白光LED具有体积小、能耗低、寿命长、环境友好等优点,是未来照明光源的发展方向.现阶段,白光LED的低显色指数和高色温限制了其发展,而红色荧光粉的性能对白光LED显色指数的提高及色温的改善非常关键.着重介绍了国内外白光LED用Eu3+激活红色荧光粉的几大主要体系的研究进展,并指出了目前红色荧光粉存在的问题及其未来的发展趋势.
参考文献
| [1] | 杨志平,路亚娟,李小宁,赵方亮,李盼来,刘海燕.白光发光二极管用红色荧光粉LiBaB9O15：Eu3+的发光性质[J].硅酸盐学报,2009(03):458-461. |
| [2] | LI Panlai,YANG Zhiping,WANG Zhijun,GUO Qinglin.Luminescent characteristics of LiCaBO3:Eu3+ phosphor for white light emitting diode[J].稀土学报（英文版）,2009(03):390-393. |
| [3] | LI Panlai,YANG Zhiping,PANG Libin,WANG Zhijun,GUO Qinglin.Luminescent characteristics of Ba3Y2(BO3)4:Eu3+ phosphor for white LED[J].稀土学报（英文版）,2008(01):44-47. |
| [4] | Guo R;Tang S L et al.Synthesis and luminescent properties of a new phosphor,La2CaB8O16:RE3+ (RE=Eu,Tb)[J].Journal of Alloys and Compounds,2013,550:459. |
| [5] | 杨志平,李立虎,路亚娟,李盼来,赵方亮.Ba3Tb（BO3）3：Eu3+的制备与发光性质[J].硅酸盐学报,2009(09):1510-1513. |
| [6] | 杨志平,田晶,李旭,杨广伟,王少丽,李盼来.白光发光二极管用CaAl2B2O7：Eu3+微晶的发光性质[J].人工晶体学报,2007(05):1178-1181. |
| [7] | Guifang Ju;Yihua Hu;Haoyi Wu;Zhongfu Yang;Chujun Fu;Zhongfei Mu;Fengwen Kang .A red-emitting heavy doped phosphor Li_6Y(BO_3)_3:Eu~(3+) for white light-emitting diodes[J].Optical materials,2011(8):1297-1301. |
| [8] | Zhao, L.-S.;Liu, J.;Wu, Z.-C.;Kuang, S.-P. .Optimized photoluminescence of SrB _2O _4:Eu ~(3+) red-emitting phosphor by charge compensation[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2012(87A):228-231. |
| [9] | Yang, F.;Liang, Y.;Liu, M.;Li, X.;Zhang, M.;Wang, N..Photoluminescence properties of novel red-emitting NaSrBO _3:Eu ~3 phosphor for near-UV light-emitting diodes[J].Optics & Laser Technology,2013:14-19. |
| [10] | 山田健一,姜伟.Ca（Eu1-xLax）4Si3O13红色荧光粉的研究及其在三基色白光LED上的应用[J].中国照明电器,2005(08):24-29. |
| [11] | Shen C Y;Yang Y;Jin S Z et al.Ca(La1-xEux)4Si3O13 red emitting phosphor for white light emitting diodes[J].Physica B,2009,404(8-11):1481. |
| [12] | Wang, L.;Wang, Y. .Luminescent properties of Eu~3-activated Sr_3B _2SiO_8: A red-emitting phosphor for white light-emitting diodes[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2011(7):1479-1481. |
| [13] | YU Hong,GAO Guimei,KONG Li,LI Guanghuan,GAN Shucai,HONG Guangyan.Synthesis and luminescence properties of a novel red-emitting phosphor SrCaSiO4:Eu3+ for ultraviolet white light-emitting diodes[J].稀土学报（英文版）,2011(05):431-435. |
| [14] | 丛妍,李斌,刘东平,杨杞,牛金海.非晶红色荧光粉Cd3AlSi3O12：Eu3+的制备及发光性能[J].无机化学学报,2011(08):1503-1506. |
| [15] | 邬洋,王永生,何大伟,富鸣,陈震旻 |
| [16] | Tyminski J K;Lawson C M;Powell R C .Energy transfer between Eu3+ ions in LiNbO3,CaWO4,and EuxY1-xP5O14 crystals[J].Journal of Chemical Physics,1982,77(09):4318. |
| [17] | Pode RB.;Dhoble SJ. .PHOTOLUMINESCENCE IN CAWO4-BI3+, EU3+ MATERIAL[J].Physica status solidi, B. Basic research,1997(2):571-577. |
| [18] | 孟庆裕,张庆,李明,刘林峰,曲秀荣,万维龙,孙江亭.Eu^3＋掺杂CaWO4红色荧光粉发光性质的浓度依赖关系研究[J].物理学报,2012(10):447-454. |
