欢迎登录材料期刊网

材料期刊网

高级检索

综述近年来国内外对于碳、合金、金属氧化物等负极材料的研究现状,重点介绍材料的性能以及储钠机理,探讨材料存在的主要问题和解决方法,对负极材料的研究方向以及前景进行展望,指出具有较大层间距和较小比表面积的碳材料是目前最有希望应用于钠离子电池的负极材料,结构稳定性较好的钛酸盐材料是极具潜力的负极材料,设计开发适合的离子电池自身特点的新材料是未来钠电子电池研究的重要方向。

The research status of anode materials in recent years, such as carbons, alloys, metal oxides and soon,were summarized, the performance and storage mechanism of sodiumofthe materials reachedwere introduced. The main problems of these kinds of anode materialsand the solutionwere discussed.The research directions and prospects on anode materialswereforecasted, and thecarbon materials with large layer spacing and less surface area is the most promising candidate anode material for sodium ion battery,and titanate with good structure stability is potential anode materials. Designing and developingnew materials is an important future research field for sodium ion battery.

参考文献

[1] M. Armand;J.-M. Tarascon.Building better batteries[J].Nature,20087179(7179):652-657.
[2] 宋刘斌;李新海;王志兴;郭华军;肖忠良;周英.锂离子电池充放电过程中的热行为及有限元模拟研究[J].功能材料,2013(8):1153-1158.
[3] M. Rosa Palacin.Recent advances in rechargeable battery materials: a chemist's perspective[J].Chemical Society Reviews,20099(9):2565-2575.
[4] Bruce Dunn;Haresh Kamath;Jean-Marie Tarascon.Electrical Energy Storage for the Grid: A Battery of Choices[J].Science,2011Nov.18 TN.6058(Nov.18 TN.6058):928-935.
[5] J. Barker;M. Y. Saidi;J. L. Swoyer.A Sodium-Ion Cell Based on the Fluorophosphate Compound NaVPO_4F[J].Electrochemical and solid-state letters,20031(1):A1-A4.
[6] Veronica Palomares;Paula Serras;Irune Villaluenga;Karina B. Hueso;Javier Carretero-Gonzalez;Teofllo Rojo.Na-ion batteries, recent advances and present challenges to become low cost energy storage systems[J].Energy & environmental science: EES,20123(3):5884-5901.
[7] 卓海涛;王先友;唐安平;刘志明.NaV1-xCrxPO4F的合成及电化学性能[J].中国有色金属学报,2006(7):1276-1280.
[8] Alex Langrock;Yunhua Xu;Yihang Liu;Sheryl Ehrman;Ayyakkannu Manivannan;Chunsheng Wang.Carbon coated hollow Na_2FePO_4F spheres for Na-ion battery cathodes[J].Journal of Power Sources,2013Feb.1(Feb.1):62-67.
[9] 杨绍斌;董伟;沈丁;王晓亮;李思南;王峰;王阳;孙闻.钠离子电池正极材料的研究进展?[J].功能材料,2015(13):13001-13006.
[10] Winter M.;Spahr ME.;Novak P.;Besenhard JO..Insertion electrode materials for rechargeable lithium batteries [Review][J].Advanced Materials,199810(10):725-763.
[11] D. A. Stevens;J. R. Dahn.The Mechanisms of Lithium and Sodium Insertion in Carbon Materials[J].Journal of the Electrochemical Society,20018(8):A803-A811.
[12] V.L. Chevrier;G. Ceder.Challenges for Na-ion Negative Electrodes[J].Journal of the Electrochemical Society,20119(9):A1011-A1014.
[13] P. Thomas;D. Billaud.Effect of mechanical grinding of pitch-based carbon fibers and graphite on their electrochemical sodium insertion properties[J].Electrochimica Acta,20001(1):39-47.
[14] Yun-Xiao Wang;Shu-Lei Chou;Hua-Kun Liu.Reduced graphene oxide with superior cycling stability and rate capability for sodium storage[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:202-208.
[15] Li, Sheng;Qiu, Jingxia;Lai, Chao;Ling, Min;Zhao, Huijun;Zhang, Shanqing.Surface capacitive contributions: Towards high rate anode materials for sodium ion batteries[J].Nano Energy,2015:224-230.
[16] 杨绍斌;费晓飞;蒋娜.增大层间距对天然石墨可逆储锂性能的影响研究[J].化学学报,2009(17):1995-2000.
