静电纺丝是一种新型的非纺织成丝技术,具有适用材料体系广泛、纤维尺寸结构可控、工艺简便等特点,是制备连续纳米纤维的重要方法.静电纺丝技术制备的纳米纤维薄膜因具有巨大的纳米表面和网状孔隙结构可调等优势,在超级电容器领域显示出诱人的应用前景.综述了近年来静电纺丝技术在超级电容器电极材料和隔膜材料方面的研究进展,介绍了碳基、金属氧化物和聚合物电极材料高活性纳米纤维的制备方法及电化学行为,以及静电纺丝无纺布作为隔膜材料显示出的巨大优势,并总结了制约静电纺丝走向商业化的不利因素,如产率低、薄膜强度不足、喷丝不稳定等,最后介绍了近年来静电纺丝技术在结构可控、规模化制备的产业进展,并展望了其在超级电容器领域中的商业化应用前景.
参考文献
| [1] | C. Portet;P. L. Taberna;P. Simon;E. Flahaut;C. Laberty-Robert .High power density electrodes for Carbon supercapacitor applications[J].Electrochimica Acta,2005(20):4174-4181. |
| [2] | S. R. Sivakkumar;Jang Myoun Ko;Dong Young Kim;B. C. Kim;G. G. Wallace .Performance evaluation of CNT/polypyrrole/MnO{sub}2 composite electrodes for electrochemical capacitors[J].Electrochimica Acta,2007(25):7377-7385. |
| [3] | Lee S I;Mitani S;Park C W et al.Electric double-layer capacitance of microporous carbon nano spheres prepared through precipitation of aromatic resin pitch[J].Journal of Power Sources,2005,139(1-2):379. |
| [4] | A. G. Pandolfe;A. F. Hollenkamp .Carbon properties and their role in supercapacitors[J].Journal of Power Sources,2006(1):11-27. |
| [5] | Hall P J;Mirzaeian M;Fletcher S I et al.Energy storage in electrochemical capacitors:Designing functional materials to improve performance[J].Energy & Environmental Science,2010,3(09):12538. |
| [6] | K. Tonurist;A. Janes;T. Thomberg .Influence of Mesoporous Separator Properties on the Parameters of Electrical Double-Layer Capacitor Single Cells[J].Journal of the Electrochemical Society,2009(4):A334-A342. |
| [7] | R. Kotz;M. Carlen .Principles and applications of electrochemical capacitors[J].Electrochimica Acta,2000(15/16):2483-2498. |
| [8] | Burke A .Ultracapacitors:Why,how,and where is the technology[J].Journal of Power Sources,2000,91(01):37. |
| [9] | Li D;McCann JT;Xia YN .Electrospinning: A simple and versatile technique for producing ceramic nanofibers and nanotubes[J].Journal of the American Ceramic Society,2006(6):1861-1869. |
| [10] | Hunley MT;Long TE .Electrospinning functional nanoscale fibers: a perspective for the future[J].Polymer international,2008(3):385-389. |
| [11] | C. Feng;K. C. Khulbe;T. Matsuura .Recent Progress in the Preparation, Characterization,and Applications of Nanofibers and Nanofiber Membranes via Electrospinning/Interfacial Polymerization[J].Journal of Applied Polymer Science,2010(2):756-776. |
| [12] | Thavasi V;Singh G;Ramakrishna S .Electrospun nanofibers in energy and environmental applications[J].Energy & Environmental Science,2008,1(02):205. |
| [13] | Yi S P;Zhang H Y;Pei L et al.The electrochemical hydrogen storage of CNTs synthesized by CVD using LaNi5 alloy particles as catalyst and treated with different temperature in nitrogen[J].Journal of Alloys and Compounds,2006,420(1-2):312. |
| [14] | 刘颖,詹亮,张睿,乔文明,梁晓怿,凌立成.印刻法制备中间相沥青基中孔炭[J].新型炭材料,2007(03):259-263. |
| [15] | Kim, C;Ngoc, BTN;Yang, KS;Kojima, M;Kim, YA;Kim, YJ;Endo, M;Yang, SC .Self-sustained thin webs consisting of porous carbon nanofibers for supercapacitors via the electrospinning of polyacrylonitrile solutions containing zinc chloride[J].Advanced Materials,2007(17):2341-2346. |
| [16] | Ji L W et al.Porous carbon nanofibers from electrospun polyacrylonitrile/SiO2 composites as an energy storage material[J].CARBO,2009,47(08):3346. |
| [17] | Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning[J].Applied physics letters,2003(6):1216-1218. |
| [18] | Kim C;Park S H;Lee W J et al.Characteristics of supercapaitor electrodes of PBI-based carbon nanofiber web prepared by electrospinning[J].Electrochimica Acta,2004,50(2-3):877. |
| [19] | Im JS;Park SJ;Lee YS .Preparation and characteristics of electrospun activated carbon materials having meso- and macropores[J].Journal of Colloid and Interface Science,2007(1):32-37. |
| [20] | S.K. Nataraj;B.H. Kim;Marilou dela Cruz;J. Ferraris;T.M. Aminabhavi;K.S. Yang .Free Standing Thin Webs Of Porous Carbon Nanofibers Of Polyacrylonitrile Containing Iron-oxide By Electrospinning[J].Materials Letters,2009(2):218-220. |
| [21] | Li Li Zhang;Rui Zhou;X. S. Zhao .Graphene-based materials as supercapacitor electrodes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(29):5983-5992. |
| [22] | Li J;Liu E H;Li W et al.Nickel/carbon nanofibers composite electrodes as supercapacitors prepared by electrospinning[J].Journal of Alloys and Compounds,2009,478(1-2):371. |
