欢迎登录材料期刊网

材料期刊网

高级检索

通过测定Al-Zn-Sn-Ga阳极在3.5% NaCl(质量分数)溶液中浸泡不同时间的电化学阻抗谱(EIS),研究该阳极的腐蚀发展过程和腐蚀特征.结果显示:当合金刚被浸入3.5% NaC1溶液时,EIS谱为反应电阻很大的容抗弧,表明此时合金处于钝化态;随着浸泡时间的延长,EIS谱中高频段的容抗弧明显减小且低频段出现感抗弧,合金进入点蚀期;继续延长浸泡时间,EIS谱中除高频段的容抗弧和中、低频段感抗弧外,在低频段出现另一容抗弧,合金处于点蚀扩展期;随着浸泡时间的继续增加,低频段感抗弧消失,EIS谱由两个容抗弧组成,合金达到均匀腐蚀期.因此,合金的腐蚀由钝化态开始,经点蚀期和点蚀扩展期,达到均匀腐蚀期.

参考文献

[1] 朱元良,赵艳娜,齐公台,刘斌.热处理对铝合金牺牲阳极电化学性能的影响[J].中国有色金属学报,2006(07):1300-1305.
[2] 王璇.铟职业病案凸显政策疏漏[J].劳动保护,2008(09):34-37.
[3] Salinas DR;Bessone JB;Garcia SG .Influence of alloying elements and microstructure on aluminium sacrificial anode performance: case of Al-Zn[J].Journal of Applied Electrochemistry,1999(9):1063-1071.
[4] 文九巴,王国伟,马景灵,贺俊光,史志红.Ga对Al-Zn-Sn系阳极合金电化学性能的影响[J].材料热处理学报,2010(08):30-33,39.
[5] GB/T 17848-1999.GB/T 17848-1999.牺牲阳极电化学性能试验方法[S].
[6] J. R. Morlidge;P. Skeldon;G. E. Thompson;H. Habazaki;K. Shimizu;G. C. Wood .Gel formation and the efficiency of anodic film growth on aluminium[J].Electrochimica Acta,1999(14):2423-2435.
[7] VENUGOPAL A;RAJA V S .AC impedance study on the activation mechanism of aluminium by indium and zinc in 3.5% NaCl medium[J].Corrosion Science,1997,39(12):2053-2065.
[8] T. J. Luo;Y. S. Yang;Y. J. Li;X. G. Dong .Influence of rare earth Y on the corrosion behavior of as-cast AZ91 alloy[J].Electrochimica Acta,2009(26):6433-6437.
[9] 李翔,严彪,董鹏,王宇鑫,杜春风.Fe基非晶合金的晶化及其在NaCl溶液中的电化学腐蚀行为[J].中国有色金属学报,2010(01):156-162.
[10] 李劲风,张昭,曹发和,程英亮,张鉴清,曹楚南.Investigation of exfoliation corrosion of rolled AA8090 Al-Li alloy using electrochemical impedance spectroscopy[J].中国有色金属学会会刊(英文版),2003(02):320-324.
[11] 董超芳,安英辉,李晓刚,生海,肖葵.7A04铝合金在海洋大气环境中初期腐蚀的电化学特性[J].中国有色金属学报,2009(02):346-352.
[12] 朱祖芳.铝合金阳极氧化工艺技术应用手册[M].北京:冶金工业出版社,2007:12-13.
[13] CABOT P L;GARRIDO J A;PEREZ E;PER(E)Z A H .EIS study of heat-treated Al-Zn-Mg alloys in the passive and transpassive potential region[J].Electrochimica Acta,1995,40(04):447-454.
[14] 刘斌,齐公台,冉伟,赵婷婷.模拟偏析相Al2Zn在3%NaCl溶液中的电化学行为[J].中国腐蚀与防护学报,2007(02):93-96.
[15] Maria Nestoridi;Derek Pletcher;Robert J.K. Wood;Shuncai Wang;Richard L. Jones;Keith R. Stokes;Ian Wilcock .The study of aluminium anodes for high power density Al/air batteries with brine electrolytes[J].Journal of Power Sources,2008(1):445-455.
[16] TUCK C D S;HUNTER J A;SCAMANS G M .Electrochemical behavior of A1-Ga alloys in alkaline and neutral electrolytes[J].Journal of the Electrochemical Society,1987,134(12):2970-2981.
[17] Flamini, DO;Saidman, SB .Polarisation behaviour of Al-Zn-Ga alloy in chloride medium[J].Journal of Applied Electrochemistry,2008(5):663-668.
[18] BRESLIN C B;CARROLL W M .Electrochemical behaviour of aluminium activated by gallium in aqueous electrolytes[J].Corrosion Science,1992,33(11):1735-1739.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%