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YBaCo4 O7是一种具有奇特氧吸附行为的材料,它在300℃左右的较低温度时就可以吸附其自身质量3%的氧,并且所吸附的氧在400℃可以快速脱附,同时具有稳定的循环特性,是一种非常有潜力的氧分离材料.介绍了YBaCo4O7的晶体结构及在外界温度变化时所产生的独特氧吸附/脱附特性;综述了晶格中不同位置的元素掺杂替代对其氧特性的影响;并对此类材料在透氧膜、脱氧纯化剂等方面的潜在应用进行了初步探索,最后总结了当前存在的一些问题并展望了可能的解决途径.

参考文献

[1] Huang YH;Dass RI;Xing ZL;Goodenough JB .Double perovskites as anode materials for solid-oxide fuel cells.[J].Science,2006(5771):254-257.
[2] Jeffrey W. Fergus .Perovskite oxides for semiconductor-based gas sensors[J].Sensors and Actuators, B. Chemical,2007(2):1169-1179.
[3] Tan L;Gu X;Yang L et al.Influence of powder synthesis methods on microstructure and oxygen permeation performance of Ba0.5 Sr0.5 Co0.8 Fe0,2 O3-δ perovskite-type membranes[J].Journal of Membrane Science,2003,212:157.
[4] A. A. Taskin;A. N. Lavrov;Yoichi Ando .Achieving fast oxygen diffusion in perovskites by cation ordering[J].Applied physics letters,2005(9):091910-1-091910-3-0.
[5] Etchegoyen G;Chartier T;Del-Gallo P .An architectural approach to the oxygen permeability of a La0.6 Sr0.4 Fe0.9Ga0.1O3-δ perovskite membrane[J].Journal of the European Ceramic Society,2006,26:2807.
[6] Kharton VV.;Kovalevsky A.;Yaremchenko AA.;Figueiredo FM.;Naumovich EN. Shaulo AL.;Marques FMB. .Surface modification of La0.3Sr0.7C0O3-delta ceramic membranes[J].Journal of Membrane Science,2002(2):277-287.
[7] Lee S.;Lee KS.;Woo SK.;Kim JW.;Ishihara T.;Kim DK. .Oxygen-permeating property of LaSrBFeO3 (B=Co, Ga) perovskite membrane surface-modified by LaSrCoO3[J].Solid state ionics,2003(3/4):287-296.
[8] 申梓刚,路朋献,胡行.利用激光刻蚀技术提高Ba_(0.5) Sr_(0.5) Co_(0.8)Fe_(0.2) O_(3-δ) 膜的透氧能力[J].无机材料学报,2010(02):221-224.
[9] Jin W;Li S;Huang P et al.Fabrication of La0.2Sr0.8Co0.8-Fe0.2 O3-δ mesoporous membranes on porous supports from polymeric precursors[J].Journal of Membrane Science,2000,170(01):9.
[10] Wang H;Cong Y;Yang W .Investigation on the partial oxidation of methane to syngas in a tubular Ba0.5 Sr0.5 Co0.a Fe0.2-O3-δ membrane reactor[J].Catalysis Today,2003,82:157.
[11] Chen CH.;Vandoorn RHE.;Kruidhof H.;Burggraaf AJ.;Bouwmeester HJM. .OXYGEN PERMEATION OF LA0.3SR0.7COO3-DELTA[J].Solid state ionics,1997(1/2):7-13.
[12] Ikeguchi M;Yoshino Y;Kanie K et al.Effects of preparation method on oxygen permeation properties of SrFeCo0.5 O3membrane[J].Separation and Purification Technology,2003,32:313.
[13] Cook R L;Sammells A F .On the systematic selection of perovskite solid electrolytes for intermediate temperature fuel cells[J].Solid-State Ionicis,1991,45:311.
[14] Shao, ZP;Haile, SM .A high-performance cathode for the next generation of solid-oxide fuel cells[J].Nature,2004(7005):170-173.
[15] Martin Valldor;Magnus Andersson .The structure of the new compound YBaCo_4O_7 with a magnetic feature[J].Solid state sciences,2002(7):923-931.
[16] Martin Valldor .Syntheses and structures of compounds with YBaCo_4O_7-type structure[J].Solid state sciences,2004(3):251-266.
[17] 郭兰静 .YBaCo<,4>O<,7>及其相关化合物氧吸附性能研究[D].郑州大学,2005.
[18] Karppinen M;Yamauchi H;Otani S;Fujita T;Motohashi T;Huang YH;Valkeapaa M;Fjellvag H .Oxygen nonstoichiometry in YBaCo4O7+delta: Large low-temperature oxygen absorption/desorption capability[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(2):490-494.
[19] ZHU Baofeng,HAO Haoshan,ZHANG Yong,JIA Jianfeng,HU Xing.Clarification of the oxygen adsorption properties of YBaCo_4O_7 at high temperature by thermogravimetry[J].稀土学报(英文版),2010(01):84-87.
[20] Hao HS;Cui JH;Chen CQ;Pan LJ;Hu J;Hu X .Oxygen adsorption properties of YBaCo4O7-type compounds[J].Solid state ionics,2006(7/8):631-637.
[21] Wang S;Hao HS;Zhu BF;Jia JF;Hu X .Modifying the oxygen adsorption properties of YBaCo4O7 by Ca, Al, and Fe doping[J].Journal of Materials Science,2008(15):5385-5389.
[22] Rasanen, S;Motohashi, T;Yamauchi, H;Karppinen, M .Stability and oxygen-storage characteristics of Al-substituted YBaCo4O7+delta[J].Journal of Solid State Chemistry,2010(3):692-695.
[23] Zhang K;Zhu Z;Ran R et al.Layered perovskite Y1-x-Cax BaCo4O7+δ as ceramic membranes for oxygen separation[J].Journal of Alloys and Compounds,2010,492(1-2):552.
[24] HAO Haoshan,ZHAO Limin,FIU Jie,HU Xing,HOU Hongwei.Oxygen adsorption/desorption behavior of YBaCo_4O_(7+δ) and its application to oxygen removal from nitrogen[J].稀土学报(英文版),2009(05):815-818.
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