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通过手标本观察、探针片镜下鉴定、XRD分析、扫描电镜分析等手段对黔北务川?正安?道真地区铝土矿的矿物学特征和地球化学特征进行研究。务正道铝土矿主要矿物为硬水铝石、高岭石、绿泥石、伊利石,次要矿物为软水铝石与黄铁矿,铝土矿常量元素以Al 2 O 3、SiO 2和TFe 2 O 3为主,MgO和TiO 2含量次之。风化过程中Zr、Cr、V、Li等微量元素明显富集,Zr和Hf以及Nb和Ta 呈高度正相关关系。微量元素比值表明:务正道铝土矿是以韩家店组页岩为主,黄龙组灰岩为辅,并有其余物源混入的多物源体系。

The mineralogical and geochemical characteristics of the bauxite in Wuchuan-Zheng’an-Daozhen area were investigated through the handle specimen observation, thin section analysis, XRD and SEM. The mineral analyses reveal that diaspore, kaolinite, chlorite and illite are the major minerals in the bauxite with small amounts of boehmite and pyrite. Geochemical investigations reveal that the main components in the bauxite are Al 2 O 3 , SiO 2 and TFe 2 O 3 , the minor components, are MgO and TiO 2 . In the process of weathering, some trace elements, such as Zr, Cr, V and Li, are enriched. Zr vs Hf and Nb vs Ta display the highest positive correlation. Trace elements show that Hanjiadian Formation is the main source of material for the bauxite formation, Huanglong Formation is the second important parent rock and there may be exist other precursor rock provide few material for the bauxite formation.

参考文献

[1] LASKOU M .Concentration of rare earths in Greek bauxite[J].Acta Geological Hungarica,1991,34(04):195-404.
[2] EVANS A M.Ore geology and industrial minerals-An introduction[M].London:Blackwell,1993:386-389.
[3] Ali Asghar Calagari;Ali Abedini .Geochemical investigations on Permo-Triassic bauxite horizon at Kanisheeteh,east of Bukan,West-Azarbaidjan,Iran[J].Journal of Geochemical Exploration: Journal of the Association of Exploration Geochemists,2007(1/3):1-18.
[4] 武国辉,金中国,鲍淼,毛佐林.黔北务正道铝土矿成矿规律探讨[J].地质与勘探,2008(06):31-35.
[5] 金中国,武国辉,赵远由,苏之良.贵州务川瓦厂坪铝土矿床地质特征[J].矿产与地质,2009(02):137-141.
[6] 殷科华.黔北务正道铝土矿的成矿作用及成矿模式[J].沉积学报,2009(03):452-457.
[7] 韩忠华.贵州道真县大塘铝土矿沉积相特征[J].矿产与地质,2008(05):428-432.
[8] 雷志远,廖友常.黔北大竹园铝土矿矿床地质特征及成因浅析[J].西部探矿工程,2007(09):94-97.
[9] 赵远由 .贵州省务川县瓦厂坪铝土矿矿床地质特征[D].昆明:昆明理工大学,2007.
[10] 刘平.三论贵州之铝土矿--贵州北部铝土矿成矿时代、物质来源及成矿模式[J].贵州地质,1993(02):105.
[11] 金中国,武国辉,黄智龙,鲍淼,周家喜.贵州务川瓦厂坪铝土矿床地球化学特征[J].矿物学报,2009(04):458-462.
[12] 梁同荣;廖士范 .贵州北部铝土矿床成矿地质条件、机制问题[J].沉积学报,1989,7(04):57-67.
[13] 刘平.八论贵州之铝土矿--黔中-渝南铝土矿成矿背景及成因探讨[J].贵州地质,2001(04):238-243.
[14] 杜定全,任军平,王约,刘幼平,龚和强,郝家栩.古岩溶起伏对黔北铝土矿的控制作用[J].矿物学报,2007(03):473-476.
[15] 武国辉,刘幼平,张应文.黔北务-正-道地区铝土矿地质特征及资源潜力分析[J].地质与勘探,2006(02):39-43.
[16] 刘平.黔北务-正-道地区铝土矿地质概要[J].地质与勘探,2007(05):29-33.
[17] 郝家栩,杜定全,王约,刘幼平,龚和强,任军平.黔北铝土矿含矿岩系的沉积时代研究[J].矿物学报,2007(03):466-472.
[18] 黄兴,张雄华,杜远生,覃永军,翁申富,雷志远,郄文昆,蒋涛.黔北地区铝土矿形成的地质时代[J].地质科技情报,2012(03):49-54.
[19] 崔滔,焦养泉,杜远生,计波,雷志远,翁申富,金中国,赵爽.黔北务正道地区铝土矿沉积特征及分布规律[J].地质科技情报,2013(01):52-56.
