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以γ-氨丙基三甲氧基硅烷(γ-APS)为前驱体,采用溶胶-凝胶法制备硅烷溶液,并采用浸涂法在纯镁表面制备有机-无机杂化腐蚀保护膜。金相显微镜对有机-无机杂化膜的表面形貌观察表明,有机-无机杂化膜比铬钝化膜更均匀致密;对有机-无机杂化膜进行动电位极化曲线测定及试验后的显微形貌表明,与铬钝化膜相比,有机-无机杂化膜的自腐蚀电位更正,腐蚀电流密度更小,耐腐蚀性能更好。且有机-无机杂化膜无污染。该工艺可以有效取代铬钝化工艺。

Using γ-aminopropyltrimethoxysilane (γ-APS) as precursor, silane solution was prepared by sol-gel method, and then the organic-inorganic duplex protecting coating on Mg was prepared by Mg dipped into the silane solution. The surface morphology of the organic-inorganic hybrid coating was observed by metallographic microscopy. The results show that the organic-inorganic duplex protecting coating is smooth and more adhesive than the chromate film. Potentiodynamic polarization curve measurement and metallographic microscopy results show that the corrosion potential of the organic-inorganic duplex protecting coating is higher and corrosion current is smaller than those of the chromate film, and thus the coating possesses better anti-corrosion performance. The organic-inorganic duplex protecting coatings is environmentally friend. The suggested process can replace the chromate process effectively.

参考文献

[1] In situ ellipsometric studies of formation kinetics of rare earth metal conversion coatings on magnesium alloy[J].Physica status solidi, C. Current topics in solid state physics: PSS,2008(5):1308-1311.
[2] 刘琰,尤宏,胡立江,张小明,孙德智.VMS有机-无机杂化膜的制备及其防腐性能研究[J].哈尔滨工业大学学报,2005(10):1344-1347.
[3] 郭增昌,王云芳,王汝敏,熊艳丽.铝合金表面防腐蚀处理新工艺[J].材料保护,2005(04):25-27.
[4] Danqing Zhu;Wim J. van Ooij .Corrosion protection of AA 2024-T3 by bis-[3-(triethoxysilyl)propyl]tetrasulfide in sodium chloride solution. Part 2: mechanism for corrosion protection[J].Corrosion Science,2003(10):2177-2197.
[5] Zhu DQ.;van Ooij WJ. .Corrosion protection of metals by water-based silane mixtures of bis-[trimethoxysilylpropyl]amine and vinyltriacetoxysilane [Review][J].Progress in Organic Coatings: An International Review Journal,2004(1):42-53.
[6] Palanivel V.;Zhu DQ.;van Ooji WJ. .Nanoparticle-filled silane films as chromate replacements for aluminum alloys[J].Progress in Organic Coatings: An International Review Journal,2003(3/4):384-392.
[7] 赵惠,崔建忠.镁及其合金表面化学镀银工艺的研究[J].表面技术,2007(04):45-48.
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