采用水溶液聚合法制备了丙烯酰胺/凹凸棒复合吸水性树脂,考察了凹凸棒含量、单体浓度、交联剂含量和引发剂含量对树脂吸水性能的影响,并通过FT-IR和SEM对接枝反应机理和材料的表面形貌进行了表征;同时对树脂在电解质溶液中的溶胀行为进行了研究.结果表明,当凹凸棒质量分数为10%时,复合吸水性树脂在蒸馏水和0.9%NaCl溶液中的吸水倍率分别达到了2645 g/g和112 g/g,树脂耐盐性能明显提高.
参考文献
| [1] | 邹新禧.超强吸水剂[M].北京:化学工业出版社,2003:690-691. |
| [2] | Buchhlz F L;Graham T.Modern Superabsorbent Polymer Technology[M].New York: Wiley-VCH,1998:1152-1154. |
| [3] | Lim D W;Whang H S;Yoon K J et al.[J].Journal of Applied Polymer Science,2001,79:1423. |
| [4] | Kabiri K.;Omidian H.;Hashemi SA.;Zohuriaan-Mehr MJ. .Synthesis of fast-swelling superabsorbent hydrogels: effect of crosslinker type and concentration on porosity and absorption rate[J].European Polymer Journal,2003(7):1341-1348. |
| [5] | Padmanabha-Raju M;Mohana-Raju K .[J].Journal of Applied Polymer Science,2001,80:2635. |
| [6] | Kabiri K;Zohuriaan-Mehr M .[J].Macromolecular Materials and Engineering,2004,289:653. |
| [7] | Neaman A;Singer A .[J].Applied Clay Science,2004,25:121. |
| [8] | Li A.;Wang AQ.;Chen JM. .Studies on poly(acrylic acid)/attapulgite superabsorbent composite. I. Synthesis and characterization[J].Journal of Applied Polymer Science,2004(3):1596-1603. |
| [9] | Flory P J.Principles of Polymer Chemistry[M].Cornell University Press: Ithaca, NY,1953:580. |
| [10] | Allcock H R;Frederick W L.Contemporary Polymer Chemistry[M].Prentice-Hall:Englewood Cliffs,NJ,1981 |
| [11] | Liu ZS.;Rempel GL. .PREPARATION OF SUPERABSORBENT POLYMERS BY CROSSLINKING ACRYLIC ACID AND ACRYLAMIDE COPOLYMERS[J].Journal of Applied Polymer Science,1997(7):1345-1353. |
| [12] | Castal D;Ricard A;Audebert R .[J].Journal of Applied Polymer Science,1990,39:11. |
| [13] | Dean J A.Lange′s Handbook of Chemistry (Thirteenth Edition)[M].McGraw-Hill Book Company,1985:380. |
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