| [19] | Yeqing Chen;Hyun Kyoung Yang;Sung Wook Park .Characterization and photoluminescent enhancement of Li~+ corporation effect on CaWO_4:Eu~(3+) phosphor[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012(1):123-128. |
| [20] | Ju Z H;Wei R P;Gao X P et al.Red phosphor SrWO4:Eu3+ for potential application in white LED[J].Optical Materials,2011,33(06):909. |
| [21] | 杨泰,李霞.红色Sr1-2xNaXWO4：Eu3+x荧光体的制备与发光性能[J].稀土,2012(01):37-41. |
| [22] | HuYS;ZhuangWD;Ye H Q et al.Anovelredphosphor for white light emitting diodes[J].Journal of Alloys and Compounds,2005,390(1-2):226. |
| [23] | Jie Liu;Hongzhou Lian;Chunshan Shi .Improved optical photoluminescence by charge compensation in the phosphor system CaMoO_4:Eu~(3+)[J].Optical materials,2007(12):1591-1594. |
| [24] | 杨志平,韩勇,李旭.一种新型的白光LED用红色荧光粉SrMoO4：Eu3+[J].河北工业大学成人教育学院学报,2006(02):13-15. |
| [25] | 唐红霞,吕树臣.发光二极管用红色荧光粉SrMoO4：Eu3+的制备和发射性质[J].物理学报,2011(03):723-728. |
| [26] | 程丽红,仲海洋,孙佳石,赵晓霞.白光LED用红色发射荧光粉Gd2（MoO4）3：Eu3+制备与表征[J].中国稀土学报,2008(02):229-233. |
| [27] | Zhao X X;Wang X J;Chen B J et al.Novel Eu3+-doped red-emitting phosphor Gd2Mo3O9 for white-light-emittingdiodes (WLEDs) application[J].Journal of Alloys and Compounds,2007,433(1-2):352. |
| [28] | Xiao-xiao Wang;Yu-lun Xian;Gang Wang;Jian-xin Shi;Qiang Su;Meng-lian Gong .Luminescence investigation of Eu~(3+)-Sm~(3+) co-doped Gd_(2-x-y)Eu-xSm_y(MoO_4)_3 phosphors as red phosphors for UV InGaN-based light-emitting diode[J].Optical materials,2007(4):521-526. |
| [29] | Guo CF;Zhang W;Luan L;Chen T;Cheng H;Huang DX .A promising red-emitting phosphor for white light emitting diodes prepared by sol-gel method[J].Sensors and Actuators, B. Chemical,2008(1):33-39. |
| [30] | 李旭,杨勇,杨志平,关丽,刘冲.Eu3+激活的La2Mo2O9红色荧光粉的制备与性能[J].发光学报,2008(01):93-96. |
| [31] | Li H Y;Yang H K;Moon B K .Structure dependence of the photoluminescence properties of Eu3+ ion-activated R2Mo4O15(R=Y,La,and Gd)[J].Journal of the Electrochemical Society,2012,159(03):J61. |
| [32] | Zhengliang Wang;Hongbin Liang;Jing Wang;Menglian Gong;Qiang Su .Red-light-emitting diodes fabricated by near-ultraviolet InGaN chips with molybdate phosphors[J].Applied physics letters,2006(7):071921-1-071921-3-0. |
| [33] | Wang Z L;Liang H B;Gong M L et al.Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure[J].Journal of Alloys and Compounds,2007,432(1-2):308. |
| [34] | Yi, LH;He, XP;Zhou, LL;Gong, FZ;Wang, RF;Sun, JH .A potential red phosphor LiGd(MoO4)(2):Eu3+ for light-emitting diode application[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2010(6):1113-1117. |
| [35] | Guo, CF;Yang, HY;Jeong, JH .Preparation and luminescent properties of phosphor MGd2(MoO4)(4): Eu3+ (M = Ca, Sr and Ba)[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2010(8):1390-1393. |
| [36] | Shao, QY;Li, HJ;Wu, KW;Dong, Y;Jiang, JQ .Photoluminescence studies of red-emitting NaEu(WO4)(2) as a near-UV or blue convertible phosphor[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2009(8):879-883. |
