang M R;Teng T H;Wu S H .LiFePO4/carbon cathode materials prepared by ultrasonic spray pyrolysis[J].Journal of Power Sources,2006,159:307.
[9] 梁风,戴永年,姚耀春.模板法制备孔状锂离子电池电极材料[J].化学进展,2009(10):2060-2066.
[10] Kosova NV.;Devyatkina ET.;Avvakumov EG.;Uvarov NF. .Mechanochemical synthesis of LiMn2O4 cathode material for lithium batteries[J].Solid state ionics,2000(1/4):107-114.
[11] Balaji S;Muthsrasu D;Ramanathan K et al.A review on microwave synthesis of electrode materials for lithium-ion batteries[J].Ionics,2009,15:765.
[12] 黄剑锋.溶胶-凝胶原理与技术[M].北京:化学工业出版社,2005
[13] Liu H;Wu Y P;Rahm E et al.Cathode materials for lithium ion batteries prepared by sol-gel methods[J].Journal of Solid State Electrochemistry,2004,8:450.
[14] Fu L J;Liu H;Li C et al.Electrode materials for lithium secondary batteries prepared by sol-gel methods[J].Progress in Materials Science,2005,50:881.
[15] Zhu C Q;Yang C H;Yang W D et al.High performances of ultrafine and layered LiCoO2 powders for lithium batteries by a novel sol-gel process[J].Journal of Alloys and Compounds,2010,496:703.
[16] Castro S;Castro A;Soulette F et al.Influence of aluminum doping on the properties of LiCoO2 and LiNi0.5 Co0.5O2oxides[J].Solid-State Ionicis,2003,156:15.
[17] Tong D G;Luo Y Y;He Y et al.Effect of Ga dopingon the structural,electrochemical and thermal properties of LiCo0.975 Ga0.025 O2 as cathode materials for lithium ion batteries[J].Materials Science and Engineering B,2006,128:220.
[18] 王兆翔,陈立泉,黄学杰.锂离子电池正极材料的结构设计与改性[J].化学进展,2011(02):284-301.
[19] Park S H;Park K S;Cho M H et al.The effects of oxygen flow rate and anion doping on the performance of the LiNiO2 electrode for lithium secondary batteries[J].Korean Journal of Chemical Engineering,2002,19:791.
[20] Song MY.;Lee R.;Kwon I. .Synthesis by sol-gel method and electrochemical properties of LiNi1-yAlyO2 cathode materials for lithium secondary battery[J].Solid state ionics,2003(3):319-328.
[21] 吴楠,张乃庆,刘伶,孙克宁.锂离子电池正极材料层状LiMnO2的研究进展[C].功能材料(2006年全国功能材料学术年会:论文专辑),2006:408-410.
[22] Guo Z P;Konstantinov K;Wang G X et al.Preparation of orthorhombic LiMnO2 material via the sol-gel process[J].Journal of Power Sources,2003,119:221.
[23] 李志刚,康雪雅,王天雕,韩英.层状多元复合正极材料的研究进展[J].电子元件与材料,2006(12):12-15.
[24] Gopukumar S;Chung K Y;Kim K B .Novel synthesis of latered LiNi12 Mn1/2 O2 as cathode material for lithium rechargeable cells[J].Electrochimica Acta,2004,49:803.
[25] 钟清华,袁中直.层状的LiNi_(0.5)Mn_(0.5)O_2合成及其电化学性能[J].电源技术,2009(07):543-546.
[26] Shin S S;Sun Y K;Amine K .Synthesis and electrochemical properties of Li[Li(1-2x)/3 Nix Mn(2-x)/3]O2 as cathode materials for lithium secondary batteries[J].Journal of Power Sources,2002,112:634.
[27] Fey G T;Shiu R F;Subramanian V et al.LiNi0.8 Co0.2 O2cathode materials synthesized by the maleic acid assisted solgel method for lithium batteries[J].Journal of Power Sources,2002,103:265.
[28] Zhu, C.;Yang, C.;Yang, W.-D.;Wu, M.-S.;Ysai, H.-M.;Hsieh, C.-Y.;Fang, H.-L. .Preparation and electrochemical characterization of LiNi _(0.8)Co_(0.2)O_2 cathode material by a modified sol-gel method[J].Journal of Applied Electrochemistry,2010(9):1665-1670.
[29] Jouybari Y H;Asgari S .Synthesis and electrochemical properties of LiNi0.8 Co0.2O2 nanopowders for lithium ion battery applications[J].Journal of Power Sources,2011,196:337.
[30] Liu H S;Zhang Z R et al.The effects of sintering temperature and time on the structure and electrochemical performance of LiNi0.8 Co0.2 O2 cathode materials derived from solgel method[J].Journal of Solid State Electrochemistry,2003,7:456.
[31] Fey GTK.;Shiu RF.;Subramanian V.;Chen CL. .The effect of varying the acid to metal ion ratio R on the structural, thermal, and electrochemical properties of sol-gel derived lithium nickel cobalt oxides[J].Solid state ionics,2002(3/4):291-298.
[32] Gurpreet S;Anjan S;Sudipto G et al.Effect of citric acid content on synthesis of LiNi1/3 Co1/3 Mn1/3 O2 and its electrochemical characteristics[J].Ceramics International,2010,36:1831.
[33] Guo H J;Liang R F;Li X H et al.Effect of calcinations temperature on characteristics of LiNi1/3 Co1/3 Mn1/3 O2 cathode for lithium ion batteries[J].Transactions of Nonferrous Metals Society of China,2007,17:1307.
[34] Kim H S;Kim K T;Kim Y S et al.Effect of a surface treatment for LiNi1/3 Co1/3 Mn1/3O2 cathode material in lithium secondary batteries[J].Metals Mater Int,2008,14:105.
[35] Kim JH.;Park CW.;Sun YK. .Synthesis and electrochemical behavior of Li[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O-2 cathode materials[J].Solid state ionics,2003(1/2):43-49.
[36] Santhanam R;Philip J;Adusumilli S et al.Influence of lithium content on high rate cycleability of layered Li1+xNi0[J].30 Co0 30 Mn0 40 O2 cathodes for high power lithiumion batteries[J] J Power Sources,2010,195:7391.
[37] 何向明,王莉,张国昀,姜长印,万春荣.溶胶凝胶法合成锂离子电池正极材料LiMn2O4[J].电化学,2006(01):104-106.
[38] 胡拥军,李义兵,吴四贵.掺杂与表面包覆对尖晶石型LiMn2O4电化学性能的影响[J].化工进展,2007(04):563-566,576.
[39] Dragana Jugovic;Dragan Uskokovic .A review of recent developments in the synthesis procedures of lithium iron phosphate powders[J].Journal of Power Sources,2009(2):538-544.
[40] 林燕,高明霞,俞永标.溶剂与pH值对溶胶凝胶法制备LiFePO4/C的影响[J].电源技术,2010(08):782-785.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%