欢迎登录材料期刊网

材料期刊网

高级检索

以三甲基铝(TMA)和水为反应源,采用原子层沉积(ALD)技术在n型单晶硅表面沉积15 nm、30 nm和100 nm的Al2O3薄膜,并对样品进行快速退火(RTA)处理.采用少子寿命测试仪测试样品的有效少子寿命,获得了表面复合速率(SRV),通过X射线光电子能谱(XPS)分析了薄膜的化学成分,在此基础上研究了薄膜厚度及退火条件对钝化效果的影响,并分析了钝化机理.结果表明:ALD技术制备的Al2O3薄膜经退火后可使n型单晶硅SRV值降低到7 cm/s,表面钝化效果显著.

参考文献

[1] Kerr MJ.;Cuevas A. .Very low bulk and surface recombination in oxidized silicon wafers[J].Semiconductor Science and Technology,2002(1):35-38.
[2] Cuevas A;Stocks M;Armand S;Stuckings M;Blakers A;Ferrazza F .High minority carrier lifetime in phosphorus-gettered multicrystalline silicon[J].Applied physics letters,1997(8):1017-1019.
[3] Zhao J.;Green MA.;Wang AH. .24.5% efficiency PERT silicon solar cells on SEH MCZ substrates and cell performance on other SEH CZ and FZ substrates[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):27-36.
[4] Kerr MJ.;Cuevas A. .Recombination at the interface between silicon and stoichiometric plasma silicon nitride[J].Semiconductor Science and Technology,2002(2):166-172.
[5] Lauinger T;Schmidt J;Aberle A G et al.Record low surface recombination velocities on 1 Ω @ cm p-silicon using remote plasma silicon nnitride passivation[J].Applied Physics Letters,1996,68(09):1232.
[6] Stefan Dauwe;Lutz Mittelstadt;Axel Metz .Experimental Evidence of Parasitic Shunting in Silicon Nitride Rear Surface Passivated Solar Cells[J].Progress in photovoltaics,2002(4):271-278.
[7] B. Hoex;J. Schmidt;P. Pohl;M. C. M. van de Sanden;W. M. M. Kessels .Silicon surface passivation by atomic layer deposited Al_(2)O_(3)[J].Journal of Applied Physics,2008(4):044903-1-044903-12-0.
[8] Hoex B;Heil S;Langereis E et al.Ultralow surface recombination of c-Si substrates passivated by plasma-assisted stomic layer deposited Al2O3[J].Applied Physics Letters,2006,89:0421124.
[9] Agostinelli G;Delabie A;Vitanov P;Alexieva Z;Dekkers HFW;De Wolf S;Beaucarne G .Very low surface recombination velocities on p-type silicon wafers passivated with a dielectric with fixed negative charge[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(18/19):3438-3443.
[10] J. Schmidt;A. Merkle;R. Brendel .Surface Passivation of High-efficiency Silicon Solar Cells by Atomic-layer-deposited Al_2O_3[J].Progress in PhotoVoltaics,2008(6):461-466.
[11] Hoex, B.;van de Sanden, M.C.M.;Schmidt, J.;Brendel, R.;Kessels, W.M.M. .Surface passivation of phosphorus-diffused n ~+-type emitters by plasma-assisted atomic-layer deposited Al _2O _3[J].physica status solidi(RRL): rapid research letterse,2012(1):4-6.
[12] Dingemans G;Seguin R;Engelhart P et al.Silicon surface passivation by ultrathin Al2 O3 films synthesized by thermal and plasma atomic layer deposition[J].Phys Status Solidi (RRL)-Rapid Res Lett,2010,4(1-2):10.
[13] B. Hoex;J. J. H. Gielis;M. C. M. van de Sanden;W. M. M. Kessels .On the c-Si surface passivation mechanism by the negative-charge-dielectric Al_(2)O_(3)[J].Journal of Applied Physics,2008(11):113703-1-113703-7-0.
[14] Alexander MR.;Beamson G.;Thompson GE. .Characterization of the oxide/hydroxide surface of aluminium using x-ray photoelectron spectroscopy: a procedure for curve fitting the O 1s core level[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2000(7):468-477.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%