| [37] | Qian, X.;Pu, X.;Zhang, D.;Li, L.;Li, M.;Wu, S. .Combustion synthesis and luminescence properties of NaY _(1-x)Eu_x(WO_4)_2 phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2011(8):1692-1695. |
| [38] | 游航英,廖金生,温和瑞,张绍安,陈景林,黄海平.溶胶-凝胶法合成KGd（WO4）2：Eu3+红色荧光粉及其发光性质的研究[J].中国稀土学报,2011(02):178-184. |
| [39] | Neeraj S.;Kijima N.;Cheetham AK. .Novel red phosphors for solid-state lighting: the system NaM(WO4)(2-x)(MoO4)(x): Eu3+ (M=Gd, Y, Bi)[J].Chemical Physics Letters,2004(1/3):2-6. |
| [40] | V. Sivakumar;U. V. Varadaraju .Intense Red Phosphor for White LEDs Based on Blue GaN LEDs[J].Journal of the Electrochemical Society,2006(3):H54-H57. |
| [41] | Wang X X;Xian Y L;Shi J X et al.The potential red emitting Gd2-y Euy (WO4)3-x (MoO4)x phosphors for UV InGaN-based light-emitting diode[J].Materials Science and Engineering B,2007,140(1-2):69. |
| [42] | Chiu CH;Liu CH;Huang SB;Chen TM .Synthesis and luminescence properties of intensely red-emitting M5Eu(WO4)(4-x)(MoO4)(x) (M = Li, Na, K) phosphors[J].Journal of the Electrochemical Society,2008(3):J71-J78. |
| [43] | Levine A K;Palilla F C .A new,highly efficient red-emitting cathodoluminescent phosphor (YVO4:Eu) for color television[J].Applied Physics Letters,1964,5(06):118. |
| [44] | S. Neeraj;N. Kijima;A.K. Cheetham .Novel red phosphors for solid state lighting; the system Bi_xLn_(1-x)VO_4; Eu~(3+)/Sm~(3+) (Ln = Y, Gd)[J].Solid State Communications,2004(1):65-69. |
| [45] | Wang YH;Sun YK;Zhang JC;Ci ZP;Zhang ZY;Wang L .New red Y0.85Bi0.1Eu0.05V1-yMyO4 (M = Nb, P) phosphors for light-emitting diodes[J].Physica, B. Condensed Matter,2008(12):2071-2075. |
| [46] | Yonghong Hu;XiaoChen;WengeYang;ZiyuLei;CongZhao .SynthesisandluminescencepropertiesofYVO4:Eu3+,Bi3+ phosphor with enhancedphotoluminescencebyBi3+ doping[J].The journal of physics and chemistry of solids,2010(3):175-180. |
| [47] | Liya Zhou;Junli Huang;Fuzhong Gong .A new red phosphor LaNb_(0.70)V_(0.30)O_4:Eu~(3+) for white light-emitting diodes[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):268-271. |
| [48] | Choi, S;Moon, YM;Kim, K;Jung, HK;Nahm, S .Luminescent properties of a novel red-emitting phosphor: Eu3+-activated Ca3Sr3(VO4)(4)[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2009(9):988-990. |
| [49] | Enhanced luminescence by charge compensation in red-emitting Eu~(3+)-activated Ca_3Sr_3(VO_4)_4[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(2):118. |
| [50] | Jiaping Huang;Qiuxia Li;Donghua Chen .Preparation and luminescence properties of Ca_3(VO_4)_2: Eu~(3+),Sm~(3+) phosphor for light-emitting diodes[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2010(2):108-113. |