[17] Shaobin Yang;Haoquan Hu;Guohua Chen.Preparation of carbon adsorbents with high surface area and a model for calculating surface area[J].Carbon: An International Journal Sponsored by the American Carbon Society,20023(3):277-284.
[18] P. Thomas;J. Ghanbaja;D. Billaud.Electrochemical insertion of sodium in pitch-based carbon fibres in comparison with graphite in NaClO{sub}4-ethylene carbonate electrolyte[J].Electrochimica Acta,19993(3):423-430.
[19] D. A. Stevens;J. R. Dahn.High capacity anode materials for rechargeable sodium-ion batteries[J].Journal of the Electrochemical Society,20004(4):1271-1273.
[20] P. Thomas;D. Billaud.Electrochemical insertion of sodium into hard carbons[J].Electrochimica Acta,200220(20):3303-3307.
[21] Ricardo Alcantara;Juan M. Jimenez-Mateos;Pedro Lavela;Jose L. Tirado.Carbon black: a promising electrode material for sodium-ion batteries[J].Electrochemistry communications,200111(11):639-642.
[22] Alcantara R.;Lavela P.;Tirado JL.;Mateos JMJ.;de Salazar CG.;Stoyanova R.;Zhecheva E.;Madrigal FJF..Characterisation of mesocarbon microbeads (MCMB) as active electrode material in lithium and sodium cells[J].Carbon: An International Journal Sponsored by the American Carbon Society,20007(7):1031-1041.
[23] R. Alcantara;P. Lavela;G. F. Ortiz.Carbon Microspheres Obtained from Resorcinol-Formaldehyde as High-Capacity Electrodes for Sodium-Ion Batteries[J].Electrochemical and solid-state letters,20054(4):A222-A225.
[24] Shinichi Komaba;Wataru Murata;Toru Ishikawa;Naoaki Yabuuchi;Tomoaki Ozeki;Tetsuri Nakayama;Atsushi Ogata;Kazuma Gotoh;Kazuya Fujiwara.Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-lon Batteries[J].Advanced functional materials,201120(20):3859-3867.
[25] Sebastian Wenzel;Takeshi Hara;Jiirgen Janek;Philipp Adelhelm.Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies![J].Energy & environmental science: EES,20119(9):3342-3345.
[26] Cao, Y.;Xiao, L.;Sushko, M.L.;Wang, W.;Schwenzer, B.;Xiao, J.;Nie, Z.;Saraf, L.V.;Yang, Z.;Liu, J..Sodium ion insertion in hollow carbon nanowires for battery applications[J].Nano letters,20127(7):3783-3787.
[27] Clement Bommier;Wei Luo;Wen-Yang Gao.Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:165-174.
[28] Luo, Wei;Bommier, Clement;Jian, Zelang;Li, Xin;Carter, Rich;Vail, Sean;Lu, Yuhao;Lee, Jong-Jan;Ji, Xiulei.Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent[J].ACS applied materials & interfaces,20154(4):2626-2631.
[29] 沈丁;董伟;李思南;杨绍斌.碳源对Sn-Co/C复合材料显微组织和电化学性能的影响[J].中国有色金属学报,2015(7):1890-1896.
[30] 杨绍斌;沈丁;吴晓光;米晗.Cu对Sn-Co/C复合材料结构和电化学性能的影响[J].中国有色金属学报,2012(4):1163-1168.
[31] Michael D. Slater;Donghan Kim;Eungje Lee;Christopher S. Johnson.Sodium-Ion Batteries[J].Advanced functional materials,20138(8):947-958.
[32] Tuan T. Tran;M. N. Obrovac.Alloy Negative Electrodes for High Energy Density Metal-Ion Cells[J].Journal of the Electrochemical Society,201112(12):A1411-A1416.
[33] Komaba, S.;Matsuura, Y.;Ishikawa, T.;Yabuuchi, N.;Murata, W.;Kuze, S..Redox reaction of Sn-polyacrylate electrodes in aprotic Na cell[J].Electrochemistry communications,2012:65-68.
[34] Wang, J.W.;Liu, X.H.;Mao, S.X.;Huang, J.Y..Microstructural evolution of tin nanoparticles during in situ sodium insertion and extraction[J].Nano letters,201211(11):5897-5902.
[35] Qian, J.;Chen, Y.;Wu, L.;Cao, Y.;Ai, X.;Yang, H..High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries[J].Chemical communications,201256(56):7070-7072.
