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采用溶胶-凝胶法制备了铁掺杂二氧化钛粉体(Fe-TiO2),采用XRD、UV-Vis、PL、纳米粒度分析仪等方法对其进行表征和分析.结果表明,Fe掺杂降低了TiO2的相转变温度,拓展了TiO2对可见光的吸收范围,有效地抑制了光生电子-空穴对的复合.光催化降解亚甲基蓝(MB)的实验表明,Fe-TiO2粉体在普通日光灯下对亚甲基蓝的降解率达90.36%,明显优于德国Degussa公司生产的P25纯TiO2光催化剂对亚甲基蓝的降解率43.58%.

参考文献

[1] 牛新书,李红花,蒋凯.金属离子掺杂纳米TiO2光催化研究进展[J].电子元件与材料,2004(08):39-42,45.
[2] HUAN CHEN;SHUO CHEN;XIE QUAN .Structuring a TiO2-Based Photonic Crystal Photocatalyst with Schottky Junction for Efficient Photocatalysis[J].Environmental Science & Technology: ES&T,2010(1):451-455.
[3] 李哓俊,司德君,方均,姜志全,黄伟新.铁和铈共掺杂二氧化钛中的协同效应[J].化学物理学报,2006(06):539-542.
[4] Ping Yang;Cheng Lu;Nanping Hua;Yukou Du .Titanium dioxide nanoparticles co-doped with Fe~(3+) and Eu~(3+) ions for photocatalysis[J].Materials Letters,2002(4):794-801.
[5] Kunpeng Xie;Lan Sun;Chenglin Wang;Yuekun Lai;Mengye Wang;Hongbo Chen;Changjian Lin .Photoelectrocatalytic properties of Ag nanoparticles loaded TiO_2 nanotube arrays prepared by pulse current deposition[J].Electrochimica Acta,2010(24):7211-7218.
[6] Ubonchonlakate K;Sikong L;Saito F et al.Photocatalytic disinfection of P.aeruginosa bacterial Ag-doped TiO2 film[J].Procedia Eng,2012,32:656.
[7] Li Xing;Jiarbo Jia;Yizhe Wang;Bailin Zhang;Shaojun Dong .Pt modified TiO_2 nanotubes electrode: Preparation and electrocatalytic application for methanol oxidation[J].International journal of hydrogen energy,2010(22):12169-12173.
[8] Significant improvement of photocatalytic hydrogen generation rate over TiO_2 with deposited CuO[J].International journal of hydrogen energy,2009(15):6096.
[9] Fujishima, M.;Takatori, H.;Tada, H. .Interfacial chemical bonding effect on the photocatalytic activity of TiO_2-SiO_2 nanocoupling systems[J].Journal of Colloid and Interface Science,2011(2):628-631.
[10] Afuyoni M;Nashed G;Nasser I M et al.TiO2doped with SnO2and studing its structural and electrical properties[J].Energy Procedia,2011,6:11.
[11] Ahed Zyoud;Nidal Zaatar;Iyad Saadeddin .Alternative natural dyes in water purification: Anthocyanin as TiO_2-sensitizer in methyl orange photo-degradation[J].Solid state sciences,2011(6):1268-1275.
[12] CdS-sensitized TiO_2 in phenazopyridine photo-degradation: Catalyst efficiency, stability and feasibility assessment[J].Journal of hazardous materials,2010(1/3):318.
[13] 林婷 .金属-非金属共掺杂纳米TiO<,2>的制备及对甲醛的光催化降解作用[D].广东工业大学,2008.
[14] Naeem, K;Feng, OY .Preparation of Fe3+-doped TiO2 nanoparticles and its photocatalytic activity under UV light[J].Physica, B. Condensed Matter,2010(1):221-226.
[15] Degradation of 4-nitrophenol (4-NP) using Fe-TiO_2 as a heterogeneous photo-Fenton catalyst[J].Journal of hazardous materials,2010(1/3):569.
[16] Preparation of Fe-doped TiO_2 nanotube arrays and their photocatalytic activities under visible light[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(2):224.
[17] Ambrus Z;Balázs N;Alapi T et al.Synthesis,structure and photocatalytic properties of Fe(Ⅲ)-doped TiO2 prepared from TiCl3[J].Applied Catalysis B:Environmental,2008,81(1-2):27.
[18] 郑广涛,施建伟,陈铭夏,袁坚,上官文峰.过渡金属离子掺杂纳米TiO2的相变与光催化活性[J].化工学报,2006(03):564-570.
[19] Jho J H;Kim D H;Kim S J et al.Synthesis and photocatalytic property of a mixture of anatase and rutile TiO2 doped with Fe by mechanical alloying process[J].Journal of Alloys and Compounds,2008,459(1-2):386.
[20] Delekara S D;Yadav H M;Achary S N et al.Structural refinement and photocatalytic activity of Fe-doped anatase TiO2 nanoparticles[J].Applied Surface Science,2012,263:536.
[21] Mengjin Yang;Chad Hume;Sangwook Lee .Correlation between Photocatalytic Efficacy and Electronic Band Structure in Hydrothermally Grown TiO2 Nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(36):15292-15297.
[22] Li Y;Xu F D;Oh J et al.Mechanistic study of co-doped titania with nonmetal and metal ions:A case of C+Mo codoped TiO2[J].ACS Catal,2012,2(03):391.
[23] 赵宗彦,柳清菊,张瑾,朱忠其.3d过渡金属掺杂锐钛矿相TiO2的第一性原理研究[J].物理学报,2007(11):6592-6599.
[24] Choi W;Termin A;Hoffmann M R .The role of metal ion dopants in quantum-sized TiO2 correlation between photoreactivity and charge carrier recombination dynamic[J].Physical Chemistry,1994,98(03):13669.
[25] Hu Y M;Hirai K;Tomioka H et al.Effect of para substituents on the molecular and electronic structures of sterically congested triplet diphenylcarbenes[J].Journal of Physical Chemistry B,1999,103(46):9280.
[26] 苏碧桃,白洁,慕红梅,佟永纯,敏世雄,佘世雄.自然光下Fe3+掺杂纳米TiO2光催化降解亚甲基蓝的研究[J].西北师范大学学报(自然科学版),2006(06):52-55,64.
[27] 赵斯琴,郭敏,张梅,王习东,长山.Y~(3+)和Eu~(3+)离子共掺杂TiO_2纳米材料的制备及其光催化性能[J].北京科技大学学报,2010(03):355-359.
[28] R. Alexandrescu;I. Morjan;M. Scarisoreanu;R. Birjega;C. Fleaca;I. Soare;L. Gavrila;V. Ciupina;W. Kylberg;E. Figgemeier .Development of the IR laser pyrolysis for the synthesis of irondoped TiO2 nanoparticles: Structural properties and photoactivity[J].Infrared physics and technology,2010(2):94-102.
[29] 吴晶,周文芳,高攀,朱忠其,柳清菊.Pr-TiO2光催化剂的制备与性能研究[J].功能材料,2010(04):562-565,569.
[30] 孙明,魏锡文,胡小华.铁掺杂TiO2纳米粉的制备、表征及其光催化活性[J].材料导报,2007(z1):153-155.
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