| [51] | Rao B V;Jang K;Lee H S et al.Synthesis and photoluminescence characterization of RE3+(RE3+ =Eu3+,Dy3+)-activated Ca3La (VO4)3 phosphors for white light-emitting diodes[J].Journal of Alloys and Compounds,2010,496(1-2):251. |
| [52] | Evans JSO.;Sleight AW.;Huang J. .Synthesis and structure of ACa(9)(VO4)(7) compounds, A = Bi or a rare earth[J].International Journal of Quantum Chemistry,2001(2):255-260. |
| [53] | 杨平,田莲花,田荣.Ca_9R（VO_4）_7∶Eu~（3+）（R=Y, La, Gd） 发光粉的发光特性[J].发光学报,2009(06):768-772. |
| [54] | Lihong Liu;Rong-Jun Xie;Naoto Hirosaki .Crystal Structure and Photoluminescence Properties of Red-Emitting Ca_9La_(1-x)(VO_4)_7:xEu~(3+) Phosphors for White Light-Emitting Diodes[J].Journal of the American Ceramic Society,2010(12):4081-4086. |
| [55] | Xiao Wu;Yanlin Huang;Hyo Jin Seo .The luminescence spectroscopy and thermal stability of red-emitting phosphor Ca_9Eu(VO_4)_7[J].CERAMICS INTERNATIONAL,2011(7):2323-2328. |
| [56] | Zhao, J.;Guo, C.;Yu, J.;Yu, R..Spectroscopy properties of Eu ~(3+) doped Ca _9R(VO _4) _7 (R=Bi, La, Gd and Y) phosphors by sol-gel method[J].Optics & Laser Technology,2013:62-68. |
| [57] | Srtlur A A;Comanzo O H A;Srivanstava A M et al.Spectroscopic evaluation of a white light phosphor for UVLEDs-Ca2NaMg2V3On:Eu3+[J].Journal of the Electrochemical Society,2005,152(12):H205. |
| [58] | Gundiah G;Shimomura Y;Kijima N;Cheetham AK .Novel red phosphors based on vanadate garnets for solid state lighting applications[J].Chemical Physics Letters,2008(4-6):279-283. |
| [59] | Xu SA;Xiao XZ;Yan B .Hybrid precursors synthesis and photoluminescence of rare earth ions - activated Sr(3)y (PO4)(3) phosphors[J].Journal of optoelectronics and advanced materials,2008(10):2727-2731. |
| [60] | Zhang, J;Wang, YH .Eu3+-Doped Ba3Bi(PO4)(3): A Red Phosphor for White Light-Emitting Diodes[J].Electrochemical and solid-state letters,2010(4):J35-J37. |
| [61] | Xin S Y;Wang Y H;Wang Z F et al.An intense red-emitting phosphor YBa3 (PO4)3:Eu3+ for near-ultraviolet light emitting diodes[J].Electrochemical and Solid State Letters,2011,14(11):H438. |
| [62] | Baozhu Yang;Zhiping Yang;Yufeng Liu .Synthesis and photoluminescence properties of the high-brightness Eu~(3+)-doped Sr_3Y(PO_4)_3 red phosphors[J].CERAMICS INTERNATIONAL,2012(6):4895-4900. |
| [63] | Guoyi Dong;Hengxin Ma;Yufeng Liu;Zhiping Yang;Qingbo Liu .Synthesis and photoluminescence properties of the high-brightness Eu~(3+)-doped Sr_(3)Bi(PO_(4))_(3) phosphors[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2012(20):4097-4101. |
| [64] | Jia Zhang;Yuhua Wang;Yan Wen;Feng Zhang;Bitao Liu .A potential Eu~(3+)-activated Ca_(10)K(PO_4)_7 red phosphor for white light-emitting diodes[J].Materials Research Bulletin,2011(12):2554-2559. |
| [65] | Dou, X.;Zhao, W.;Song, E.;Zhou, G.;Yi, C.;Zhou, M. .Photoluminescence characterization of Ca_(10)Na(PO _4)_7:Eu~(3+) red-emitting phosphor[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2011(2):821-825. |
