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碳钢试片表面模拟有机涂层不同程度的破损状态,在 NaCl溶液中进行了电化学测试.提出了破损程度系数Kp,建立了Kp与涂层体系 电化学等效电路参数之间的函数关系,可用来判辨有机涂层的破损程度,为现场检测仪器的 研制提供了理论依据.同时还测定了有机涂层不同破损程度的电化学阻抗谱,分析了谱图特 征.

The electrochemical measurement was conducted on car bon steel samples coated with organic coatings.The coatings were induced hol es with different diameters in order to simulate artificially the damage severit y of the coatings in practice.A coefficient of damage severity of organic coatin g Kp was put forward,and the relationship of Kp and the parameters o f the electrochemical equivalent circuit of the coating system was given,which c ould describe the damage severity of organic coatings.This paper offered a theor etic fundamental for designing instruments for field monitoring.Furthermore,the electrochemical impedance spectroscopy of organic coatings with different damage severities was measured and analyzed.

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