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  4. 光诱导钌配合物的几何异构和结构异构反应研究进展

影像科学与光化学 , 2012, 30(6): 401-410.

光诱导钌配合物的几何异构和结构异构反应研究进展

靳晓伟 1, , 王建茹 2, , 段青青 3, , 乔晓艳 4, , 王宏飞 5,

1.山西大学物理电子工程学院,山西太原030006

2.山西大学光电研究所,山西太原030006

3.山西大学光电研究所,山西太原030006

4.山西大学物理电子工程学院,山西太原030006

5.山西大学物理电子工程学院,山西太原030006;山西大学光电研究所,山西太原030006

基金项目:   山西省回国留学人员科研资助项目(2011-003;2011-017)  

关键词： 钌配合物 , 光反应 , 几何异构 , 结构异构 , 激发态 , 亚稳态

Photo-Induced Isomerization Reaction of Ruthenium Complexes

金属钌(Ru)的配合物具有丰富的基态和激发态的光物理、光化学性质,在太阳能转换、光催化以及分子识别等方面都得到了广泛深入的研究.光诱导的钌配合物的异构反应是其颇具特色的一类光反应,研究光异构反应对于光能量转化、信息储存以及“分子光开关”和“分子马达”的设计具有重要的意义.本文小结和综述了钌配合物的光诱导几何异构和结构异构反应的特性和机理以及最新的研究进展.