[36] Hongshuai Hou;Yingchang Yang;Yirong Zhu;Mingjun Jing;Chengchi Pan;Laibing Fang;Weixin Song;Xuming Yang;Xiaobo Ji.An Electrochemical Study of Sb/Acetylene Black Composite as Anode for Sodium-Ion Batteries[J].Electrochimica Acta,2014:328-334.
[37] Lin Wu;Xiaohong Hu;Jiangfeng Qian;Feng Pei;Fayuan Wu;Rongjun Mao;Xinping Ai;Hanxi Yang;Yuliang Cao.Sb-C nanofibers with long cycle life as an anode material for high-performance sodium-ion batteries[J].Energy & environmental science: EES,20141(1):323-328.
[38] Li, Kefei;Su, Dawei;Liu, Hao;Wang, Guoxiu.Antimony-Carbon-Graphene Fibrous Composite as Freestanding Anode Materials for Sodium-ion Batteries[J].Electrochimica Acta,2015:304-309.
[39] Xiao, L.;Cao, Y.;Xiao, J.;Wang, W.;Kovarik, L.;Nie, Z.;Liu, J..High capacity, reversible alloying reactions in SnSb/C nanocomposites for Na-ion battery applications[J].Chemical communications,201227(27):3321-3323.
[40] Lin Wu;Feng Pei;Rongjun Mao;Fayuan Wu;Yue Wu;Jiangfeng Qian;Yuliang Cao;Xinping Ai;Hanxi Yang.SiC-Sb-C nanocomposites as high-capacity and cycling-stable anode for sodium-ion batteries[J].Electrochimica Acta,2013:41-45.
[41] Youngjin Kim;Yuwon Park;Aram Choi;Nam-Soon Choi;Jeongsoo Kim;Junesoo Lee;Ji Heon Ryu;Seung M. Oh;Kyu Tae Lee.An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries[J].Advanced Materials,201322(22):3045-3049.
[42] Qian Sun;Qin-Qi Ren;Hong Li;Zheng-Wen Fu.High capacity Sb_2O_4 thin film electrodes for rechargeable sodium battery[J].Electrochemistry communications,201112(12):1462-1464.
[43] Hariharan, S.;Saravanan, K.;Balaya, P..α-MoO_3: A high performance anode material for sodium-ion batteries[J].Electrochemistry communications,2013:5-9.
[44] Su, D.;Ahn, H.-J.;Wang, G..SnO_2@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance[J].Chemical communications,201330(30):3131-3133.
[45] Zhang, Yandong;Xie, Jian;Zhang, Shichao;Zhu, Peiyi;Cao, Gaoshao;Zhao, Xinbing.Ultrafine tin oxide on reduced graphene oxide as high-performance anode for sodium-ion batteries[J].Electrochimica Acta,2015:8-15.
[46] 许婧;杨德志;廖小珍;何雨石;马紫峰.还原氧化石墨烯/TiO2复合材料在钠离子电池中的电化学性能[J].物理化学学报,2015(5):913-919.
[47] Chen, Chaoji;Wen, Yanwei;Hu, Xianluo;Ji, Xiulei;Yan, Mengyu;Mai, Liqiang;Hu, Pei;Shan, Bin;Huang, Yunhui.Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling[J].Nature Communications,2015Apr.(Apr.)
[48] Ge, Yeqian;Jiang, Han;Zhu, Jiadeng;Lu, Yao;Chen, Chen;Hu, Yi;Qiu, Yiping;Zhang, Xiangwu.High cyclability of carbon-coated TiO2 nanoparticles as anode for sodium-ion batteries[J].Electrochimica Acta,2015:142-148.
[49] Premkumar Senguttuvan;Gwenaelle Rousse;Vincent Seznec.Na2Ti3O7: Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries[J].Chemistry of Materials: A Publication of the American Chemistry Society,201118(18):4109-4111.
[50] Zhou, Qian;Liu, Li;Tan, Jinli;Yan, Zichao;Huang, Zhifeng;Wang, Xianyou.Synthesis of lithium titanate nanorods as anode materials for lithium and sodium ion batteries with superior electrochemical performance[J].Journal of Power Sources,2015Jun.1(Jun.1):243-250.
[51] Qin, Wei;Chen, Taiqiang;Pan, Likun;Niu, Lengyuan;Hu, Bingwen;Li, Dongsheng;Li, Jinliang;Sun, Zhuo.MoS2-reduced graphene oxide composites via microwave assisted synthesis for sodium ion battery anode with improved capacity and cycling performance[J].Electrochimica Acta,2015:55-61.
[52] 黄宗令;王丽平;牟成旭;李晶泽.对苯二甲酸镁作为钠离子电池的有机负极材料[J].物理化学学报,2014(10):1787-1793.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%