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将乙烯-醋酸乙烯酯共聚物(EVA)、丙烯酸酯弹性体(AR)和云母(Mica)熔融共混制备了一系列复合材料.动态力学分析发现,EVA与AR共混后,tanδ在5℃附近出现了新峰;在EVA-AR(80/20)中加入聚合级空间受阻酚MPDI(4-甲基-苯酚与二环戊二烯和异丁烯的反应产物),tanδ峰值逐渐增大,且峰位置逐渐向高温方向偏移.云母的加人使EVA-AR-MPDI共混物的tanδ峰位置明显向高温方向偏移,而且峰宽拓宽明显.随着云母含量的增加,高温区tanδ数值逐步变大,损耗模量E"大幅度提高,当云母含量为58.8 wt%时E"峰值由未加云母时的79 MPa增加至280 MPa,并且E"峰位置向高温偏移.氢键红外光谱和扫描电镜分析结果表明,复合材料阻尼性能有所提高.

参考文献

[1] 曾正荣.EVA的技术进展及开发应用[J].现代化工,1996(11):1 9-23.Zeng Zhengrong.Advance in technology of EVA and its application[J].Modern Chemical Industry,1996 (11):19-23.
[2] Paulo J,Soares B G.The effect of mercapto-modified EVA on rheological and dynamic mechanical properties of NBR/EVA blends[J].Journal of Applied Polymer Science,2002,84:2335-2344.
[3] Wu Caiyun,Wei Chunyan,Guo Weihong,Wu Chifei.Dynamic mechanical properties of acrylic rubber blended With phenolic resin[J].Journal of Applied Polymer Science,2008,109:2065-2070.
[4] Wu Chifei,Tadaaki Yamagishi,Yoshiaki Nakamoto,et al.Organic hybrid of chlorinated polyethylene and hindered phenol Ill:Influence of the molecular weight and chlorine concentration of the polymer on the viscoelastic properties[J].Journal of Polymer Science,Part B:Polymer Physics,2000,38:2943-2953.
[5] Wu Chifei,Tadaaki Yamagishi,Yoshiaki Nakamoto,et al.Viscoelaslic properties of an organic hybrid of chlorinated polyethylene and a small molecule[J].Journal of Polymer Science,Part B..Polymer Physics,2000,38(10):1341-1347.
[6] Wu Chifei,Akiyama Suburo.Dynamic properties of carbon black filled chlorinated polyethylene/hindered phenol blends[J].Polymer International,2003,52:1249-1255.
[7] Bleach N C,Nazhat S N,Tanner K E,et al.Effect of fillet concentration on mechanical and dynamic mechanical properties of particulate biphasic calcium phosphate-polylactide composites[J].Biomaterials,2002,23:1579-1585.
[8] 范力仁,董晓娜,郑梯和.超细绢云母/Jm成型液体硅橡胶复合材料的制备及性能[J].复合材料学报,2008,25(4):90-95.Fan Liren,Dong Xiaona,Zheng Tihe.Preparation and properties of uhrafine sericite/addition liquid silicone rubber composites[J].Acta Materiae Compositae Sinica,2008,25 (4):90-95.
[9] 沈效峰,钱钟钟,张伟安.熔融法制备EVA/OMMT纳米复合材料及其热性能和动态力学性能[J].应用化学,2004,21(10):1042-1045.Shen Xiaofeng,Qian Zhongzhong,Zhang Weian.Thermal properties and dynamic mechanical behavior of poly(ethyleneco vinyl acetate)/montmorillonite nanoeomposites prepared by melt blending[J].Chinese Journal of Applied Chemistry,2004,21(10):1042-1045.
[10] Hajime K,Manabu K,Satoshi M,et al.Damping properties of thermoplastic elastomer interleaved carbon fiber reinforced epoxy composites[J].Composites Science and Technology,2004,64:2517-2523.
[11] Bernd W,Werner R,Lei Q H.Mechanical spectroscopy of polymer magnetite composites[J].Materials Science and Engineering A,2004,370(1/2):278-283.
[12] 赵秀英,向平,张立群.受阻酚/丁腈橡胶复合材料的结构与性能[J].复合材料学报,2007,24(2):44-49.Zhao Xinying,Xiang Ping,Zhang Liqun.Structure and properties of hindered pbenol/nitrile-butadiene rubber composites[J].Acta Materiae Compoaitae Sinica,2007,24 (2):44-49.
[13] 向平,肖大玲,赵秀英,卢咏来,张立群.受阻酚AO 80/NBR/PVC交联复合材料的结构与动态力学性能[J].复合材料学报,2007,24(6):44-49.Xiang Ping,Xiao Daling,Zhao Xiuying,Lu Yonglai,Zhang Liqun.Microstructure and dynamic mechanical properties of hindered phenol AO-80/NBR/PVC crosslinking composites[J].Acta Materiae Compositae Sinica,2007,24(6):44-49.
[14] Zhang Cheng,Wang Ping,Ma Chunan.Damping properties of chlorinated polyethylene based hybrids:Effect of organic:additives[J].Journal of Applied Polymer Science,2006,100:3307-3311.
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