参考文献

[1] Chou C C;Wu K L;Chi Y et al.Ruthenium(Ⅱ) sensitizers with heteroleptic tridentate chelates for dye-sensitized solar cells[J].Angewandte Chemie International Edition in English,2011,50(09):2054-2058.
[2] Ito S;Zakeeruddin SM;Comte P;Liska P;Kuang DB;Gratzel M .Bifacial dye-sensitized solar cells based on an ionic liquid electrolyte[J].Nature photonics,2008(11):693-698.
[3] Zhang, A.-G.;Zhang, Y.-Z.;Duan, Z.-M.;Wang, K.-Z.;Wei, H.-B.;Bian, Z.-Q.;Huang, C.-H. .Dual molecular light switches for pH and DNA based on a novel Ru(II) complex. A non-intercalating Ru(II) complex for DNA molecular light switch[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2011(14):6425-6436.
[4] Lutterman DA;Chouai A;Liu Y;Sun Y;Stewart CD;Dunbar KR;Turro C .Intercalation is not required for DNA light-switch behavior[J].Journal of the American Chemical Society,2008(4):1163-1170.
[5] Gao F;Chao H;Ji L N .DNA binding,photocleavage,and topoisomerase inhibition of functionalized ruthenium (Ⅱ)-polypyridine complexes[J].CHEMISTRY & BIODIVERSITY,2008,5(10):1962-1979.
[6] Zhou, Q.;Lei, W.;Chen, Y.;Li, C.;Hou, Y.;Zhang, B.;Wang, X. .Ruthenium(II)-arene complexes with strong fluorescence: Insight into the underlying mechanism[J].Chemistry: A European journal,2012(28):8617-8621.
[7] 吴世康,汪鹏飞.有机-过渡金属配合物的三重态发光问题[J].影像科学与光化学,2011(02):81-98.
[8] Goulkov, M;Schaniel, D;Woike, T .Pulse recording of thermal and linkage isomer gratings in nitrosyl compounds[J].Journal of the Optical Society of America, B. Optical Physics,2010(5):927-932.
[9] Sylvester, S.O.;Cole, J.M.;Waddell, P.G. .Photoconversion bonding mechanism in ruthenium sulfur dioxide linkage photoisomers revealed by in situ diffraction[J].Journal of the American Chemical Society,2012(29):11860-11863.
[10] Cole, JM .Applications of photocrystallography: a future perspective[J].Zeitschrift fur Kristallographie,2008(4/5):363-369.
[11] Philip Coppens .The New Photocrystallography[J].Angewandte Chemie,2009(24):4280-4281.
[12] Durham B;Wilson S R;Hodgson D J et al.Cis-trans photoisomerization in Ru (bpy)2 (OH2)22+.Crystal structure of trans-[Ru(bpy)2(OH2)(OH)](C1O4)2[J].Journal of the American Chemical Society,1980,102(02):600-607.
[13] Hesek D.;Everitt SRL.;Inoue Y. .Conformational switching in the thermal and photochemical synthesis of cis- and trans-ruthenium bis(bipyridine) sulfoxide complexes[J].Chemistry Letters,1999(2):109-110.
[14] Wang H;Tomizawa H;Miki E .Photoirradiation reactions and crystal structures of two geometrical isomers of [Ru(OAc)(2cqn)(2)NO] (H2cqn=2-chloro-8-quinolinol)[J].Inorganica Chimica Acta,2004(14):4291-4296.
[15] Wang Hongfei;Hagihara Taiki .Electronic effects of the substituent group in 8-quinolinolato ligand on geometrical isomerism for nitrosylruthenium(II) complexes[J].Inorganica Chimica Acta,2000(1):80-90.
[16] Suganuma T;Tanada A;Tomizawa H et al.Relationship between pKa of 8-quinolinol derivatives and a πdonor ability of the 8-quinolinolato oxygen in linear nitrosylruthenium(Ⅱ) complexes[J].Inorganica Chimica Acta,2001,320(12):22-30.
[17] Wang H;Tomizawa H;Miki E .Novel thermal reactions of two geometrical isomers of[Ru(OAc)(2cqn)2NO](H2cqn=2-chloro-8-quinolinol)[J].Inorganica Chimica Acta,2001,321(12):215220.
[18] Wang H;Miki E;Re S et al.Molecular geometries,vibrational analysis,bonding and molecular orbitals of the three isomers of[RuC1 (qn) 2 NO](Hqn=2-methyl-8-quinolinol or 2-chloro-8-quinolinol):density functional theory studies[J].Inorganica Chimica Acta,2002,340:119-126.
[19] Wang HF.;Onozuka T.;Tomizawa H.;Tanaka M.;Miki E. .The unexpected reactions of [RuCl3(2mqn)NO](-)(H2mqn=2-methyl-8-quinolinol) with 2-chloro-8-quinolinol (H2cqn) and of [RuCl(2cqn)(2mqn)NO] on photoirradiation[J].Inorganica Chimica Acta,2004(4):1303-1308.
[20] Harada F;Onozuka T;Tomizawa H;Tanaka M;Miki E .Substituent effect of 8-quinolinolato ligands on photo-induced isomerization for linear nitrosylruthenium(II) complexes - Experimental study[J].Inorganica Chimica Acta,2006(2):665-672.
[21] Yamazaki, H.;Hakamata, T.;Komi, M.;Yagi, M. .Stoichiometric photoisomerization of mononuclear ruthenium(II) monoaquo complexes controlling redox properties and water oxidation catalysis[J].Journal of the American Chemical Society,2011(23):8846-8849.
[22] M. D. Carducci;M. R. Pressprich;P. Coppens .Diffraction Studies of Photoexcited Crystals: Metastable Nitrosyl-Linkage Isomers of Sodium Nitroprusside[J].Journal of the American Chemical Society,1997(11):2669-2678.
[23] Thomas E. Bitterwolf .Photochemical nitrosyl linkage isomerism/metastable states[J].Coordination chemistry reviews,2006(9/10):1196-1207.
[24] Michael J. Rose;Pradip K. Mascharak .Photoactive ruthenium nitrosyls: Effects of light and potential application as NO donors[J].Coordination chemistry reviews,2008(18/20):2093-2114.
[25] Morioka Y.;Tomizawa H.;Miki E.;Ishikawa A. .Light-induced metastable states in nitrosyl-ruthenium complexes containing ethylenediamine and oxalate ion ligands[J].Journal of the Chemical Society, Dalton Transactions.Inorganic Chemistry,2000(5):781-786.
[26] Kawano M.;Morioka Y.;Tomizawa H.;Miki EI.;Ohashi Y.;Ishikawa A. .X-Ray diffraction and spectroscopic studies of the light-induced metastable state of a ethylenediamine nitrosyl ruthenium complex[J].Journal of the Chemical Society, Dalton Transactions.Inorganic Chemistry,2000(14):2425-2431.
[27] Schaniel D;Cormary B;Malfant I;Valade L;Woike T;Delley B;Kramer KW;Gudel HU .Photogeneration of two metastable NO linkage isomers with high populations of up to 76% in trans-[RuCl(py)(4)(NO)][PF6](2) center dot 1/2H(2)O[J].Physical chemistry chemical physics: PCCP,2007(28):3717-3724.
[28] Giglmeier H;Kerscher T;Klufers P.Nitric-oxide photorelease and photoinduced linkage isomerism on solid[Ru(NO)(terpy)(L)]BPh4(L=glycolate dianion)[J].Dalton Transactions,2009(42):9113-9116.
[29] Dominik Schaniel;Nicholas Mockus;Theo Woike .Reversible photoswitching between nitrito-N and nitrito-O isomers in trans-[Ru(py)4(NO2)2][J].Physical chemistry chemical physics: PCCP,2010(23):6171-6178.
[30] Vandenburgh L;Buck MR;Freedman DA .Preparation, Separation, and Characterization of Ruthenium(II) Thiocyanate Linkage Isomers[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2008(20):9134-9136.
[31] Brewster, T.P.;Ding, W.;Schley, N.D.;Hazari, N.;Batista, V.S.;Crabtree, R.H. .Thiocyanate linkage isomerism in a ruthenium polypyridyl complex[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2011(23):11938-11946.
[32] Kovalevsky AY.;Bagley KA.;Coppens P. .The first photocrystallographic evidence for light-induced metastable linkage isomers of ruthenium sulfur dioxide complexes[J].Journal of the American Chemical Society,2002(31):9241-9248.
[33] Keating C S;McClure B A;Rack J J et al.Mode coupling pattern changes drastically upon photoisomerization in Ru Ⅱ complex[J].Journal of Physical Chemistry C,2010,117(39):16740-16745.
[34] Rachford D A;Rack J J;Turro C .Mode coupling pattern changes drastically upon photoisomerization in Ru Ⅱ complex[J].J Phys Chem Lett,2010,1(39):3371-3375.
[35] Yuhuan Jin;Shadrick I. M. Paris;Jeffrey J. Rack .Bending Materials with Light: Photoreversible Macroscopic Deformations in a Disordered Polymer[J].Advanced Materials,2011(37):4312-4317.
[36] McClure, BA;Abrams, ER;Rack, JJ .Excited State Distortion in Photochromic Ruthenium Sulfoxide Complexes[J].Journal of the American Chemical Society,2010(15):5428-5436.
[37] McClure, B.A.;Rack, J.J. .Ultrafast spectroscopy of a photochromic ruthenium sulfoxide complex[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2011(16):7586-7590.
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