| [66] | SONG Enhai,ZHAO Weiren,ZHOU Guoxiong,DOU Xihua,YI Chunyu,ZHOU Minkang.Luminescence properties of red phosphors Ca10Li (PO4)7:Eu3+[J].稀土学报（英文版）,2011(05):440-443. |
| [67] | Liu, Q.;Liu, Y.;Yang, Z.;Li, X.;Han, Y. .UV-excited red-emitting phosphor Eu ~(3+)-activated Ca _9Y(PO _4) _7[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2012(87A):190-193. |
| [68] | Dilllip G R;Raju B D P .A study of the luminescence in near UV-pumped red-emitting novel Eu3+-doped Ba3Ca3 (PO4)4 phosphors for white light emitting diodes[J].Journal of Alloys and Compounds,2012,540:67. |
| [69] | Dillip, G.R.;Dhoble, S.J.;Manoj, L.;Madhukar Reddy, C.;Deva Prasad Raju, B. .A potential red emitting K _4Ca(PO _4) _2: Eu ~3 phosphor for white light emitting diodes[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2012(11):3072-3076. |
| [70] | Li X;Guamn L;Li X N et al.Luminescent properties of NaBaPO4:Eu3+ red-emitting phosphor for white light-emitting diodes[J].Powder Technology,2010,200(1-2):12. |
| [71] | Guifang Ju;Yihua Hu;Li Chen .Luminescent properties of Na_3Gd_(1-x)Eu_x(PO_4)_2 and energy transfer in these phosphors[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(18):5655-5659. |
| [72] | 莎仁,赵斯琴,王喜贵.超细红色荧光粉LaMgAl11O19：Eu3+的制备与发光性能[J].中国科学B辑,2010(04):331-335. |
| [73] | 刘慧娟,孙洪巍,赵冉,胡行,胡少杰.红色荧光粉YAlO3∶Eu3+Cu+的制备和发光特性[J].郑州大学学报（理学版）,2012(01):83-87. |
| [74] | Qiang, RF;Xiao, SG;Ding, JW;Yuan, WH;Zhu, CQ .Red emission in B3+- and Li+-doped SrAl2O4:EU3+ phosphor under UV excitation[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2009(8):826-828. |
| [75] | Zhao C C;Yin X;Huang F Q et al.Novel red perovskite phosphor Ca2 A1NbO6:Eu3+ for white light-emitting diode application[J].Physica B,2011,406(24):4608. |
| [76] | ZHANG Jian,YIN Jing,LIU Panpan,GAO Bin,BIE Lijian.Preparation and luminescent properties of MgTiO3:Eu3+ phosphor for white LEDs[J].稀土学报（英文版）,2012(10):1009-1012. |
| [77] | Sun, ZA;Zhang, QH;Li, YG;Wang, HZ .Thermal stable La_2Ti_2O_7:Eu~(3+) phosphors for blue-chip white LEDs with high color rendering index[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):338-342. |
| [78] | Dongseok Kang;Hyoung Sun Yoo;Sang Hoon Jung .Synthesis and Photoluminescence Properties of a Novel Red-Emitting Na2Y2Ti3O_(10):Eu~(3+),Sm~(3+) Phosphor for White-Light-Emitting Diodes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(49):24334-24340. |
| [79] | Yan X S;Li W W;Sun K .A novel red emitting phosphors CaIn2 O4:Eu3+,Sm3+ with a broadened near-ultraviolet absorption band for solid-state lighting[J].Materials Research Bulletin,2011,46(01):87. |
| [80] | Li Y C;Chang Y H;Lin Y F et al.Synthesis and luminescent properties of Ln3+ (Eu3+,Sm3+,Dy3+)-doped lanthanum aluminum germanate LaAlGe2O7 phosphors[J].Journal of Alloys and Compounds,2007,439(1-2):367. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%