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本文对含有β成核剂等规聚丙烯的注塑样品进行压缩,研究了不同压缩比、不同压缩温度条件下,注塑样品的皮芯结构变化情况.结果表明,当注塑样品压缩比达到一定临界值时,压缩可以消除注塑样品中晶体结构的不均一性,对于注塑iPP样品来说,该值介于2和4之间;随着压缩比的增大,样品中的β晶和α晶均被进一步破坏,总结晶度降低,晶体的取向度增加;随压缩温度的升高,β晶破坏明显,而α晶含量增加,晶体取向度均略微增大.

参考文献

[1] Stocker W.;Graff S.;Thierry A.;Wittmann JC.;Lotz B.;Schumacher M. .Epitaxial crystallization and AFM investigation of a frustrated polymer structure: Isotactic poly(propylene), beta phase[J].Macromolecules,1998(3):807-814.
[2] Zhang YF;Xin Z .Isothermal crystallization behaviors of isotactic polypropylene nucleated with alpha/beta compounding nucleating agents[J].Journal of Polymer Science, Part B. Polymer Physics,2007(5):590-596.
[3] Chang-Mou Wu;Ming Chen;Jozsef Karger-Kocsis .The role of metastability in the micromorphologic features of sheared isotactic polypropylene melts[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(15):4195-4203.
[4] Varga J;Menyhard A .Effect of solubility and nucleating duality of N,N '-dicyclohexyl-2,6-naphthalenedicarboxamide on the supermolecular structure of isotactic polypropylene[J].Macromolecules,2007(7):2422-2431.
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