以人造棉布为原料,经(NH4)2HPO4浸渍后炭化、石墨化处理制备柔性的碳布材料.研究了浸渍液对人造棉布炭化历程的影响,以及碳布收率、电阻率、拉伸强度、断裂伸长率的变化规律.结果表明,经过(NH4)2HPO4的浸渍,碳布的炭化收率从11.3％提高到31.3％;电阻率有明显下降,石墨化后碳布的电阻率降为0.068Ω·cm;断裂伸长率为14.7％.同时具有良好的透气性能和一定的强度,可用于燃料电池气体扩散层材料.
参考文献
| [1] | Yuan-Kai Liao;Tse-Hao Ko;Ching-Han Liu .Performance of a Polymer Electrolyte Membrane Fuel Cell with Fabricated Carbon Fiber Cloth Electrode[J].Energy & Fuels,2008(5):3351-3354. |
| [2] | S. Litster;G. McLean .PEM fuel cell electrodes[J].Journal of Power Sources,2004(1/2):61-76. |
| [3] | Aguiar P;Adjiman C S;Brandon N P .Anode-supported intermediate temperature direct internal reforming solid oxide fuel cell.I:model-based steady state performance[J].Journal of Power Sources,2004,138(1-2):120-136. |
| [4] | Xuejun Zhang;Zengmin Shen .Carbon fiber paper for fuel cell electrode[J].Fuel,2002(17):2199-2201. |
| [5] | Yasuda E;Tanabe Y;Manocha L M et al.Matrix modification by graphite powder additives in carbon fiber/carbon composite with thermosetting resin precursor as a matrix[J].Carbon,1988,26(02):225-227. |
| [6] | Y. Bultel;K. Wiezell;F. Jaouen;P. Ozil;G. Lindbergh .Investigation of mass transport in gas diffusion layer at the air cathode of a PEMFC[J].Electrochimica Acta,2005(3):474-488. |
| [7] | Sekoh H;Okamotoh H;Ishiim .Method for manufacturing carbon sheet[P].US:B1,6331224,2001-12-18. |
| [8] | Hiroshi K .Gas diffusion layer for solid polymer electrolyte fuel cell[P].US:6127059,2000-10-3. |
| [9] | 贺福;赵建国;王润娥 .粘胶基碳纤维[J].化工新型材料,1999,27(01):3-10. |
| [10] | Jordan L R;Shukla A K;Behrsing T et al.Diffusion layer parameters influencing optimal fuel cell performance[J].Journal of Power Sources,2000,86:250-254. |
| [11] | 黄乃科,王曙中,李灵忻.质子交换膜燃料电池电极用气体扩散层材料[J].电源技术,2003(03):329-332. |
| [12] | James L;Andrew D.Fuel cell systems explained[M].England:John Wiley & Sons,Ltd,2000:66-69. |
| [13] | Junru Tan;Lazhen Shen;Xiansong Fu;Wenxiang Hou;Xiuzeng Chen .Preparation and conductive mechanism of mica titania conductive pigment[J].Dyes and Pigments,2004(2):107-114. |
| [14] | Yan-Long Tai;Zhen-Guo Yang;Zhi-Dong Li .A promising approach to conductive patterns with high efficiency for flexible electronics[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(16):7096-7100. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%