简要介绍了化学法还原氧化石墨烯的主要类型和机理,着重对比了几种常用化学还原法的还原效果,探讨了化学还原法的优缺点,包括还原能力、还原条件及还原机理等方面的内容.认为发挥多种还原剂或制备方法的优势,可以获得性能优异的石墨烯,最后展望了其未来的发展方向及其他潜在应用.
参考文献
[1] | Novoselov K S;Geim A K;Morozov S V et al.Electric field in atomically thin carbon films[J].Science,2004,306(5696):666. |
[2] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
[3] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN .Superior thermal conductivity of single-layer graphene[J].Nano letters,2008(3):902-907. |
[4] | Bolotin, KI;Sikes, KJ;Jiang, Z;Klima, M;Fudenberg, G;Hone, J;Kim, P;Stormer, HL .Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008(9/10):351-355. |
[5] | Stoller MD;Park SJ;Zhu YW;An JH;Ruoff RS .Graphene-Based Ultracapacitors[J].Nano letters,2008(10):3498-3502. |
[6] | Zhang Yuanbo;Tan Yanwen;Stormer H L et al.Experimental observation of the quantum hall effect and berry's phase in graphene[J].Nature,2005,438(7065):201. |
[7] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
[8] | Somani PR;Somani SP;Umeno M .Planer nano-graphenes from camphor by CVD[J].Chemical Physics Letters,2006(1-3):56-59. |
[9] | Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN .Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006(5777):1191-1196. |
[10] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner .Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1558-1565. |
[11] | Yang XY;Dou X;Rouhanipour A;Zhi LJ;Rader HJ;Mullen K .Two-dimensional graphene nanoribbons[J].Journal of the American Chemical Society,2008(13):4216-4217. |
[12] | Hernandez Y;Nicolosi V;Lotya M;Blighe FM;Sun ZY;De S;McGovern IT;Holland B;Byrne M;Gun'ko YK .High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008(9):563-568. |
[13] | Zhong-Shuai Wu;Wencai Ren;Libo Gao .Synthesis of high-quality graphene with a pre-determined number of layers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(2):493-499. |
[14] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS .Graphene-based composite materials[J].Nature,2006(7100):282-286. |
[15] | Hummers S;Offeman R .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339. |
[16] | Brodie B C .On the atomic weight of graphite[J].Philos Transact Royal Soc London,1859,149:249. |
[17] | Staudenmaier L .Verfahren zur darstellung der graphits(a)ure[J].Ber Deutschen Chemischen Ges,1898,31(02):1481. |
[18] | Allen M J;Tung V C;Kaner R B .Honeycomb carbon:A review of graphene[J].Chemical Reviews,2010,110:132. |
[19] | Tung, VC;Allen, MJ;Yang, Y;Kaner, RB .High-throughput solution processing of large-scale graphene[J].Nature nanotechnology,2009(1):25-29. |
[20] | Ren Penggang;Yan Dingxiang;Ji Xu et al.Temperature dependence of graphene oxide reduced by hydrazine hydrate[J].Nanotechnology,2011,22(05):055705. |
[21] | Li Junfeng;Lin Hong;Yang Zhilong et al.A method for the catalytic reduction of graphene oxide at temperatures below 150℃[J].Carbon,2011,49:3024. |
[22] | Boukhvalov DW;Katsnelson MI .Modeling of graphite oxide[J].Journal of the American Chemical Society,2008(32):10697-10701. |
[23] | Pei Songfeng;Zhao Jinping;Du Jinhong et al.Direct reduction of graphene oxide films into highly conductive and fiexible graphene films by hydrohalic acids[J].Carbon,2010,48(15):4466. |
[24] | Zhou, T.;Chen, F.;Liu, K.;Deng, H.;Zhang, Q.;Feng, J.;Fu, Q. .A simple and efficient method to prepare graphene by reduction of graphite oxide with sodium hydrosulfite[J].Nanotechnology,2011(4):045704-1-045704-6. |
[25] | Hyeon-Jin Shin;Ki Kang Kim;Anass Benayad;Seon-Mi Yoon;Hyeon Ki Park;In-Sun Jung;Mei Hua Jin;Hae-Kyung Jeong;Jong Min Kim;Jae-Young Choi;Young Hee Lee .Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance[J].Advanced functional materials,2009(12):1949-1961. |
[26] | 马文石,周俊文,程顺喜.石墨烯的制备与表征[J].高校化学工程学报,2010(04):719-722. |
[27] | Zhu, P.;Shen, M.;Xiao, S.;Zhang, D. .Experimental study on the reducibility of graphene oxide by hydrazine hydrate[J].Physica, B. Condensed Matter,2011(3):498-502. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%