为了认识Mg—Li结构对其微弧氧化陶瓷膜的影响,研究了纯α相、α+β双相及纯β相Mg.Li合金在Na2SiO3溶液中微弧氧化的成膜特点。采用ICP—AES测量了微弧氧化时基体中Li+的析出量;通过SEM,EDS,XRD等分析了陶瓷膜表面和截面形貌、元素分布及其相组成;利用测厚仪测量了陶瓷膜的厚度。结果显示:β相基体中的Li在微弧氧化过程中的析出量超过仅相和仅+13相;“相击穿电压最低,最终槽压最大;α+β相膜层最为均匀,孔洞最少;陶瓷膜均由O,Na,Mg,Si4种元素组成;α相膜层由MgO相组成,α+β相和B相膜层均由MgO和Mg2SiO4两相组成;α相基体表面膜层最厚,膜层厚度随时间都呈近似抛物线变化。
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