欢迎登录材料期刊网

材料期刊网

中国科学院金属研究所 科学出版社
高级检索
  1. 首页
  2. 期刊
  3. 复合材料学报
  4. 苯并噁嗪共混树脂及其玻璃纤维布增强复合材料的制备与性能

复合材料学报, 2013, 30(4): 13-21.

苯并噁嗪共混树脂及其玻璃纤维布增强复合材料的制备与性能

刘志华 1, , 袁荞龙 2, , 黄发荣 3,

1.

2.

3.

基金项目:   上海市重点学科资助项目(B502)  

关键词： 苯并噁嗪 , 含硅芳炔树脂 , 共混 , 复合材料 , 热性能 , 介电性能

Preparation and properties of polybenzoxazine blends and their glass fabric-reinforced composites

Keywords： benzoxazine , silicon-containing arylacetylene resin(PSA) , blend , composites , thermal property , dielectrical property

采用氨基保护和还原方法合成了对氨基苯炔丙基醚(APPE),与苯酚和多聚甲醛通过Mannich缩合制备了含炔丙基的苯并噁嗪(P-APPE).采用溶液共混的方法,将P-APPE与苯酚/苯胺型苯并噁嗪(PAF)和含硅芳炔树脂(PSA)共混得到了改性苯并噁嗪树脂.用差示扫描量热法、动态热力学分析、热失重分析和宽频介电仪研究了该树脂体系的热性能和介电性能.研究结果表明:PSA加入到苯并噁嗪树脂中可提高共混树脂的热性能,加入质量分数为14.3％的PSA可使共混树脂的Tg从195℃提高至235℃,其5％热失重温度从350℃提高至399℃；共混树脂的介电损耗因子和介电常数随PSA加入量的增加而降低.玻璃纤维布增强的共混树脂复合材料的层间剪切强度和弯曲强度在加入质量分数为5.3％的PSA后下降超过50％.

