地质聚合物是一种新型高性能胶凝材料.由于其特殊的缩聚三维网络结构,使其在众多方面具有高分子材料、水泥和陶瓷等材料的特征.综述了国内外地质聚合物的制备研究及聚合反应机理,概述了地质聚合物具备的性能特点及其在土木工程、快速修补和有毒废料及放射性废料处理等领域广阔的应用发展前景,分析了目前国内地质聚合物推广应用中存在的问题,并结合自身的研究提出了几点建议.
参考文献
| [1] | Davidovits J .The ancient egyptian pyramids-concrete or ro-ck[J].Concrete International,1987,9(12):28. |
| [2] | Davidovits J .Geopolymers and geopolymeric new materials[J].Journal of Thermal Analysis,1989,35(02):429. |
| [3] | Davidovits J .Geopolymers:Inorganic polymer new mate-rials[J].Journal of Thermal Analysis,1991,37:1633. |
| [4] | Van Jaarsveld J G S;Van Deventer J S J;Lorenzen L .The potential use of geopolymerlc materials to immobilize toxic materials:part 1.Theory and application[J].Materials and Engineering,1997,10(07):659. |
| [5] | 马鸿文,杨静,任玉峰,凌发科.矿物聚合材料：研究现状与发展前景[J].地学前缘,2002(04):397-407. |
| [6] | Davidovits J.Geopolymer chemistry and properties[A].Compiegne:The Geopolymer Institute,1988:25. |
| [7] | Davidovits J .Geopolymers:Man-made rock geosynthesis and the resultion development of very early high strength cement[J].J Mater Education,1994,16(2-3):91. |
| [8] | Davidovits J .Recent progresses in concretes for nuclear waste and uranium waste containment[J].Concrete International,1994,16(12):53. |
| [9] | 代新祥,文梓芸.土壤聚合物水泥[J].新型建筑材料,2001(06):34-35. |
| [10] | 袁玲,施惠生,汪正兰.土聚水泥研究与发展现状[J].房材与应用,2002(02):21-24. |
| [11] | 张书政,龚克成.地聚合物[J].材料科学与工程学报,2003(03):430-436. |
| [12] | 翁履谦,宋申华.新型地质聚合物胶凝材料[J].材料导报,2005(02):67-68,80. |
| [13] | 苏达根,朱锦辉,周新涛.矿物键合材料研究进展[J].广州化工,2005(05):8-9. |
| [14] | 李海红,徐惠忠,高原,刘子全,阎逢元.矿物聚合物材料的研究进展[J].机械工程材料,2006(06):1-3,33. |
| [15] | Davidovites J .First patent on polycondensation of kaolinite with NaOH[P].US FR72138746,1972-11-02. |
| [16] | Davidovites J.Synthesis of new high-temperature geo-polymers for reinforced plastics /composites[A].USA:Brookfield Center,1979:151. |
| [17] | Barbosa V F F;Mackenzie K J D;Thaumaturgo C.Synthesis and characterisation of materials based on inorganic polymers of alumina and silica:sodium polysialate polymers[J].International Journal of Inorganic Materials,2000(02):309. |
| [18] | Palomo A;Maclas A;Blancom T.Physical,chemical and mechanical characterisation of geopolymers[A].New Delhi,India,1992:505. |
| [19] | Van Jaarsveld J G S;Van deventer J S J;Lorenzen L .Factors affecting the immobilisation of metals in geopolymerized fly ash[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1998,29:283. |
| [20] | Van Jaarsveld J G S;Van Deventer J S J .The potential use of geopolymeric materials to immobolise toxic metals:PartⅡ.Materials and leaching characteristics[J].Miter Eng,1999,12:75-91. |
| [21] | Van Jaarsveld J G S;Van Deventer J S J .Effect of the alkali metal activator on the properties of fly ash-based geopolymers[J].Industrial and Engineering Chemistry Research,1999,38:3932. |
| [22] | Van Jaarsveld J G S;Lukey G C;Van Deventer J S J et al.The stabilization of mine tailings by reactive geopolymerization[J].Publ Australas Inst Min Metall,2000,5:363. |
| [23] | 吴怡婷,施惠生.制备土聚水泥中若干因素的影响[J].水泥,2003(03):1-3. |
| [24] | 王玉江,李和平,任和平.土聚水泥的研究[J].硅酸盐通报,2003(04):70-74. |
| [25] | 王爱国,孙道胜,胡普华,任小敏.碱激发偏高岭土制备土聚水泥的试验研究[J].合肥工业大学学报（自然科学版）,2008(04):617-621. |
| [26] | 聂轶苗,马鸿文,杨静,苏玉柱,李如臣,高飞.矿物聚合材料固化过程中的聚合反应机理研究[J].现代地质,2006(02):340-346. |
| [27] | 苏玉柱,杨静,马鸿文,聂轶苗,李如臣.利用粉煤灰制备高强矿物聚合材料的实验研究[J].现代地质,2006(02):354-360. |
| [28] | 李化建,孙恒虎,肖雪军.煤矸石质硅铝基胶凝材料的试验研究[J].煤炭学报,2005(06):778-782. |
| [29] | 曾燕伟;方永浩;徐玲玲.化学激发胶凝材料研究进展[A].南京:东南大学出版社,2005:44. |
| [30] | 张云升,孙伟,林玮,郑克仁,沙建芳,刘斯凤.用环境扫描电镜原位定量研究K-PS型地聚合物水泥的水化过程[J].东南大学学报(自然科学版),2003(03):351-354. |
| [31] | 张云升,孙伟,郑克仁,林玮,沙建芳,刘斯凤.ESEM追踪K-PSDS型地聚合物水泥的水化[J].建筑材料学报,2004(01):8-13. |
| [32] | 段瑜芳,王培铭,杨克锐.碱激发偏高岭土胶凝材料水化硬化机理的研究[J].新型建筑材料,2006(01):22-25. |
| [33] | 聂轶苗,马鸿文,杨静,苏玉柱,李如臣,高飞.矿物聚合材料固化过程中的聚合反应机理研究[J].现代地质,2006(02):340-346. |
| [34] | 胡普华,王爱国,孙道胜.煤系高岭土制备土聚水泥的正交优化设计[J].材料导报,2008(11):150-152,156. |
| [35] | Davidovits J.Properties of geopolymer cement[A].Kiev Ukraine:Scientific Research Institute on Binders and Materials,1994:131. |
| [36] | Mallow;William A .Fixation of haxardous wastes and rela-ted products[P].US 5976244,1999-11-02. |
| [37] | 王恩,倪文,孙汉.工业固体废弃物制备地质聚合物技术的原理与发展[J].矿产综合利用,2005(02):30-34. |
| [38] | 郑娟荣.地聚物基涂料的试验研究[J].新型建筑材料,2004(05):54-55. |
| [39] | 郑娟荣,覃维祖.地聚物材料的研究进展[J].新型建筑材料,2002(04):11-12. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%