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  4. 过渡金属催化烯烃聚合

高分子材料科学与工程, 2006, 22(3): 1-5.

过渡金属催化烯烃聚合

陈正军 1,

1.中国科学院研究生院长春应用化学研究所,吉林,长春,130022

关键词： 烯烃聚合催化剂 , 链增长 , 链转移 , 链终止 , 失活过程

TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION

论述了烯烃聚合催化剂的发展更新过程,催化聚合的过程.涉及配位聚合的链增长机理、单体几种可能的插入模式及聚合的立构控制方式、链转移或链终止机理以及可能存在的催化活性中心的失活过程.对于过渡金属催化烯烃聚合的理解有助于催化剂设计的理性化.

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