[20] Qingfei Wang;Jun Deng;Xuefei Liu;Qizuan Zhang;Silei Sun;Chengzhu Jiang;Fang Zhou .Discovery of the REE minerals and its geological significance in the Quyang bauxite deposit, West Guangxi, China[J].Journal of Asian earth sciences,2010(6):701-712.
[21] MACLEAN W H;KRANIDIOTIS P .Immobile elements as monitors of mass transfer in hydrothermal alteration:Phelps Dodge massive sulfide deposit,Matagami,Quebec[J].Economic Geology,1987,82:951-962.
[22] MACLEAN W H;BARRETT T J .Lithogeochemical techniques using immobile elements[J].Geochemical Exploration,1993,48:109-133.
[23] Andrew C. Kurtz;Louis A. Derry;Oliver A. Chadwick;Mary Jo Alfano .Refractory element mobility in volcanic soils[J].Geology,2000(8):683-686.
[24] Panahi A.;Rainbird RH.;Young GM. .Behavior of major and trace elements (including REE) during Paleoproterozoic pedogenesis and diagenetic alteration of an Archean granite near Ville Marie, Quebec, Canada[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,2000(13):2199-2220.
[25] VALETON I;BIERMANN M;RECHE R;ROSENBERG F.Genesis of nickel laterites and bauxites in Greece during the Jurassic and Cretaceous,and their relation to ultrabasic parent rocks[J].Ore Geology Reviews,1987:359-404.
[26] MACLEAN W H .Mass change calculations in altered rock series[J].Mineralium Deposita,1990,25:44-49.
[27] SCHROLL E;SAUER D.Beitrag zur geochemie von titan, chrom, nikel, cobalt, vanadium undmolibdan in bauxitischen gestermenund problem der stofflichen herkunft des aluminiums[A].Amsterdam:Elsevier,1968:83-96.
[28] FOX G S.Bauxite and aluminous laterite[M].London:Technical Press,1932:19-26.
[29] CONDIE K C .Another look at REEs in shales[J].Geochimica et Cosmochimica Acta,1991,55:2527-2531.
[30] HOLMES A .Laterites and bauxites of Antrim[J].NATURE,1954,173:812-813.
[31] BUSHINSKY G I.Case of natural bleaching of bauxites[A].Amsterdam:Elsevier,1968:17-30.
[32] VALETON I.Bauxites development in soil sciences[M].Amsterdam:Elsevier,1972:222-226.
[33] BáRDOSSY G.Karst bauxites,bauxite deposits on carbonate rocks[M].London:Developments in Economic Geology,1982:320-332.
[34] D'ARGENIO B;MINDSZENTY A .Bauxites and related paleokarst:tectonic and climatic event markers at regional unconformities[J].Eclogae Geologica Helvetiae,1995,88(03):453-499.
[35] Sedat Temur;Guersel Kansun .Geology and petrography of the Masatdagi diasporic bauxites, Alanya, Antalya, Turkey[J].Journal of Asian earth sciences,2006(4):512-522.
[36] GORECKY Y K;LAVROVICH N S;LYUBIMOV A B.Bauxite[M].Moscow:Gosgeoltekhizdat,1949:185-186.
[37] ERVIN JR S;OSBORN E F .The system Al 2 O 3-H 2 O[J].The Journal of Geology,1951,59:381-394.
[38] KENNEDY G .Phase relations in the system Al 2O3-H2 O at high temperatures and pressures[J].American Journal of Science,1959,257:563-573.
[39] KELLER W D.The principles of chemical weathering.lucas brothers publ[M].Columbia:Missouri,1962:111-126.
[40] VALETON I;AMSTUTZ G C.Problems of boehmite and diasporic bauxites in sedimentology and ore genesis[M].Amsterdam:Elsevier,1964:123-129.
[41] NIA R .On the importance of sampling for method is hen genetic studies of bauxite-bearing on equip example of the upper cretaceous bauxites of the Parnassos zone Kiona griechlands[J].Mineralium Deposita,1968,3(04):368-374.
[42] NIA R.Genesis of boehmite and diaspore in greek upper cretaceous bauxites of the parnassos-kiona zone proc[A].Amsterdam:Elsevier,1971:69-98.
[43] KITTRICK J A .Soil minerals in the Al 2 O 3-SiO 2-H 2 O system and a theory of their formation[J].Clays and clay minerals,1969,17(02):157-167.
[44] KELLER W D;STEVENS R P .Physical arrangement of high-alumina clay types in a Missouri clay deposit and implications for their genesis[J].Clays and clay minerals,1983,31:422-434.
[45] ZLü N.New facts on diaspore genesis in the Akseki-Seydisehir bauxite deposit(Western Taures,Turkey)[A].London,1985:53-62.