参考文献

[1] Kiskan B,Ghosh N N,Yagci Y.Polybenzoxazine-based composites as high-performance materials[J].Polymer International,2011,60(2):167-177.
[2] Agag T,Takeichi T.Novel benzoxazine monomers containing p-phenyl propargyl ether:Polymerization of monomers and properties of polybenzoxazines[J].Macromolecules,2001,34(21):7257-7263.
[3] Agag T,Takeichi T.Preparation,characterization,and polymerization of maleimidobenzoxazine monomers as a novel class of thermosetting resins[J].Journal of Polymer Science Part A,2006,44(4):1424-1435.
[4] Kiskan B,Yagci Y.Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst[J].Polymer,2008,49(10):2455-2460.
[5] Chernykh A,Agag T,Ishida H.Effect of polymerizing diacetylene groups on the lowering of polymerization temperature of benzoxazine groups in the highly thermally stable,main-chain-type polybenzoxazines[J].Macromolecules,2009,42(14):5121-5127.
[6] Demir K D,Kiskan B,Yagci Y.Thermally curable acetylene-containing main-chain benzoxazine polymers via sonogashira coupling reaction[J].Macromolecules,2011,44(7):1801-1807.
[7] Nagai A,Kamei Y,Wang X,et al.Synthesis and crosslinking behavior of a novel linear polymer bearing 1,2,3-triazol and benzoxazine groups in the main chain by a step-growth clickcoupling reaction[J].Journal of Polymer Science Part A,2008,46(7):2316-2325.
[8] Chernykh A,Agag T,Ishida H.Synthesis of linear polymers containing benzoxazine moieties in the main chain with high molecular design versatility via click reaction[J].Polymer,2009,50(2):382-390.
[9] Ergin M,Kiskan B,Gacal B,et al.Thermally curable polystyrene via click chemistry[J].Macromolecules,2007,40(13):4724-4727.
[10] Kiskan B,Demiray G,Yagci Y.Thermally curable polyvinylchloride via click chemistry[J].Journal of Polymer Science Part A,2008,46(11):3512-3518.
[11] Kukut M,Kiskan B,Yagci Y.Self-curable benzoxazine functional polybutadienes synthesized by click chemistry[J].Designed Monomers and Polymers,2009,12(2):167-176.
[12] Chang H C,Lin C H,Lin H T,et al.Deprotection-free preparation of propargyl ether-containing phosphinated benzoxazine and the structure-property relationship of the resulting thermosets[J].Journal of Polymer Science Part A,2012,50(5):1008-1017.
[13] Kiskan B,Aydogan B,Yagci Y.Synthesis,characterization,and thermally activated curing of oligosiloxanes containing benzoxazine moieties in the main chain[J].Journal of Polymer Science Part A,2009,47(3):804-811.
[14] Rimduslt S,Ishida H.Development of new class of electronic packing materials based on ternary systems of benzoxazine,epoxy,and phenolic resins[J].Polymer.2000,41(22):7941-7949.
[15] 凌鸿,顾宜,谢美丽,等.开环聚合酚醛树脂基复合材料的研究:ALPF3-EGF层压板的研制[J].热固性树脂.1999,14(1):20-23.Ling Hong,Gu Yi,Xie Meili,et al.Study on the ringopening polymerized phenolic-basis composite-development of laminate(ALPF3-EGF)[J].Thermoseting Resin,1999,14(1):20-23.
[16] Kimura H,Matsumoto A,Ohtsuka K.Glass fiber-reinforced composite based on benzoxazine resin[J].Journal of Applied Polymer Science,2009,114(2):1256-1263.
[17] 冉起超,高念,李培源,等.一种RTM用苯并噁嗪树脂的工艺性及其复合材料性能[J].复合材料学报,2011,28(1):15-20.Ran Qichao,Gao Nian,Li Peiyuan,et al.Processing property of a RTM benzoxazine resin and properties of composites[J].Acta Materiae Compositae Sinica,2011,28(1):15-20.
[18] 刘峰,赵西娜,陈轶华.酚醛改性苯并噁嗪树脂及其复合材料性能[J].复合材料学报,2008,25(5):57-63.Liu Feng,Zhao Xina,Chen Yihua.Resin of phenolic modification benzoxazine and its properties of composite[J].Acta Materiae Compositae Sinica,2008,25(5):57-63.
[19] 郑林,张驰,王洲一,等.一种改性苯并嗯嗪树脂及其玻璃布层压板[J].航空材料学报,2011,31(1):62-66.Zheng Lin,Zhang Chi,Wang Zhouyi,et al.Modified benzoxazine and its glass cloth laminate[J].Journal of Aeronautical Materials,2011,31(1):62-66.
[20] Wang X,Gu Y.Preparation,characterization,and properties of resol-based benzoxazine intermediates and glass cloth reinforced laminates based on their polymers[J].Journal of Macromolecular Science Part B,2011,50(11):2214-2226.
[21] 严浩,齐会民,黄发荣.新颖含硅芳基多炔树脂的合成与性能[J].石油化工,2004,33(9):880-883.Yan Hao,Qi Huimin,Huang Farong.Synthesis and characterization of poly(arylene acetylene)containing dimethylsilylene[J].Petrochemical Technology,2004,33(9):880-883.
[22] Wang F,Huang F R,Du L,et al.Synthesis and characterization of poly(dimethylsilylene-ethynylenephenyleneethynylene)terminated with phenylacetylene[J].Polymer Bulletin,2006,56(1):19-26.
[23] 全国纤维增强塑料标准化技术委员会.GB/T 3356-1999中国标准书号[S].北京:中国标准出版社,1999.National Technical Committee on Fiber Reinforced Plastic of Standardization Administration of China.GB/T 3356-1999China standard book number[S].Beijing:Standards Press of China,1999.
[24] 全国塑料标准化技术委员会纤维增强塑料分会.JC/T773-1982中国标准书号[S].北京:中国标准出版社,1982.National Technical Committee on Plastics of Standardization Administration of China,Branch of Fiber Reinforced Plastics.JC/T 773-1982 China standard book number[S].Beijing:Standards Press of China,1982.
[25] American Society for Testing and Materials.ASTM D 3056-2000 Standard test method for gel time of solventless varnishes[S].Philadelphia,America:American Society for Testing and Materials,2000.
[26] 全国人造板标准化技术委员会.GB/T14074-2006中国标准书号[S].北京:中国标准出版社,2006.National Technical Committee on Non-Wood-Based Board of Standardization Administration of China.GB/T 14074-2006 China standard book number[S].Beijing:Standards Press of China,2006.
[27] Dunkers J,Ishida H.Vibrational assignments of 3-alkyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazines in the fingerprint region[J].Spectrochimica Acta Part A,1995,51(6):1061-1074.
[28] Ishida H,Low H Y.Synthesis of benzoxazine functional silane and adhesion properties of glass-fiber-reinforced polybenzoxazine composites[J].Journal of Applied Polymer Science,1998,69(13):2559-2567.
[29] Kim H D,Ishida H.A study on hydrogen-bonded network structure of polybenzoxazines[J].Journal of Physical Chemistry A,2002,106(14):3271-3280.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
作者相关
文章评分
  • 您的评分：
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%

版权所有©2010中国科学院金属研究所中国科技出版传媒股份有限公司

本系统由北京仁和汇智信息技术有限公司设计开发

技术支持：info@rhhz.net