| [23] | Qiaohui Guo;Xiaoping Zhou;Xiaoyan Li .Supercapacitors based on hybrid carbon nanofibers containing multiwalled carbon nanotubes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(18):2810-2816. |
| [24] | Ju Y W;Choi G R;Jung H R et al.Electrochernieal properties of electrospun PAN/MWCNT carbon nanofibers electrodes coated with polypyrrole[J].Electrochimica Acta,2008,53(19):5796. |
| [25] | Young-Wan Ju;Seok-Hwan Park;Hong-Ryun Jung .Electrospun Activated Carbon Nanofibers Electrodes Based on Polymer Blends[J].Journal of the Electrochemical Society,2009(6):A489-A494. |
| [26] | Rowlands S;Latham R;Schlindwein W .Supercapacitor devices using porous silicon electrodes[J].IONICS,1999,5(01):144. |
| [27] | Du C W;Li T Q;Chen M M .Studies on the performances of silica aerogel electrodes for the application of supercapacitor[J].IONICS,2009,15(01):561. |
| [28] | A novel carbon-silicon composite nanofiber prepared via electrospinning as anode material for high energy-density lithium ion batteries[J].Journal of Power Sources,2010(15):p.5052. |
| [29] | Hu Z A;Xie Y L;Wang Y X et al.Polyaniline/SnO2 nanocomposite for supercapacitor applications[J].Materials Chemistry and Physics,2009,114(2-3):990. |
| [30] | Mallouki M;Tran-Van F;Sarrazin C;Simon P;Daffos B;De A;Chevrot C;Fauvarque J .Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage[J].Journal of solid state electrochemistry,2007(3):398-406. |
| [31] | Young-Wan Ju et al.Preparation of RuO2/PAN-based carbon nanofiber web by co-electrospinning and its electrochemical property[J].Applied Geochemistry,2005,9(01):53. |
| [32] | Gyoung-Rin Choi et al.Preparation of manganese/PANbased carbon nanofiber web by co-electrospinning[J].Applied Geochemistry,2005,9(01):49. |
| [33] | Young-Wan Ju;Hong-Ryun Jung;Chan Kim et al.Preparation of Ru/PAN-based carbon/MWCNT nanofiber composite web electrode by co-electrospinning[J].Theories Appl Chem Eng,2005,11(02):2533. |
| [34] | L. Wang;Y. Yu;P.C. Chen;D.W. Zhang;C.H. Chen .Electrospinning Synthesis Of C/fe_3o_4 Composite Nanofibers And Their Application For High Performance Lithium-ion Batteries[J].Journal of Power Sources,2008(2):717-723. |
| [35] | Abdul-Majeed Azad .Fabrication of yttria-stabilized zirconia nanofibers by electrospinning[J].Materials Letters,2006(1):67-72. |
| [36] | Zou L;Ruitao L;Wang M X.A film of porous carbon nanofibers that contain Sn/SnOx nanoparticles in the pores and its electrochemical performance as an anode material for lithium ion batteries[J].CARBO,2010 |
| [37] | Qiu Y;Yu J;Zhou X et al.Synthesis of porous NiO and ZnO submicro-and nanofibers from electrospun polymer fiber templates[J].Nanoscale Research Letters,2009,4(02):173. |
| [38] | Hai Ying Wang,Yang Yang,Xiang Li,Li Juan Li,Ce Wang.Preparation and characterization of porous TiO2/ZnO composite nanofibers via electrospinning[J].中国化学快报（英文版）,2010(09):1119-1123. |
| [39] | Kang TS;Lee SW;Joo J;Lee JY .Electrically conducting polypyrrole fibers spun by electrospinning[J].Synthetic Metals,2005(1/3):61-64. |
| [40] | Alexis Laforgue .All-textile flexible supercapacitors using electrospun poly(3,4-ethylenedioxythiophene)nanofibers[J].Journal of Power Sources,2011(1):559-564. |
| [41] | Neburchilov V;Martin J;Wang H J et al.A review of polymer electrolyte membranes for direct methanol fuel cells[J].Journal of Power Sources,2007,169(02):221. |
| [42] | Cho T H;Tanaka M;Onishi H et al.Battery performances and thermal stability of polyacrylonitrile nano-fiberbased nonwoven separators for Li-ion battery[J].Journal of Power Sources,2008,181(01):155. |
| [43] | Choi S S;Lee Y S;Joo C W et al.Electrospun PVDF nanofiber web as polymer electrolyte or separator[J].Electrochimica Acta,2004,50(2-3):339. |
| [44] | Dong, B.;Gwee, L.;Salas-De La Cruz, D.;Winey, K.I.;Elabd, Y.A. .Super proton conductive high-purity nafion nanofibers[J].Nano letters,2010(9):3785-3790. |
| [45] | Gu SY;Ren J;Vancso GJ .Process optimization and empirical modeling for electrospun polyacrylonitrile (PAN) nanofiber precursor of carbon nanofibers[J].European Polymer Journal,2005(11):2559-2568. |
| [46] | Smit E;Buttner U;Sanderson RD .Continuous yarns from electrospun fibers[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(8):2419-2423. |
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