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Determination of(Fe,Cr)_7C_3 in Cr27 cast iron results about 30 v.-%.Minor Si and Mn are present.Sectional area of the M_7C_3 grains is 1—50μm~2.Combining matrix analysis of elec- tron diffraction pattern with calculated angle between plane traces,{011}twins and also {013}twins producing local environment for Ru_7B_3 are observed in the orthorhombic M_7C_3. A crystallographic model for M_7C_3 is proposed.

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