[46] 布申斯基.铝土矿地质学[M].北京:地质出版社,1984:129-130.
[47] DANGI?A .Kaolinization of bauxite:A study in the Vlasenice bauxite area, Yugoslavia.Ⅰ. Alteration of matrix[J].Clays and clay minerals,1985,33(06):517-524.
[48] GOLDMAN M I.Petrography of bauxite surrounding a core of kaolinized nepheline syenite in Arkansas[J].Economic Geology Bulletin of the Society of Economic Geologists,1955:586-609.
[49] GOLDMAN M I;TRACEY J I J .Relation of bauxite and kaolin in the Arkansas bauxite deposits[J].Economic Geology,1964,14:567-575.
[50] KELLER W D;CLARKE O M J .Resilication of bauxite at the Alabama Street Mine,Saline County,Arkansas,illustrated by scanning electron micrographs[J].Clays and clay minerals,1984,32:139-146.
[51] 刘巽锋;王庆生;陈有能.黔北铝土矿成矿地质特征及成矿规律[M].贵阳:贵阳人民出版社,1990:135-138.
[52] ZTüRK H;HEIN J .Genesis of the Do?nkuzu and Morta?Bauxite Deposits,Taurides,Turkey:Separation of Al,Fe and Mn and implications for passive margin metallogeny[J].Economic Geology,2002,97:1063-1077.
[53] M.Laskou;M.Economou-Eliopoulos .The role of microorganisms on the mineralogical and geochemical characteristics of the Parnassos-Ghiona bauxite deposits,Greece[J].Journal of Geochemical Exploration: Journal of the Association of Exploration Geochemists,2007(2):67-77.
[54] BERNER R A .Authigenic mineral formation resulting from organic matter decomposition in modern sediments[J].FORTSCHRITTE DER MINERALOGIE,1981,59:117-135.
[55] GERMAN-HEINS J .Iron-rich encrustation on the footwall of the Gánt bauxite(Vértes Hills,Hungary)-Evidence forpreservation of organic matter under exceptional conditions[J].Sedimentary Geology,1994,94:73-83.
[56] Stavros Kalaitzidis;George Siavalas;Nikos Skarpelis .Late Cretaceous coal overlying karstic bauxite deposits in the Parnassus-Ghiona Unit, Central Greece: Coal characteristics and depositional environment[J].International Journal of Coal Geology,2010(4):211-226.
[57] ALTSCHULER Z S;SCHNEPFE M M;SILBER C C;SIMON F O .Sulfur diagenesis in everglades peat and origin of pyrite in coal[J].SCIENCE,1983,221:221-227.
[58] 崔滔,焦养泉,杜远生,余文超,计波,雷志远,翁申富,金中国,和秀林.黔北务正道地区铝土矿形成环境的古盐度识别[J].地质科技情报,2013(01):46-51.
[59] ZLü N .Trace element contents of karst bauxites and their parent rocks in the Mediterranean belt[J].Mineralium Deposita,1983,18:469-476.
[60] LAPPARENT F .Geological reasons for the formation of three natural aluminum hydroxides[J].International Congress of Mines,1935,7(02):375-381.
[61] COMBES J P.Recherches sur la genese des bauxites dans le Nord-Est de l'Espagne,le Languedoc et l'Ariege(france)-Mém[J].Centre Etudes Rech Geol Hydrogeol Montpellier,1969:340-342.
[62] COMBES J P .Regards sur1a géologie des bauxites:aspects récents surla génese de quelques gisements àsubstratum carbonate[J].Bulletin des Centres de Recherches Exploration-Production Elf-Aquitaine,1984,8:251-274.
[63] KOMLOSSY G Y.The Iszkaszentgy?rgy bauxite[A].Amsterdam:Elsevier,1970:347-358.
[64] KOMLOSSY G Y .Paleogeographic implications of karst bauxite genesis[J].The International Committee for Study of Bauxite Alumina&Aluminium Travaux,1985,19(03):15-22.
[65] MINDSZENTY A .The lithology of some Hungarian bauxites:A contribution of the paleogeographic reconstruction[J].Acta Geologica Academiae Scientiarum Hungaricae,1984,27(34):441-455.
[66] MINDSZENTY A;D’ARGENIO B;BOGNAR L .Cretaceous bauxites of Austria and Hungary:Lithology and paleotectonic implications[J].The International Committee for study of Bauxite Alumina&Aluminium Travaux,1986,16(06):13-39.
[67] Xuefei Liu;Qingfei Wang;Jun Deng .Mineralogical and geochemical investigations of the Dajia Salento-type bauxite deposits, western Guangxi, China[J].Journal of Geochemical Exploration: Journal of the Association of Exploration Geochemists,2010(3):137-152.
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